Urea excited state 6 (to lf of ground state) Fri Jul 15 10:10:43 2022 -------------------------------------------------------------------------------------========= obs o-c error blends Notes o-c wt / instead of : below denotes (o-c)>3*err -------------------------------------------------------------------------------------========= ! ! State originally assigned as vib6 ! 1: 19 1 19 18 0 18 211166.0994 0.0001 0.050 2: 20 1 20 19 0 19 221997.6264 -0.0003 0.050 3: 21 1 21 20 0 20 232828.7590 -0.0325 0.050 4: 23 1 23 22 0 22 254489.9878 0.0247 0.050 5: 24 1 24 23 0 23 265319.9697 0.0350 0.050 6: 28 1 28 27 0 27 308635.3503 0.0298 0.050 7: 29 1 29 28 0 28 319463.5768 0.621 UNFITTD 319462.9548 resonance 8: 30 1 30 29 0 29 330289.9738 -0.0959 0.050 9: 31 1 31 30 0 30 341116.7307 0.0828 0.050 10: 32 1 32 31 0 31 351942.7255 0.0532 0.050 11: 33 1 33 32 0 32 362768.1723 0.0468 0.050 12: 34 1 34 33 0 33 373593.0680 0.0776 0.050 13: 35 1 35 34 0 34 384417.2871 0.0371 0.050 14: 36 1 36 35 0 35 395240.9378 0.0507 0.050 15: 38 1 38 37 0 37 416886.2275 0.0013 0.050 16: 39 1 39 38 0 38 427707.8949 0.0008 0.050 17: 40 1 40 39 0 39 438528.8583 -0.0132 0.050 18: 41 1 41 40 0 40 449349.1492 0.0071 0.050 19: 42 1 42 41 0 41 460168.6100 -0.0784 0.050 20/ 43 1 43 42 0 42 470987.3371 -0.1571 0.050 21: 44 1 44 43 0 43 481805.5033 -0.0391 0.050 22: 45 1 45 44 0 44 492622.8256 0.0091 0.050 ! 23: 18 2 17 17 1 16 210971.9785 -0.0003 0.050 24: 20 2 19 19 1 18 232634.3165 0.0201 0.050 25: 22 2 21 21 1 20 254295.1415 0.0419 0.050 26: 22 2 21 21 1 20 254295.1428 0.0431 0.050 27: 23 2 22 22 1 21 265124.9382 0.0510 0.050 28: 27 2 26 26 1 25 308439.5302 0.0074 0.050 29: 28 2 27 27 1 26 319266.9858 0.0215 0.050 30: 29 2 28 28 1 27 330093.9012 0.0175 0.050 31: 30 2 29 29 1 28 340920.2839 0.0203 0.050 32: 31 2 30 30 1 29 351746.2165 0.1301 0.050 33: 32 2 31 31 1 30 362571.3485 0.0136 0.050 34: 33 2 32 32 1 31 373395.9993 0.0076 0.050 35: 34 2 33 33 1 32 384220.1523 0.1127 0.050 36: 35 2 34 34 1 33 395043.4077 -0.0536 0.050 37: 36 2 35 35 1 34 405866.1603 -0.0796 0.050 38/ 37 2 36 36 1 35 416688.1689 -0.1891 0.050 39: 38 2 37 37 1 36 427509.7423 -0.0564 0.050 40: 39 2 38 38 1 37 438330.4512 -0.0937 0.050 41: 40 2 39 39 1 38 449150.5234 -0.0563 0.050 42: 41 2 40 40 1 39 459969.8160 -0.0701 0.050 43: 42 2 41 41 1 40 470788.4417 -0.0055 0.050 44: 43 2 42 42 1 41 481606.2719 0.0256 0.050 45/ 44 2 43 43 1 42 492423.4668 0.2004 0.050 ! 