Pure second order Stark effect: E.level = E.o + ( A.g + B.g M^2 ) mu.g^2 E^2 Mixed order: E.level = (E1+E2)/2 +- [ (DE/2)^2 + mu.g^2 E^2 |xi|^2 M^2 ]^(1/2) = E1-DE/2+[...]^(1/2) and E2+DE/2-[...]^(1/2) for E1>E2, DE=E1-E2 * E1,E2,DE should in general be inclusive of second order Stark contributions * Asterisk denotes levels implicated in near degeneracy for which A and B are evaluated without the connecting (|Phi.Zg|) term * Sum field contributions for more than one dipole component * Dipoles in D, energies in MHz, field in V/cm * In the .INT file set mu.g to 1 (only one at a time) and STRFLG=1 ------------------------------------------------------------------------ SO2 ------------------------------------------------------------------------ A.g B.g level g -1.214082E-06 1.214082E-06 0 0 0 1 1 -5.813827E-07 -1.073520E-06 1 0 1 1 1 -2.651729E-07 1.285159E-06 1 1 0 1 1 2.394917E-06 -1.509291E-06 1 1 1 1 1 1.342888E-07 -6.606998E-09 2 2 1 1 1 -1.734391E-07 3.593255E-07 2 1 1 1 1 -2.412199E-06 1.421310E-07 2 1 2 1 1 1.211625E-07 -8.774357E-10 2 2 0 1 1 -1.860645E-06 1.810367E-08 2 0 2 1 1 ------------------------------------------------------------------------ ------------------------------------------------------------------------