SYMF version 4.II.2001 ------------------------------------------------------------------------------- CL3CCN, all 35.Cl ------------------------------------------------------------------------------- Fit of symmetric top Hamiltonian with splitting terms: B.z = 1732.1794248417970000000 +- 3.1679492515806440000 B = 1666.8089217588860000000 +- .0000557630072341186 DJ = .0001350193776807525 +- .0000000100314410300 DJK = .0006056918218348380 +- .0000001726037815156 HJ = -.0000000000190602679 +- .0000000000004567823 HJK = .0000000011338472289 +- .0000000000090915521 HKJ = -.0000000014781600767 +- .0000000000936280987 h3 = .0000000000220886826 +- .0000000000001970606 Deviation of fit = .032010 Weighted deviation of fit = .819853 TRANSITION Observed Obs-Calc Error 1. 8 0 30002.1200 -.0469 .2000 2. 9 0 33335.7400 .1017 .2000 3. 10 0 36669.0300 -.0474 .2000 4. 26 0- 2 89996.9870 -.0084 .0200 5. 26 3 89996.7440 -.0141 .0200 6. 26 4 89996.5130 -.0149 .0200 7. 26 5 89996.2200 -.0143 .0200 8. 26 6 89995.8610 -.0144 .0200 9. 26 7 89995.4370 -.0143 .0200 10. 28 0- 1 96661.7250 -.0007 .0200 11. 28 2 96661.6030 -.0001 .0200 12. 28 3 96661.4220 -.0087 .0200 13. 28 4 96661.1790 -.0038 .0200 14. 28 5 96660.8620 -.0056 .0200 15. 28 6 96660.4850 .0026 .0200 16. 28 7 96660.0210 -.0060 .0200 17. 28 8 96659.5090 .0074 .0200 18. 28 9 96658.9170 .0110 .0200 19. 31 0- 1 106658.0690 .0184 .0200 20. 31 2 106657.9330 .0176 .0200 21. 31 3 106657.7380 .0112 .0200 22. 31 4 106657.4630 .0110 .0200 23. 31 5 106657.1240 .0196 .0200 24. 31 6 106656.6980 .0184 .0200 25. 31 7 106656.1970 .0195 .0200 26. 31 8 106655.6240 .0259 .0200 27. 31 9 106654.9610 .0196 .0200 28. 31 10 106654.2130 .0056 .0200 29. 31 11 106653.3720 -.0240 .0200 30. 41 0- 1 139971.8810 -.0149 .0200 31. 41 2 139971.7140 -.0050 .0200 32. 41 3 139971.4510 -.0326 .0200 33. 41 4 139971.1100 -.0025 .0200 34. 41 5 139970.6560 -.0016 .0200 35. 41 6 139970.1080 .0065 .0200 36. 41 7 139969.4570 .0126 .0200 37. 41 8 139968.6820 -.0040 .0200 38. 41 9 139967.8400 .0135 .0200 39. 41 10 139966.8830 .0172 .0200 40. 41 11 139965.8170 .0132 .0200 41. 41 12 139964.6590 .0184 .0200 42. 41 13 139963.3910 .0149 .0200 43. 41 14 139962.0430 .0328 .0200 44. 41 15 139960.5850 .0420 .0300 45. 41 16 139958.9730 -.0013 .0300 46. 41 17 139957.3060 .0018 .0300 47. 41 18 139955.5570 .0245 .0300 48. 52 0- 1 176601.2370 -.0239 .0300 49. 52 2 176601.0340 -.0046 .0300 50. 52 D 3 176600.6920 -.0290 .0300 51. 52 4 176600.2600 -.0163 .0300 52. 52 5 176599.6860 -.0185 .0300 53. 52 6 176598.9860 -.0196 .0300 54. 52 7 176598.1510 -.0285 .0300 55. 52 8 176597.1770 -.0493 .0300 56. 52 9 176596.1320 -.0140 .0300 57. 52 10 176594.9110 -.0274 .0300 58. 