46: 17 3 15 16 2 14 210777.9179 -0.0124 0.050 47: 18 3 16 17 2 15 221608.8509 0.0182 0.050 48: 19 3 17 18 2 16 232439.4404 0.0308 0.050 49: 20 3 18 19 2 17 243269.6617 0.0283 0.050 50: 21 3 19 20 2 18 254099.5131 0.0343 0.050 51: 22 3 20 21 2 19 264928.9516 0.0287 0.050 52: 27 3 25 26 2 24 319069.4119 0.0173 0.050 53: 28 3 26 27 2 25 329896.0468 0.0436 0.050 54: 29 3 27 28 2 26 340722.1884 0.1154 0.050 55: 30 3 28 29 2 27 351547.5516 -0.0342 0.050 56: 32 3 30 31 2 29 373196.9048 0.0353 0.050 57: 33 3 31 32 2 30 384020.6082 0.0034 0.050 58: 34 3 32 33 2 31 394843.7231 0.0111 0.050 59: 36 3 34 35 2 33 416487.8690 -0.1041 0.050 60: 37 3 35 36 2 34 427309.0214 -0.0709 0.050 61: 38 3 36 37 2 35 438129.4550 -0.0591 0.050 62: 39 3 37 38 2 36 448949.2066 -0.0148 0.050 63: 40 3 38 39 2 37 459768.2433 0.0462 0.050 64: 41 3 39 40 2 38 470586.4597 0.0356 0.050 65: 42 3 40 41 2 39 481404.0101 0.1248 0.050 ! 66: 16 4 13 15 3 12 210586.6530 0.0647 0.050 67: 17 4 14 16 3 13 221416.4098 0.0180 0.050 68: 18 4 15 17 3 14 232246.0540 0.0140 0.050 69: 19 4 16 18 3 15 243075.4727 0.0158 0.050 70: 20 4 17 19 3 16 253904.6026 0.0176 0.050 71: 21 4 18 20 3 17 264733.3966 0.0182 0.050 72: 26 4 23 25 3 22 318871.1549 -0.0061 0.050 73: 27 4 24 26 3 23 329697.3238 0.0287 0.050 74: 28 4 25 27 3 24 340522.9484 0.0467 0.050 75: 29 4 26 28 3 25 351347.9949 0.0346 0.050 76/ 30 4 27 29 3 26 362172.8315 0.3804 0.050 77/ 31 4 28 30 3 27 372996.0123 -0.3422 0.050 78: 33 4 30 32 3 29 394642.2186 -0.1052 0.050 79: 34 4 31 33 3 30 405464.2889 -0.0637 0.050 80/ 35 4 32 34 3 31 416285.4962 -0.2236 0.050 81: 36 4 33 35 3 32 427106.3447 -0.0627 0.050 82: 37 4 34 36 3 33 437926.3723 -0.0252 0.050 83: 38 4 35 37 3 34 448745.6706 -0.0020 0.050 84: 39 4 36 38 3 35 459564.1955 -0.0193 0.050 85: 40 4 37 39 3 36 470382.0107 0.0035 0.050 ! 86: 15 5 11 14 4 10 210404.4685 0.0892 0.050 87: 16 5 12 15 4 11 221231.0125 0.0366 0.050 88: 17 5 13 16 4 12 232058.1610 -0.0028 0.050 89: 18 5 14 17 4 13 242885.6286 0.0057 0.050 90: 19 5 15 18 4 14 253713.1656 0.0232 0.050 91: 20 5 16 19 4 15 264540.5940 0.0169 0.050 92: 28 5 24 27 4 23 351148.2679 0.0248 0.050 93: 29 5 25 28 4 24 361972.1038 0.0166 0.050 94: 33 5 29 32 4 28 405261.5901 0.0179 0.050 95: 34 5 30 33 4 29 416082.3648 0.0015 0.050 96: 35 5 31 34 4 30 426902.3785 -0.1034 0.050 97: 36 5 32 35 4 31 437721.7947 -0.1141 0.050 98: 37 5 33 36 4 32 448540.5955 -0.0297 0.050 99: 39 5 35 38 4 34 470175.8599 0.0084 0.050 100: 40 5 36 39 4 35 480992.3614 0.0364 0.050 101/ 41 5 37 40 4 36 491808.2331 0.2183 0.050 ! 