------------------------------------------------------------------------------ Ar...ClCN, Keenan,Wozniak,Flygare - JCP 75,631(1981), some lines reassigned ------------------------------------------------------------------------------ TRANSITIONS: J K K <- J K K I F <- I F Obs Obs-Calc -1 +1 -1 +1 1. 4 0 4 3 1 3 5/2 13/2 5/2 11/2 7293.54680 -0.00322 2. 4 0 4 3 1 3 3/2 11/2 3/2 9/2 7294.25850 -0.00113 3. 4 0 4 3 1 3 3/2 9/2 5/2 7/2 7301.19100 -0.00074 4. 4 0 4 3 1 3 3/2 7/2 3/2 5/2 7306.59140 -0.00309 5. 4 0 4 3 1 3 5/2 11/2 5/2 9/2 7306.71500 -0.00100 6. 4 0 4 3 1 3 5/2 9/2 3/2 7/2 7307.25770 -0.00182 7. 1 1 1 0 0 0 1/2 1/2 1/2 1/2 7382.36540 0.00068 8. 1 1 1 0 0 0 5/2 5/2 5/2 5/2 7382.90910 0.00042 9. 1 1 1 0 0 0 3/2 3/2 3/2 3/2 7383.57040 0.00074 10. 1 1 1 0 0 0 3/2 5/2 3/2 3/2 7402.38480 0.00316 11. 1 1 1 0 0 0 5/2 7/2 5/2 5/2 7403.10150 0.00385 12. 1 1 1 0 0 0 1/2 3/2 1/2 1/2 7403.39840 0.00074 13. 1 1 1 0 0 0 3/2 1/2 3/2 3/2 7418.85240 -0.00262 14. 1 1 1 0 0 0 5/2 3/2 5/2 5/2 7418.90090 -0.00521 15. 5 1 4 5 0 5 3/2 13/2 3/2 13/2 7663.61750 0.00473 16. 5 1 4 5 0 5 5/2 13/2 5/2 13/2 7682.17780 -0.00596 17. 5 1 4 5 0 5 5/2 11/2 5/2 11/2 7683.19720 -0.00271 18. 2 1 2 1 0 1 3/2 5/2 5/2 5/2 9876.28790 -0.00416 19. 2 1 2 1 0 1 5/2 7/2 5/2 5/2 9876.49740 -0.00364 20. 2 1 2 1 0 1 3/2 5/2 3/2 3/2 9876.60200 -0.00502 21. 2 1 2 1 0 1 3/2 1/2 1/2 1/2 9883.62330 -0.00309 22. 2 1 2 1 0 1 5/2 5/2 5/2 5/2 9883.90120 -0.00334 23. 2 1 2 1 0 1 5/2 3/2 3/2 3/2 9884.24030 -0.00209 24. 2 1 2 1 0 1 3/2 5/2 3/2 5/2 9885.59220 -0.00028 25. 2 1 2 1 0 1 5/2 7/2 5/2 7/2 9886.13920 -0.00302 26. 2 1 2 1 0 1 3/2 3/2 1/2 3/2 9886.34900 -0.00345 27. 2 1 2 1 0 1 3/2 7/2 3/2 5/2 9895.75080 -0.00067 28. 2 1 2 1 0 1 3/2 7/2 5/2 7/2 9896.09420 0.00197 29. 2 1 2 1 0 1 1/2 5/2 3/2 5/2 9896.41230 -0.00052 30. 2 1 2 1 0 1 5/2 9/2 5/2 7/2 9896.58830 0.00043 31. 2 1 2 1 0 1 1/2 5/2 1/2 3/2 9896.89470 -0.00100 32. 2 1 2 1 0 1 5/2 5/2 5/2 3/2 9901.07660 -0.00147 33. 2 1 2 1 0 1 1/2 3/2 3/2 1/2 9911.46500 -0.00455 34. 2 1 2 1 0 1 5/2 1/2 5/2 3/2 9911.50380 -0.00347 35. 5 0 5 4 1 4 1/2 11/2 1/2 9/2 10478.44980 0.00070 36. 5 0 5 4 1 4 3/2 13/2 3/2 11/2 10479.13450 -0.00008 37. 5 0 5 4 1 4 3/2 7/2 3/2 5/2 10485.30920 0.00160 38. 5 0 5 4 1 4 3/2 11/2 3/2 9/2 10485.42040 0.00122 39. 5 0 5 4 1 4 5/2 9/2 5/2 7/2 10485.85100 -0.00046 40. 5 0 5 4 1 4 3/2 9/2 3/2 7/2 10488.73760 0.00274 41. 5 0 5 4 1 4 5/2 13/2 5/2 11/2 10488.82260 -0.00255 42. 5 0 5 4 1 4 5/2 11/2 5/2 9/2 10489.31860 -0.00006 43. 3 1 3 2 0 2 3/2 7/2 3/2 5/2 12213.24380 0.00233 44. 