------------------------------------------------------------------------------ VINYL FLUORIDE...HCl35 ------------------------------------------------------------------------------ TRANSITIONS: J K K <- J K K I F <- I F Obs Obs-Calc -1 +1 -1 +1 1. 1 1 0 1 0 1 3/2 5/2 3/2 5/2 9803.56630 -0.00215 2. 1 1 0 1 0 1 3/2 3/2 3/2 1/2 9803.78200 -0.00255 3. 1 1 0 1 0 1 3/2 1/2 3/2 3/2 9806.41280 -0.00192 4. 1 1 0 1 0 1 3/2 3/2 3/2 5/2 9810.43240 -0.00237 5. 1 1 0 1 0 1 3/2 5/2 3/2 3/2 9811.88330 -0.00086 6. 1 1 0 1 0 1 3/2 3/2 3/2 3/2 9818.75140 0.00092 7. 1 1 1 0 0 0 3/2 3/2 3/2 3/2 12916.74210 -0.00189 8. 2 1 2 1 0 1 3/2 1/2 3/2 1/2 16023.00000 0.00514 9. 2 1 2 1 0 1 3/2 7/2 3/2 5/2 16024.73320 -0.00054 10. 2 1 2 1 0 1 3/2 5/2 3/2 3/2 16026.20200 0.00266 11. 2 1 2 1 0 1 3/2 3/2 3/2 3/2 16031.09800 -0.00646-- 12. 2 1 1 2 0 2 3/2 3/2 3/2 1/2 10053.63680 0.00070 13. 2 1 1 2 0 2 3/2 1/2 3/2 1/2 10048.79670 0.00443 14. 2 1 1 2 0 2 3/2 5/2 3/2 7/2 0.00000 -10053.76701-- 15. 2 1 1 2 0 2 3/2 7/2 3/2 7/2 10055.78100 -0.00038 16. 2 1 1 2 0 2 3/2 5/2 3/2 3/2 10056.17160 0.00007 17. 2 1 1 2 0 2 3/2 3/2 3/2 3/2 10062.00390 0.00004 18. 2 1 1 2 0 2 3/2 1/2 3/2 3/2 0.00000 -10057.16003-- 19. 2 1 1 2 0 2 3/2 5/2 3/2 5/2 0.00000 -10062.15851-- 20. 2 1 1 2 0 2 3/2 3/2 3/2 5/2 0.00000 -10067.99085-- 21. 2 1 1 2 0 2 3/2 7/2 3/2 5/2 10064.17140 -0.00149 22. 3 1 3 2 1 2 3/2 7/2 3/2 7/2 9682.42210 -0.00299 23. 3 1 3 2 1 2 3/2 5/2 3/2 3/2 9688.55650 -0.00005 24. 3 1 3 2 1 2 3/2 7/2 3/2 5/2 9689.27540 0.00020 25. 3 1 3 2 1 2 3/2 3/2 3/2 1/2 9690.65350 -0.00046 26. 3 1 3 2 1 2 3/2 9/2 3/2 7/2 9691.37840 0.00031 27. 3 1 3 2 1 2 3/2 5/2 3/2 5/2 9693.46150 -0.00017 28. 3 1 3 2 1 2 3/2 3/2 3/2 3/2 9697.51100 0.00070 29. 3 0 3 2 0 2 3/2 7/2 3/2 7/2 10031.22410 -0.00167 30. 3 0 3 2 0 2 3/2 5/2 3/2 3/2 10038.16110 0.00016 31. 3 0 3 2 0 2 3/2 3/2 3/2 1/2 10033.48530 0.00116 32. 3 0 3 2 0 2 3/2 7/2 3/2 5/2 10039.61840 0.00112 33. 3 0 3 2 0 2 3/2 9/2 3/2 7/2 10041.78590 0.00060 34. 3 0 3 2 0 2 3/2 5/2 3/2 5/2 10044.14760 -0.00032 35. 3 0 3 2 0 2 3/2 3/2 3/2 3/2 10041.84800 -0.00390 36. 3 2 2 2 2 1 3/2 5/2 3/2 5/2 10053.90970 -0.00039 37. 3 2 2 2 2 1 3/2 7/2 3/2 5/2 10053.90970 0.00192 38. 3 2 2 2 2 1 3/2 3/2 3/2 3/2 10059.85480 -0.00541 39. 3 2 2 2 2 1 3/2 5/2 3/2 3/2 10059.85480 0.00020 40. 3 2 2 2 2 1 3/2 9/2 3/2 7/2 10062.21960 0.00058 41. 3 2 2 2 2 1 3/2 7/2 3/2 7/2 10062.21960 -0.00621 42. 3 2 1 2 2 0 3/2 7/2 3/2 5/2 10072.45520 0.00138 43. 3 2 1 2 2 0 3/2 3/2 3/2 3/2 10078.20060 0.00184 44. 3 2 1 2 2 0 3/2 5/2 3/2 3/2 10078.35850 -0.00028 45. 