102: 14 6 9 13 5 8 210250.5874 -0.1034 0.050 103: 15 6 10 14 5 9 221066.0892 -0.0021 0.050 104: 16 6 11 15 5 10 231885.6288 -0.0071 0.050 105: 17 6 12 16 5 11 242707.5957 0.0067 0.050 106: 18 6 13 17 5 12 253530.9856 0.0161 0.050 107: 19 6 14 18 5 13 264355.2092 0.0309 0.050 108: 25 6 20 24 5 19 329302.8686 0.0733 0.050 109: 26 6 21 25 5 20 340126.6444 0.0787 0.050 110: 27 6 22 26 5 21 350949.9168 0.0087 0.050 111: 28 6 23 27 5 22 361772.7950 0.0165 0.050 112: 29 6 24 28 5 23 372595.1345 -0.0044 0.050 113: 30 6 25 29 5 24 383416.9476 -0.0084 0.050 114: 34 6 29 33 5 28 426698.0926 -0.1279 0.050 115: 35 6 30 34 5 29 437516.9068 -0.0034 0.050 116: 36 6 31 35 5 30 448334.9786 0.0745 0.050 117: 37 6 32 36 5 31 459152.2049 0.0243 0.050 118: 38 6 33 37 5 32 469968.7157 -0.0038 0.050 ! 119: 14 6 8 13 7 7 220966.0798 -0.0176 0.050 120: 14 7 8 13 6 7 220969.6322 -0.0499 0.050 121: 15 6 9 14 7 8 231758.2605 0.2260 0.050 0.0513 0.50 122: 15 7 9 14 6 8 231758.2605 -0.1234 0.050 0.0513 0.50 123: 16 6 10 15 7 9 242561.6466 -0.0247 0.050 -0.0403 0.50 124: 16 7 10 15 6 9 242561.6466 -0.0558 0.050 -0.0403 0.50 125: 17 7 11 16 6 10 253372.6177 0.0053 0.050 126: 18 7 12 17 6 11 264187.9846 0.0020 0.050 127: 24 7 18 23 6 17 329111.9260 0.0458 0.050 128: 25 7 19 24 6 18 339933.6853 0.0176 0.050 129: 26 7 20 25 6 19 350755.2375 -0.0224 0.050 130: 27 7 21 26 6 20 361576.6033 0.0414 0.050 131: 28 7 22 27 6 21 372397.3978 -0.0997 0.050 132: 29 7 23 28 6 22 383218.0139 0.0095 0.050 133: 30 7 24 29 6 23 394038.0274 -0.0026 0.050 134: 32 7 26 31 6 25 415676.4453 -0.0188 0.050 135: 35 7 29 34 6 28 448129.5838 0.0413 0.050 136: 36 7 30 35 6 29 458945.8909 -0.0058 0.050 137: 37 7 31 36 6 30 469761.6104 0.0721 0.050 138: 38 7 32 37 6 31 480576.5008 0.0574 0.050 0.0574 0.50 139: 38 7 32 37 6 31 480576.5008 0.0574 0.050 0.0574 0.50 140: 39 7 33 38 6 32 491390.6498 0.0606 0.050 ! ! resonances at J"=14,27,33-34 ! 