52 11 176593.6090 .0054 .0300 59. 52 12 176592.1310 -.0105 .0300 60. 52 13 176590.5150 -.0370 .0300 61. 52 14 176588.8380 .0028 .0300 62. 52 15 176586.9830 -.0080 .0300 63. 52 17 176582.9610 .0410 .0300 64. 52 18 176580.7010 .0078 .0300 65. 52 19 176578.3380 -.0007 .0300 66. 52 20 176575.8480 -.0084 .0300 67. 52 21 176573.2340 -.0124 .0300 68. 52 22 176570.4980 -.0104 .0300 69. 52 23 176567.6510 .0085 .0300 70. 52 24 176564.6510 .0024 .0300 71. 52 25 176561.5190 -.0075 .0300 72. 52 26 176558.3160 .0399 .0300 73. 52 27 176554.9180 .0205 .0300 74. 52 28 176551.4400 .0496 .0300 75. 62 0- 1 209882.7010 -.0269 .0300 76. 62 2 209882.4890 .0244 .0300 77. 62 3 209882.1880 -.0325 .0300 78. 62 -3 209881.9970 .0392 .0300 79. 62 4 209881.5680 .0047 .0300 80. 63 0- 1 213209.7810 -.0215 .0300 81. 63 2 213209.5430 .0079 .0300 82. 63 3 213209.2360 -.0601 .0300 83. 63 -3 213209.0290 .0172 .0300 84. 63 4 213208.6060 -.0141 .0300 85. 63 5 213207.9160 -.0167 .0300 86. 63 6 213207.0680 -.0250 .0300 87. 63 7 213206.0940 -.0061 .0300 88. 64 0- 1 216536.6440 -.0251 .0300 89. 64 2 216536.3950 -.0025 .0300 90. 64 3 216536.1410 -.0234 .0300 91. 64 -3 216535.8780 .0208 .0300 92. 64 4 216535.4680 -.0010 .0300 93. 64 5 216534.7420 -.0291 .0300 94. 64 6 216533.9130 -.0057 .0300 95. 64 7 216532.9090 -.0018 .0300 96. 64 8 216531.6950 -.0530 .0300 97. 64 9 216530.3990 -.0311 .0300 98. 64 10 216528.9580 .0010 .0300 99. 64 11 216527.3150 -.0137 .0300 100. 64 12 216525.5300 -.0152 .0300 101. 64 13 216523.6010 -.0053 .0300 102. 64 14 216521.5400 .0279 .0300 103. 64 15 216519.2280 -.0344 .0300 104. 64 16 216516.8360 -.0212 .0300 105. 64 17 216514.2790 -.0174 .0300 106. 64 18 216511.5750 -.0050 .0300 107. 64 19 216508.6660 -.0418 .0300 108. 64 20 216505.6860 .0062 .0300 109. 64 21 216502.5110 .0151 .0300 110. 64 22 216499.2150 .0590 .0300 111. 64 23 216495.6650 .0050 .0300 112. 64 24 216491.9520 -.0558 .0300 113. 64 25 216488.1950 -.0043 .0300 114. 64 26 216484.2000 -.0343 .0300 115. 64 27 216480.0830 -.0298 .0300 116. 64 28 216475.8610 .0264 .0300 117. 64 29 216471.3670 -.0326 .0300 118. 64 30 216466.7820 -.0257 .0300 119. 64 31 216462.0120 -.0468 .0300 120. 64 32 216457.1180 -.0346 .0300 121. 64 33 216452.0860 -.0030 .0300 122. 64 34 216446.8930 .0250 .0300 123. 64 35 216441.4760 -.0133 .0300 124. 64 36 216435.9640 .0112 .0300 125. 64 37 216430.2760 .0176 .0300 126. 64 38 216424.4170 .0113 .0300 127. 64 39 216418.4260 .0312 .0300 128. 64 40 216412.2370 .0116 .0300 129. 64 41 216405.8630 -.0342 .0300 130. 65 0 219863.4170 .0532 .0300 131. 65 1 219863.3270 .0419 .0300 132. 65 2 219863.0760 .0272 .0300 133. 65 3 219862.8050 -.0171 .0300 134. 65 -3 219862.5190 .0284 .0300 135. 