3 1 3 2 0 2 5/2 9/2 5/2 7/2 12213.72780 0.00354 45. 3 1 3 2 0 2 3/2 5/2 1/2 3/2 12213.85800 0.00283 46. 3 1 3 2 0 2 5/2 5/2 3/2 5/2 12217.21760 0.00178 47. 3 1 3 2 0 2 5/2 7/2 5/2 7/2 12217.60960 0.00202 48. 3 1 3 2 0 2 3/2 7/2 3/2 7/2 12221.50840 -0.00344 49. 3 1 3 2 0 2 5/2 9/2 5/2 9/2 12222.22990 -0.00360 50. 3 1 3 2 0 2 5/2 5/2 5/2 3/2 12223.34180 0.00623 51. 3 1 3 2 0 2 5/2 7/2 5/2 5/2 12223.56000 0.00630 52. 3 1 3 2 0 2 3/2 3/2 5/2 3/2 12223.66250 0.00533 53. 3 1 3 2 0 2 3/2 9/2 3/2 7/2 12229.75450 0.00199 54. 3 1 3 2 0 2 5/2 11/2 5/2 9/2 12230.59680 0.00143 55. 3 1 3 2 0 2 1/2 7/2 1/2 5/2 12230.83180 -0.00223 56. 3 1 3 2 0 2 5/2 3/2 5/2 3/2 12231.65070 0.00790 57. 3 1 3 2 0 2 1/2 5/2 5/2 5/2 12231.92180 0.00846 58. 3 1 3 2 0 2 5/2 3/2 3/2 3/2 12240.06690 0.00205 59. 3 1 3 2 0 2 5/2 3/2 5/2 1/2 12240.08310 0.00616 60. 3 1 3 2 0 2 1/2 5/2 3/2 3/2 12240.35510 0.00621 61. 3 1 3 2 0 2 5/2 1/2 5/2 1/2 12240.59690 0.00672 62. 5 2 3 5 1 4 3/2 13/2 3/2 13/2 12403.12700 0.00083 63. 5 2 3 5 1 4 1/2 11/2 1/2 11/2 12403.78700 -0.00335 64. 4 2 2 4 1 3 3/2 11/2 3/2 11/2 12858.88180 0.00203 65. 4 2 2 4 1 3 5/2 13/2 5/2 13/2 12859.67060 0.00432 66. 4 2 2 4 1 3 1/2 9/2 1/2 9/2 12859.81960 0.00290 67. 4 2 2 4 1 3 5/2 5/2 5/2 5/2 12863.90400 -0.00247 68. 3 2 1 3 1 2 5/2 9/2 5/2 9/2 13312.58220 -0.00100 69. 3 2 1 3 1 2 3/2 9/2 3/2 9/2 13330.91370 -0.00307 70. 3 2 1 3 1 2 5/2 11/2 5/2 11/2 13331.93520 -0.00112 71. 3 2 1 3 1 2 1/2 7/2 1/2 7/2 13332.17660 -0.00392 72. 6 0 6 5 1 5 1/2 13/2 1/2 11/2 13638.53640 0.00474 73. 2 2 0 2 1 1 3/2 7/2 3/2 7/2 13750.14010 0.00127 74. 2 2 0 2 1 1 5/2 9/2 5/2 9/2 13751.48350 0.00031 75. 2 2 0 2 1 1 1/2 5/2 1/2 5/2 13751.93060 0.00013 76. 4 1 4 3 0 3 5/2 9/2 3/2 7/2 14412.23560 -0.00293 77. 4 1 4 3 0 3 5/2 11/2 5/2 9/2 14412.86620 -0.00210 78. 4 1 4 3 0 3 3/2 7/2 3/2 5/2 14413.00250 -0.00049 79. 4 1 4 3 0 3 5/2 7/2 5/2 5/2 14418.27240 -0.00274 80. 4 1 4 3 0 3 3/2 9/2 5/2 7/2 14418.78030 -0.00382 81. 4 1 4 3 0 3 3/2 11/2 3/2 9/2 14426.80870 0.00020 82. 4 1 4 3 0 3 5/2 13/2 5/2 11/2 14427.60760 -0.00318 83. 4 1 4 3 0 3 1/2 9/2 1/2 7/2 14427.77820 -0.00340 84. 4 1 4 3 0 3 1/2 7/2 1/2 5/2 14433.49580 -0.00212 85. 2 2 1 2 1 2 3/2 5/2 1/2 5/2 14716.28400 -0.00424 86. 2 2 1 2 1 2 5/2 7/2 3/2 7/2 14716.34850 -0.00367 87. 2 2 1 2 1 2 5/2 5/2 5/2 5/2 14716.53080 -0.00148 88. 2 2 1 2 1 2 3/2 7/2 5/2 7/2 14717.19080 -0.00342 89. 2 2 1 2 1 2 1/2 5/2 3/2 5/2 14717.21340 -0.00397 90. 3 2 2 3 1 3 1/2 7/2 1/2 7/2 15217.12950 0.00465 91. 3 2 2 3 1 3 5/2 11/2 5/2 11/2 15217.23480 0.00338 92. 