141: 12 8 5 11 7 4 212405.2876 0.0586 0.050 142: 13 7 6 12 8 5 220866.9583 -0.1275 0.050 143: 13 8 6 12 7 5 221477.6063 0.0472 0.050 144: 14 7 7 13 8 6 231752.7047 -0.0310 0.050 145: 14 8 7 13 7 6 231840.4353 -0.0640 0.050 146: 15 8 8 14 7 7 242523.1796 0.0085 0.050 147: 15 7 8 14 8 7 242512.4778 -0.0427 0.050 148: 16 8 9 15 7 8 253282.7344 -0.0021 0.050 149: 16 7 9 15 8 8 253281.6309 0.0346 0.050 150: 17 8 10 16 7 9 264068.5998 -0.0201 0.050 0.0352 0.50 151: 17 7 10 16 8 9 264068.5998 0.0905 0.050 0.0352 0.50 152: 23 8 16 22 7 15 328931.9737 0.0433 0.050 153: 24 8 17 23 7 16 339749.8579 -0.0263 0.050 154: 25 8 18 24 7 17 350568.3331 0.0740 0.050 155: 26 8 19 25 7 18 361386.8019 -0.0062 0.050 156: 29 8 22 28 7 21 393841.8309 -0.0290 0.050 157: 30 8 23 29 7 22 404659.6262 -0.0072 0.050 158: 31 8 24 30 7 23 415476.9863 0.0040 0.050 159: 32 8 25 31 7 24 426293.7619 -0.0835 0.050 160: 36 8 29 35 7 28 469555.4951 0.0016 0.050 161: 37 8 30 36 7 29 480369.2614 -0.0019 0.050 162: 38 8 31 37 7 30 491182.3236 0.0109 0.050 ! ! resonances at J"=10-20,27-28,34-35 ! 163/ 11 9 3 10 8 2 225260.9618 -0.2361 0.050 164: 12 9 4 11 8 3 230833.1395 -0.1412 0.050 165/ 13 8 5 12 9 4 229623.1328 -0.2375 0.050 166: 13 9 5 12 8 4 235754.7470 0.0704 0.050 167/ 14 8 6 13 9 5 242281.9206 -0.1652 0.050 168: 14 9 6 13 8 5 243606.9437 0.0452 0.050 169: 15 8 7 14 9 6 253334.9043 -0.0346 0.050 170: 15 9 7 14 8 6 253549.8556 0.0087 0.050 171: 16 8 8 15 9 7 264085.2364 -0.0561 0.050 172: 16 9 8 15 8 7 264114.1442 -0.0355 0.050 173: 21 9 13 20 8 12 317968.4430 0.0778 0.050 174: 22 9 14 21 8 13 328774.8776 0.0112 0.050 175: 23 9 15 22 8 14 339584.5703 0.0050 0.050 176: 24 9 16 23 8 15 350396.3522 -0.0416 0.050 177: 25 9 17 24 8 16 361209.6348 0.0080 0.050 178: 26 9 18 25 8 17 372023.7438 -0.0116 0.050 179: 27 9 19 26 8 18 382838.4382 0.0249 0.050 180: 28 9 20 27 8 19 393653.2299 -0.0989 0.050 181: 29 9 21 28 8 20 404468.2416 -0.0551 0.050 182: 30 9 22 29 8 21 415283.0963 -0.0613 0.050 183: 31 9 23 30 8 22 426097.7653 -0.0205 0.050 184: 32 9 24 31 8 23 436912.1291 0.0490 0.050 185: 33 9 25 32 8 24 447725.9320 -0.0248 0.050 186: 34 9 26 33 8 25 458539.3602 0.0136 0.050 187: 37 9 29 36 8 28 490976.1593 0.1199 0.050 ! ! resonance(s) beyond J"=28 ! 188: 11 10 2 10 9 1 238029.3344 -0.1167 0.050 189: 13 10 4 12 9 3 256067.2272 0.0531 0.050 190/ 14 10 5 13 9 4 259891.5923 0.3113 0.050 191/ 15 10 6 14 9 5 266163.7672 0.2196 0.050 192: 21 9 12 20 10 11 328668.8323 0.0094 0.050 0.0041 0.50 193: 21 10 12 20 9 11 328668.8323 -0.0012 0.050 0.0041 0.50 194: 22 10 13 21 9 12 339458.4226 -0.0108 0.050 195: 23 10 14 22 9 13 350255.3469 -0.0167 0.050 196: 24 10 15 23 9 14 361057.1881 -0.0165 0.050 197: 25 10 16 24 9 15 371862.3650 -0.0204 