65 4 219862.1070 .0004 .0300 136. 66 0- 1 223189.7460 -.0192 .0300 137. 66 4 223188.5280 -.0018 .0300 138. 66 5 223187.8200 .0090 .0300 139. 66 6 223186.9420 .0087 .0300 140. 66 7 223185.8730 -.0223 .0300 141. 66 8 223184.7080 .0100 .0300 142. 66 9 223183.3760 .0351 .0300 143. 66 10 223181.8250 .0010 .0300 144. 67 0- 1 226515.9620 -.0262 .0300 145. 67 2 226515.7370 .0327 .0300 146. 67 3 226515.5070 .0138 .0300 147. 67 -3 226515.1350 .0268 .0300 148. 67 4 226514.7270 -.0082 .0300 149. 67 5 226514.0190 .0130 .0300 150. 85 0- 1 286347.0170 .0015 .0500 151. 85 3 .0000 -286346.7859EXCL .0500 152. 85 2 .0000 -286346.6534EXCL .0500 153. 85 -3 286345.5630 .0232 .0500 154. 85 4 286345.5630 .0935 .0500 155. 85 5 286344.5730 .0227 .0500 156. 85 6 286343.4520 .0134 .0500 157. 85 7 286342.1080 -.0073 .0500 158. 85 8 286340.6250 .0301 .0500 159. 86 0- 1 .0000 -289668.4762EXCL .0500 160. 86 3 .0000 -289668.2753EXCL .0500 161. 86 2 .0000 -289668.1091EXCL .0500 162. 86 -3 289666.9810 .0259 .0500 163. 86 4 289666.9810 .0648 .0500 164. 86 5 289665.9880 .0019 .0500 165. 86 6 289664.8750 .0124 .0500 166. 86 7 289663.5280 .0040 .0500 167. 86 8 289662.0340 .0472 .0500 168. 105 3 .0000 -352719.3591EXCL .0500 169. 105 0- 2 352718.4050 .0293 .0500 170. 105 4 352716.9220 .0328 .0500 171. 105 -3 .0000 -352715.8141EXCL .0500 172. 105 5 352715.7060 .0008 .0500 173. 105 D 6 352714.3390 .0115 .0500 174. 105 7 352712.7220 .0055 .0500 175. 105 8 352710.8950 .0307 .0500 176. 106 3 356034.6520 .0531 .0500 177. 106 0- 2 356033.4870 -.0385 .0500 178. 106 4 356032.0890 .0345 .0500 179. 106 5 356030.9070 .0545 .0500 180. 106 -3 .0000 -356030.8835EXCL .0500 181. 106 D 6 356029.4600 -.0005 .0500 182. 106 7 356027.8190 -.0155 .0500 183. 107 3 359349.4790 -.0131 .0500 184. 107 0- 2 359348.2920 -.0322 .0500 185. 107 4 359346.8590 -.0129 .0500 186. 107 5 359345.6520 .0009 .0500 187. 107 -3 .0000 -359345.5999EXCL .0500 188. 107 D 6 359344.3000 .0555 .0500 189. 107 7 359342.6480 .0446 .0500 190. 107 8 359340.7700 .0520 .0500 191. 107 9 359338.5760 -.0095 .0500 192. 107 10 359336.1830 -.0203 .0500 193. 107 11 359333.6100 .0380 .0500 194. 107 12 359330.7660 .0755 .0500 195. 107 13 359327.5300 -.0287 .0500 196. 107 14 359324.2120 .0356 .0500 197. 107 15 359320.5720 .0288 .0500 198. 107 16 359316.7010 .0418 .0500 199. 107 17 359312.5760 .0520 .0500 200. 107 18 359308.1690 .0314 .0500 201. 109 3 365978.1640 -.0618 .0500 202. 109 0- 2 365976.7810 -.0735 .0500 203. 109 4 365975.4560 .0060 .0500 204. 109 5 365974.1450 -.0438 .0500 205. 109 -3 .0000 -365973.9598EXCL .0500 206. 109 D 6 365972.7390 -.0132 .0500 207. 109 7 365971.0650 -.0156 .0500 208. 109 8 365969.1120 -.0498 .0500 209. 