3 2 2 3 1 3 3/2 9/2 3/2 9/2 15217.67900 0.00422 93. 4 2 3 4 1 4 1/2 9/2 1/2 9/2 15892.37970 0.00769 94. 4 2 3 4 1 4 5/2 13/2 5/2 13/2 15892.49900 0.00474 95. 4 2 3 4 1 4 3/2 11/2 3/2 11/2 15893.13680 0.00417 96. 5 1 5 4 0 4 3/2 13/2 3/2 11/2 16521.98990 -0.00338 97. 5 1 5 4 0 4 1/2 11/2 1/2 9/2 16522.84380 -0.00276 98. 5 2 4 5 1 5 1/2 11/2 1/2 11/2 16744.26620 -0.00903 Standard deviation = 0.003770 ITERATION NO = 2 CONSTANTS, deviations and changes: A = 6152.520361755 +- 0.001103725 -0.000000035 B = 1577.090036409 +- 0.000714229 0.000000066 C = 1246.429136045 +- 0.000648762 -0.000000070 DJ = 0.009704427 +- 0.000008594 0.000000001 DJK = 0.114832607 +- 0.000048525 -0.000000005 DK = -0.066028236 +- 0.000229383 0.000000000 dJ = 0.002140012 +- 0.000005477 0.000000000 dK = 0.092174011 +- 0.000305044 0.000000036 I1: X.aa = 37.950101370 +- 0.004166358 -0.000000078 I1: Xbb-Xcc = -121.097983256 +- 0.006391237 -0.000000191 I2: X.aa = 1.641018185 +- 0.004156599 0.000000374 I2: Xbb-Xcc = -5.274024602 +- 0.006238144 0.000000097 FINAL RESULTS OF LEAST SQUARES FITTING PROCEDURE ================================================ FITTED CONSTANTS: A /MHz 6152.52036(110) LKKJ /mHz 0. B /MHz 1577.090036(714) 1:Xa /MHz 37.95010(416) C /MHz 1246.429136(648) 1:Xb-c/MHz -121.09798(639) DJ /kHz 9.70442(859) 1:Xab /MHz 21.899999999999998 DJK /kHz 114.8326(485) 2:Xa /MHz 1.64101(415) DK /kHz -66.028(229) 2:Xb-c/MHz -5.27402(623) dJ /kHz 2.14001(547) 2:Xab /MHz 0.95 dK /kHz 92.174(305) 1:Ma /MHz 0. HJ / Hz 0. 1:Mb-c/MHz 0. HJK / Hz 0. 1:Tr /MHz 0. HKJ / Hz 0. 2:Ma /MHz 0. HK / Hz 0. 2:Mb-c/MHz 0. hJ / Hz 0. 2:Tr /MHz 0. hJK / Hz 0. Da /kHz 0. hK / Hz 0. Db-c /kHz 0. Dba /kHz 0. 1:X.bb /MHz -79.524042312955 1:X.cc /MHz 41.573940942967 2:X.bb /MHz -3.457521393300 2:X.cc /MHz 1.816503208478 CORRELATION COEFFICIENTS: A B C DJ DJK DK dJ dK A 1.0000 B -0.0825 1.0000 C -0.0775 -0.7029 1.0000 DJ -0.2908 0.8887 -0.3693 1.0000 DJK 0.4125 -0.6914 0.6936 -0.5643 1.0000 DK 0.8744 0.0071 -0.3061 -0.2827 0.0459 1.0000 dJ 0.5374 0.5219 -0.3105 0.3622 -0.1026 0.5155 1.0000 dK -0.3009 0.7802 -0.8764 0.6042 -0.7992 -0.0959 0.0262 1.0000 1:Xa 0.0924 -0.0123 -0.0074 -0.0309 0.0617 0.1011 0.0646 -0.0382 1:Xb-c -0.0070 -0.1975 0.2082 -0.1575 0.1760 -0.0606 -0.1010 -0.1948 2:Xa 0.0460 -0.0270 0.0248 -0.0310 0.0444 0.0302 0.0473 -0.0544 2:Xb-c 0.0669 -0.1112 0.1050 -0.0973 0.1291 0.0356 -0.0492 -0.1269 1:Xa 1:Xb-c 2:Xa 2:Xb-c 1:Xa 1.0000 1:Xb-c 0.0988 1.0000 2:Xa -0.0502 -0.0024 1.0000 2:Xb-c 0.0096 -0.0366 -0.0491 1.0000