0.050 198: 26 10 17 25 9 16 382669.8469 0.0001 0.050 199: 27 10 18 26 9 17 393478.8489 -0.0015 0.050 200: 28 10 19 27 9 18 404288.8218 -0.0461 0.050 201: 29 10 20 28 9 19 415099.5273 0.0157 0.050 202: 31 10 22 30 9 21 436721.6152 0.0364 0.050 203: 32 10 23 31 9 22 447532.5584 -0.0460 0.050 204: 33 10 24 32 9 23 458343.3771 -0.0501 0.050 205: 35 10 26 34 9 25 479964.1319 0.0983 0.050 ! ! resonances in region J"=29-31 ! 206: 12 11 2 11 10 1 260988.2652 -0.0020 0.050 207: 20 11 10 19 10 9 328693.7661 -0.1135 0.050 208: 20 10 10 19 11 9 328690.9836 0.0345 0.050 209: 21 10 11 20 11 10 339424.4694 0.1897 0.050 0.0257 0.50 210: 21 11 11 20 10 10 339424.4694 -0.1384 0.050 0.0257 0.50 211: 22 10 12 21 11 11 350182.4368 0.0276 0.050 0.0107 0.50 212: 22 11 12 21 10 11 350182.4368 -0.0062 0.050 0.0107 0.50 213: 23 10 13 22 11 12 360956.6752 -0.0120 0.050 -0.0137 0.50 214: 23 11 13 22 10 12 360956.6752 -0.0153 0.050 -0.0137 0.50 215: 24 11 14 23 10 13 371741.6042 0.0001 0.050 216: 25 11 15 24 10 14 382533.6772 -0.0227 0.050 217: 26 11 16 25 10 15 393330.6866 -0.0492 0.050 218: 27 11 17 26 10 16 404131.2172 0.0086 0.050 219: 28 11 18 27 10 17 414934.0731 -0.0040 0.050 220: 29 11 19 28 10 18 425738.5896 -0.0111 0.050 221: 30 11 20 29 10 19 436544.1438 -0.0944 0.050 222: 31 11 21 30 10 20 447350.5309 -0.0554 0.050 223: 33 11 23 32 10 22 468964.2313 -0.0227 0.050 224: 34 11 24 33 10 23 479771.1655 0.0181 0.050 225: 35 11 25 34 10 24 490577.7807 -0.0859 0.050 ! ! initially problematic beyond J"=29 ! 226: 20 12 9 19 11 8 339679.3328 0.0763 0.050 227: 21 11 10 20 12 9 350279.0278 0.0285 0.050 228: 21 12 10 20 11 9 350286.6705 0.0722 0.050 229: 22 11 11 21 12 10 360977.4005 -0.1359 0.050 230: 22 12 11 21 11 10 360978.4849 0.0354 0.050 231: 23 11 12 22 12 11 371710.0697 0.0839 0.050 0.0336 0.50 232: 23 12 12 22 11 11 371710.0697 -0.0167 0.050 0.0336 0.50 233: 24 11 13 23 12 12 382465.0280 -0.0156 0.050 -0.0208 0.50 234: 24 12 13 23 11 12 382465.0280 -0.0259 0.050 -0.0208 0.50 235: 25 12 14 24 11 13 393235.0635 0.0012 0.050 236: 26 12 15 25 11 14 404015.1718 -0.0341 0.050 237: 27 12 16 26 11 15 414802.3898 0.0296 0.050 238: 28 12 17 27 11 16 425594.5066 0.0628 0.050 239: 29 12 18 28 11 17 436390.0144 -0.0093 0.050 240: 30 12 19 29 11 18 447188.0914 0.0065 0.050 241: 31 12 20 30 11 19 457987.8183 -0.0713 0.050 242: 32 12 21 31 11 20 468788.8680 -0.0232 0.050 243: 33 12 22 32 11 21 479590.6829 0.0072 0.050 244: 34 12 23 33 11 22 490392.9896 0.0662 0.050 245: 21 12 9 20 13 8 361283.5268 -0.1339 0.050 ! ! subsequences disappear below J"=20 ! 