109 9 365966.9680 -.0246 .0500 210. 109 10 365964.5850 .0154 .0500 211. 109 11 365961.8730 -.0205 .0500 212. 109 13 365955.7890 .0103 .0500 213. 109 14 365952.4060 .0666 .0500 214. 109 16 365944.7440 .0483 .0500 215. 109 17 365940.4890 -.0020 .0500 216. 109 19 365931.2490 -.0662 .0500 217. 109 20 365926.3540 .0103 .0500 218. 110 3 369292.0530 -.0067 .0500 219. 110 0- 2 369290.6060 .0269 .0500 220. 110 4 369289.1960 -.0084 .0500 221. 110 5 369287.8820 -.0395 .0500 222. 110 -3 .0000 -369287.5964EXCL .0500 223. 110 D 6 369286.4500 -.0195 .0500 224. 110 7 369284.8220 .0396 .0500 225. 110 8 369282.7720 -.0748 .0500 226. 110 9 369280.6470 -.0123 .0500 227. 110 10 369278.1400 -.0758 .0500 228. 110 11 369275.4680 -.0495 .0500 229. 110 12 369272.6120 .0490 .0500 230. 110 13 369269.3380 -.0140 .0500 231. 110 14 369265.8870 .0027 .0500 232. 110 15 369262.1050 -.0546 .0500 233. 110 16 369258.1400 -.0376 .0500 234. 112 3 375918.7320 .0864 .0500 235. 112 0- 2 375916.9730 .0432 .0500 236. 112 4 375915.6700 .0419 .0500 237. 112 5 375914.2200 -.0782 .0500 238. 112 -3 .0000 -375913.7657EXCL .0500 239. 112 D 6 375912.7770 -.0372 .0500 240. 112 7 375911.0550 -.0408 .0500 241. 112 8 375909.0480 -.0785 .0500 242. 112 9 375906.8790 -.0233 .0500 243. 112 10 375904.4200 .0020 .0500 244. 112 12 375898.6900 .0178 .0500 245. 112 13 375895.4490 .0403 .0500 246. 112 16 375884.0010 -.0512 .0500 247. 112 17 375879.7940 .0501 .0500 248. 112 18 375875.1690 -.0050 .0500 249. 112 20 375865.2010 -.0474 .0500 250. 112 21 375859.9420 .0497 .0500 251. 112 22 375854.2610 -.0129 .0500 252. 112 23 375848.3830 -.0099 .0500 253. 112 24 375842.2980 .0489 .0500 254. 112 25 375835.8460 .0036 .0500 255. 112 26 375829.1520 -.0205 .0500 Sigma = .032010 243 Transitions in fit Sigma.w = .819853 235 Degrees of freedom B.z /MHz 1732.1(31) LJK /microHz 0. B /MHz 1666.808921(55) LKKJ/microHz 0. LK /microHz 0. DJ /kHz 0.135019(10) l1 /microHz 0. DJK /kHz 0.60569(17) l2 /microHz 0. DK /kHz 0. l3 /microHz 0. d1 /kHz 0. l4 /microHz 0. d2 /kHz 0. PJ /nHz 0. HJ /mHz -0.01906(45) PJJK /nHz 0. HJK /mHz 1.1338(90) PJK /nHz 0. HKJ /mHz -1.478(93) PKJ /nHz 0. HK /mHz 0. PKKJ /nHz 0. h1 /mHz 0. PK /nHz 0. h2 /mHz 0. p1 /nHz 0. h3 /mHz 0.02208(19) p2 /nHz 0. LJ /microHz 0. p3 /nHz 0. LJJK/microHz 0. p4 /nHz 0. p5 /nHz 0. CORRELATION COEFFICIENTS: B.z B DJ DJK HJ HJK HKJ h3 B.z 1.0000 B -.0050 1.0000 DJ .0029 .8960 1.0000 DJK -.0168 .2176 -.0505 1.0000 HJ .0242 .8149 .9788 -.1417 1.0000 HJK -.0301 .0843 -.1223 .7589 -.2551 1.0000 HKJ -.0063 .2431 .0672 .8394 .0384 .3604 1.0000 h3 .1311 -.0406 -.0722 .0569 -.1277 .1879 -.0430 1.0000 -------------------------------------------------------------------------------