3 2 1 2 2 0 3/2 9/2 3/2 7/2 10080.67520 0.00166 46. 3 2 1 2 2 0 3/2 3/2 3/2 1/2 10086.57100 0.00025 47. 3 1 2 2 1 1 3/2 7/2 3/2 7/2 10418.68380 -0.00131 48. 3 1 2 2 1 1 3/2 7/2 3/2 5/2 10420.69950 0.00002 49. 3 1 2 2 1 1 3/2 5/2 3/2 3/2 10416.50950 0.00074 50. 3 1 2 2 1 1 3/2 5/2 3/2 5/2 10422.34080 -0.00030 51. 3 1 2 2 1 1 3/2 9/2 3/2 7/2 10422.22830 0.00113 52. 3 1 2 2 1 1 3/2 3/2 3/2 1/2 10424.94040 0.00203 53. 3 1 2 2 1 1 3/2 3/2 3/2 3/2 10420.09590 0.00136 54. 3 1 2 3 0 3 3/2 5/2 3/2 3/2 10436.66090 0.00017 55. 3 1 2 3 0 3 3/2 7/2 3/2 9/2 0.00000 -10432.68119-- 56. 3 1 2 3 0 3 3/2 3/2 3/2 3/2 10440.24600 -0.00050 57. 3 1 2 3 0 3 3/2 9/2 3/2 9/2 10436.22250 -0.00075 58. 3 1 2 3 0 3 3/2 7/2 3/2 5/2 10438.70920 -0.00087 59. 3 1 2 3 0 3 3/2 5/2 3/2 5/2 10440.35130 -0.00039 60. 3 1 2 3 0 3 3/2 7/2 3/2 7/2 0.00000 -10443.24072-- 61. 3 1 2 3 0 3 3/2 3/2 3/2 5/2 0.00000 -10443.93746-- 62. 3 1 2 3 0 3 3/2 5/2 3/2 7/2 0.00000 -10444.88234-- 63. 3 1 2 3 0 3 3/2 9/2 3/2 7/2 0.00000 -10446.78278-- 64. 4 1 4 3 1 3 3/2 9/2 3/2 9/2 12905.42710 -0.00214 65. 4 1 4 3 1 3 3/2 7/2 3/2 5/2 12913.64470 0.00052 66. 4 1 4 3 1 3 3/2 9/2 3/2 7/2 12914.38230 0.00006 67. 4 1 4 3 1 3 3/2 5/2 3/2 3/2 12914.50740 0.00151 68. 4 1 4 3 1 3 3/2 11/2 3/2 9/2 12915.24700 0.00105 69. 4 1 4 3 1 3 3/2 7/2 3/2 7/2 12917.83020 -0.00044 70. 4 1 4 3 1 3 3/2 5/2 3/2 5/2 12923.46030 0.00066 71. 4 0 4 3 0 3 3/2 7/2 3/2 5/2 13367.08200 -0.00086 72. 4 0 4 3 0 3 3/2 5/2 3/2 3/2 0.00000 -13372.02426-- 73. 4 0 4 3 0 3 3/2 9/2 3/2 7/2 13368.59930 0.00002 74. 4 0 4 3 0 3 3/2 11/2 3/2 9/2 13366.63300 0.00063 75. 4 1 3 3 1 2 3/2 9/2 3/2 9/2 13887.79800 -0.00262 76. 4 1 3 3 1 2 3/2 7/2 3/2 5/2 13891.24140 -0.00082 77. 4 1 3 3 1 2 3/2 9/2 3/2 7/2 13891.34250 -0.00019 78. 4 1 3 3 1 2 3/2 5/2 3/2 3/2 13892.09210 0.00099 79. 4 1 3 3 1 2 3/2 11/2 3/2 9/2 13892.21470 0.00126 80. 4 1 3 3 1 2 3/2 7/2 3/2 7/2 13892.88460 0.00076 81. 4 1 3 3 1 2 3/2 5/2 3/2 5/2 13895.67730 0.00041 82. 4 1 3 4 0 4 3/2 5/2 3/2 5/2 10960.31450 0.00115 83. 4 1 3 4 0 4 3/2 11/2 3/2 11/2 10961.80490 0.00058 84. 4 1 3 4 0 4 3/2 7/2 3/2 7/2 10964.51180 0.00076 85. 4 1 3 4 0 4 3/2 9/2 3/2 9/2 10965.98430 0.00017 86. 5 1 5 4 1 4 3/2 9/2 3/2 7/2 16133.52690 -0.00096 87. 5 1 5 4 1 4 3/2 7/2 3/2 5/2 16133.98700 0.00056 88. 5 1 5 4 1 4 3/2 11/2 3/2 9/2 16134.08710 0.00006 89. 5 1 5 4 1 4 3/2 13/2 3/2 11/2 16134.54340 0.00113 90. 5 0 5 4 0 4 3/2 9/2 3/2 7/2 16672.11790 0.00002 91. 5 0 5 4 0 4 3/2 7/2 3/2 5/2 16672.27160 0.00135 92. 