246: 21 13 9 20 12 8 361412.9601 0.0408 0.050 247: 22 13 10 21 12 9 371916.2563 -0.0033 0.050 248: 22 12 10 21 13 9 371897.6674 0.0214 0.050 249: 23 13 11 22 12 10 382556.3374 0.0434 0.050 250: 24 12 12 23 13 11 393254.4757 0.0856 0.050 -0.0551 0.50 251: 24 13 12 23 12 11 393254.4757 -0.1959 0.050 -0.0551 0.50 252: 25 12 13 24 13 12 403985.7323 0.0981 0.050 0.0828 0.50 253: 25 13 13 24 12 12 403985.7323 0.0674 0.050 0.0828 0.50 254: 26 13 14 25 12 13 414737.3481 -0.0239 0.050 255: 27 13 15 26 12 14 425503.0061 0.0101 0.050 256: 28 13 16 27 12 15 436278.2533 -0.0120 0.050 257: 29 13 17 28 12 16 447060.3326 -0.0240 0.050 258: 30 13 18 29 12 17 457847.3401 0.0036 0.050 259: 31 13 19 30 12 18 468637.7961 -0.0451 0.050 260: 32 13 20 31 12 19 479430.8825 -0.0034 0.050 261: 33 13 21 32 12 20 490225.7412 -0.0013 0.050 ! 262/ 22 13 9 21 14 8 382969.4164 -0.1709 0.050 263: 23 14 10 22 13 9 393593.7158 0.1179 0.050 264: 23 13 10 22 14 9 393550.2414 -0.0572 0.050 265: 24 14 11 23 13 10 404163.4181 0.0562 0.050 266: 24 13 11 23 14 10 404157.4359 0.0414 0.050 267: 25 14 12 24 13 11 414819.6613 0.1294 0.050 268: 25 13 12 24 14 11 414818.8260 0.0405 0.050 269: 26 13 13 25 14 12 425520.8812 0.0461 0.050 0.0030 0.50 270: 26 14 13 25 13 12 425520.8812 -0.0400 0.050 0.0030 0.50 271: 27 14 14 26 13 13 436250.4139 0.0687 0.050 0.0734 0.50 272: 27 13 14 26 14 13 436250.4139 0.0780 0.050 0.0734 0.50 273: 28 14 15 27 13 14 446998.4711 -0.0026 0.050 274: 29 14 16 28 13 15 457759.5696 0.0125 0.050 275: 30 14 17 29 13 16 468529.9125 0.0841 0.050 276: 31 14 18 30 13 17 479306.7066 -0.0164 0.050 277: 32 14 19 31 13 18 490088.5036 0.0621 0.050 ! ! R-branches better seen as Kc sequences ! 278/ 10 10 1 9 9 0 221512.8823 -0.2255 0.050 279: 10 10 0 9 9 1 221723.4511 -0.0824 0.050 280/ 11 11 1 10 10 0 243944.8374 -0.2413 0.050 281/ 11 11 0 10 10 1 244053.3328 -0.2608 0.050 282/ 12 12 1 11 11 0 266348.9873 -0.1857 0.050 283: 12 12 0 11 11 1 266404.1079 -0.1384 0.050 284: 14 14 0 13 13 1 311127.0944 -0.0856 0.050 285: 15 15 1 14 14 0 333482.9722 -0.0241 0.050 286: 15 15 0 14 14 1 333489.6546 -0.0537 0.050 287: 16 16 0 15 15 1 355849.9636 0.0906 0.050 288: 16 16 1 15 15 0 355846.7157 0.1122 0.050 289/ 17 17 1 16 16 0 378205.1671 0.1767 0.050 290: 17 17 0 16 16 1 378206.7135 0.1414 0.050 ! ! Q-branch lines ! 291/ 21 2 20 21 1 21 218078.1374 0.2723 0.050 292/ 22 3 20 22 2 21 218002.8598 0.3471 0.050 293/ 23 4 20 23 3 21 217919.5252 0.1972 0.050 294: 24 5 20 24 4 21 217827.7667 0.0529 0.050 295: 25 6 20 25 5 21 217726.8977 -0.1459 0.050 296: 26 7 20 26 6 21 217616.6959 0.0354 0.050 297: 29 10 20 29 9 21 217220.1138 -0.0734 0.050 298: 30 11 20 30 10 21 217063.6426 -0.0958 0.050 299: 31 12 20 31 11 21 216893.6854 -0.1109 0.050 300: 32 13 20 32 12 21 216709.3729 -0.1222 0.050 301: 33 14 20 33 13 21 216509.8732 -0.0545 0.050 302: 34 15 20 34 14 21 216294.0900 -0.0530 0.050 303: 35 16 20 35 15 21 216061.0121 -0.1316 0.050 304: 36 17 20 36 16 21 215809.8111 -0.0709 0.050 305: 37 18 20 37 17 21 215539.1961 -0.0614 0.050 ! 306/ 23 2 21 23 1 22 228635.7375 0.1681 0.050 307/ 24 3 21 24 2 22 228550.3618 0.1569 0.050 308/ 25 4 21 25 3 22 228456.9269 0.1715 0.050 309: 26 5 21 26 4 22 228354.7025 0.0469 0.050 310: 27 6 21 27 5 22 228243.3034 -0.0108 0.050 311: 28 7 21 28 6 22 228122.0708 -0.0425 0.050 312: 29 8 21 29 7 22 227990.3367 -0.0699 0.050 313: 30 9 21 30 8 22 227847.4046 -0.1146 0.050 314: 31 10 21 31 9 22 227692.6680 -0.0779 0.050 315: 32 12 21 32 11 22 227525.2327 -0.1173 0.050 316: 34 13 21 34 12 22 227149.4785 -0.0990 0.050 317: 35 14 21 35 13 22 226939.5042 -0.0512 0.050 318: 36 15 21 36 14 22 226713.5848 -0.0309 0.050 319: 37 16 21 37 15 22 226470.8361 -0.0010 0.050 320: 38 17 21 38 16 22 226210.2278 -0.0262 0.050 321: 39 18 21 39 17 22 225930.8329 -0.0209 0.050 322: 40 19 21 40 18 22 225631.4449 -0.1278 0.050 ! 323/ 23 1 22 23 0 23 239348.5551 0.2424 0.050 324/ 24 2 22 24 1 23 239268.1338 0.2843 0.050 325/ 25 3 22 25 2 23 239180.2509 0.1595 0.050 326: 26 4 22 26 3 23 239084.6274 0.0794 0.050 327: 27 5 22 27 4 23 238980.7478 0.0408 0.050 328: 28 6 22 28 5 23 238867.9913 -0.0420 0.050 329: 29 7 22 29 6 23 238745.8638 -0.1051 0.050 330: 30 8 22 30 7 23 238613.8658 -0.0651 0.050 331: 31 9 22 31 8 23 238471.2357 -0.0764 0.050 332: 32 10 22 32 9 23 238317.4081 -0.0710 0.050 333: 33 11 22 33 10 23 238151.6946 -0.0770 0.050 334: 34 12 22 34 11 23 237973.4746 -0.0265 0.050 335: 35 13 22 35 12 23 237781.8782 -0.0712 0.050 336: 36 14 22 36 13 23 237576.4183 0.0508 0.050 337: 37 15 22 37 14 23 237356.0890 0.1160 0.050 338/ 38 16 22 38 15 23 237120.1261 0.1769 0.050 339/ 39 17 22 39 16 23 236867.6766 0.2342 0.050 340/ 40 18 22 40 17 23 236597.8615 0.3020 0.050 341/ 41 19 22 41 18 23 236309.7837 0.4182 0.050 ! 