5 0 5 4 0 4 3/2 11/2 3/2 9/2 16672.65920 -0.00011 93. 5 0 5 4 0 4 3/2 13/2 3/2 11/2 16672.83060 0.00028 94. 5 0 5 4 0 4 3/2 9/2 3/2 9/2 16675.13050 -0.00161 95. 5 2 4 4 2 3 3/2 11/2 3/2 9/2 16753.34780 0.00030 96. 5 2 4 4 2 3 3/2 9/2 3/2 7/2 16753.59560 0.00003 97. 5 2 4 4 2 3 3/2 13/2 3/2 11/2 16755.03680 -0.00016 98. 5 2 4 4 2 3 3/2 7/2 3/2 5/2 16755.28160 0.00163 99. 5 2 3 4 2 2 3/2 11/2 3/2 9/2 16845.27520 0.00038 100. 5 2 3 4 2 2 3/2 9/2 3/2 7/2 16845.49680 -0.00208 101. 5 2 3 4 2 2 3/2 13/2 3/2 11/2 16846.80340 0.00009 102. 5 2 3 4 2 2 3/2 7/2 3/2 5/2 16847.01910 0.00049 103. 5 1 4 4 1 3 3/2 9/2 3/2 7/2 17354.10740 0.00038 104. 5 1 4 4 1 3 3/2 11/2 3/2 9/2 17354.26980 -0.00087 105. 5 1 4 4 1 3 3/2 7/2 3/2 5/2 17354.55280 -0.00381 106. 5 1 4 4 1 3 3/2 13/2 3/2 11/2 17354.73590 0.00334 Standard deviation = 0.001777 ITERATION NO = 2 CONSTANTS, deviations and changes: A = 11361.090281699 +- 0.000478253 0.000000000 B = 1799.077321980 +- 0.000837649 0.000000003 C = 1554.416041633 +- 0.000820838 -0.000000003 DJ = 0.006086413 +- 0.000003281 0.000000000 DJK = -0.001026693 +- 0.000023402 0.000000000 dJ = 0.001029895 +- 0.000002108 0.000000000 dK = 0.041773610 +- 0.000405979 0.000000002 I1: X.aa = -33.258999702 +- 0.001915800 -0.000000009 I1: Xbb-Xcc = -21.593525998 +- 0.003452151 -0.000000002 I1: Xab = 36.212571269 +- 0.002453110 -0.000000120 FINAL RESULTS OF LEAST SQUARES FITTING PROCEDURE ================================================ FITTED CONSTANTS: A /MHz 11361.090281(478) LKKJ /mHz 0. B /MHz 1799.077321(837) 1:Xa /MHz -33.25899(191) C /MHz 1554.416041(820) 1:Xb-c/MHz -21.59352(345) DJ /kHz 6.08641(328) 1:Xab /MHz 36.21257(245) DJK /kHz -1.0266(234) 2:Xa /MHz 0. DK /kHz 0. 2:Xb-c/MHz 0. dJ /kHz 1.02989(210) 2:Xab /MHz 0. dK /kHz 41.773(405) 1:Ma /MHz 0. HJ / Hz 0. 1:Mb-c/MHz 0. HJK / Hz 0. 1:Tr /MHz 0. HKJ / Hz 0. 2:Ma /MHz 0. HK / Hz 0. 2:Mb-c/MHz 0. hJ / Hz 0. 2:Tr /MHz 0. hJK / Hz 0. Da /kHz 0. hK / Hz 0. Db-c /kHz 0. Dba /kHz 0. 1:X.bb /MHz 5.832736852086 1:X.cc /MHz 27.426262850183 CORRELATION COEFFICIENTS: A B C DJ DJK dJ dK 1:Xa A 1.0000 B -0.1571 1.0000 C 0.1415 -0.9778 1.0000 DJ -0.1206 0.8294 -0.7171 1.0000 DJK 0.1284 -0.5683 0.6235 -0.5103 1.0000 dJ -0.3724 0.1522 -0.1248 0.0675 0.0780 1.0000 dK -0.0706 0.9781 -0.9850 0.7743 -0.6356 -0.0043 1.0000 1:Xa 0.0952 -0.0525 0.0375 -0.0691 0.0227 -0.0736 -0.0296 1.0000 1:Xb-c 0.0151 -0.0109 0.0103 -0.0031 -0.0008 -0.0422 -0.0016 0.0377 1:Xab -0.1792 0.0387 0.0112 0.1291 0.0560 0.0041 0.0066 -0.0844 1:Xb-c 1:Xab 1:Xb-c 1.0000 1:Xab -0.0060 1.0000