342: 27 4 24 27 3 25 260437.0028 0.1155 0.050 343: 28 5 24 28 4 25 260336.4810 0.0300 0.050 344: 29 6 24 29 5 25 260228.2843 -0.0099 0.050 345: 30 7 24 30 6 25 260111.9114 -0.0615 0.050 346: 31 8 24 31 7 25 259986.9357 -0.0890 0.050 347: 32 9 24 32 8 25 259852.9400 -0.0292 0.050 348: 33 10 24 33 9 25 259709.1931 -0.1137 0.050 349: 34 11 24 34 10 25 259555.4011 -0.1175 0.050 350: 35 12 24 35 11 25 259390.9293 -0.1357 0.050 351: 36 13 24 36 12 25 259215.3312 -0.0544 0.050 352: 37 14 24 37 13 25 259027.9384 0.0407 0.050 353: 38 15 24 38 14 25 258828.0222 0.0264 0.050 354: 39 16 24 39 15 25 258615.0710 0.0206 0.050 355: 40 17 24 40 16 25 258388.4001 -0.0062 0.050 356: 41 18 24 41 17 25 258147.4929 0.1105 0.050 357: 42 19 24 42 18 25 257891.2725 0.0041 0.050 358: 43 20 24 43 19 25 257619.3011 -0.0240 0.050 359: 44 21 24 44 20 25 257330.6447 -0.1366 0.050 ! 360: 35 4 32 35 3 33 345422.9825 -0.0741 0.050 361: 36 5 32 36 4 33 345295.1198 -0.0678 0.050 362: 38 7 32 38 6 33 345019.7294 -0.1243 0.050 363: 39 8 32 39 7 33 344871.7895 -0.1066 0.050 364/ 40 9 32 40 8 33 344716.5470 -0.1899 0.050 365/ 41 10 32 41 9 33 344553.9008 -0.2096 0.050 366: 42 11 32 42 10 33 344383.6621 -0.0812 0.050 367: 43 12 32 43 11 33 344205.4297 0.0762 0.050 368: 44 13 32 44 12 33 344018.7716 0.1206 0.050 369: 45 14 32 45 13 33 343823.4538 0.1168 0.050 370: 46 15 32 46 14 33 343619.1768 0.0729 0.050 371/ 47 16 32 47 15 33 343406.0008 0.3658 0.050 ! 372: 36 3 33 36 2 34 356041.5537 0.0627 0.050 373: 37 4 33 37 3 34 355909.3803 -0.0350 0.050 374: 38 5 33 38 4 34 355770.9911 0.0162 0.050 375: 40 7 33 40 6 34 355473.9987 -0.0834 0.050 376: 41 8 33 41 7 34 355315.0612 -0.0925 0.050 377: 43 10 33 43 9 34 354975.1389 0.0489 0.050 378: 44 11 33 44 10 34 354793.4044 -0.0308 0.050 379: 45 12 33 45 11 34 354603.6879 0.0144 0.050 380: 46 13 33 46 12 34 354405.4510 -0.0748 0.050 381: 48 15 33 48 14 34 353982.9452 0.0277 0.050 382: 49 16 33 49 15 34 353757.8495 -0.0086 0.050 383: 50 17 33 50 16 34 353523.0974 -0.1180 0.050 ! 384: 37 3 34 37 2 35 366658.8791 0.0830 0.050 385: 38 4 34 38 3 35 366522.4756 0.1207 0.050 386: 39 5 34 39 4 35 366379.6220 -0.0024 0.050 387: 41 7 34 41 6 35 366074.5136 0.0805 0.050 388: 42 8 34 42 7 35 365911.3906 -0.1345 0.050 389: 43 9 34 43 8 35 365741.2861 -0.1475 0.050 390: 45 11 34 45 10 35 365378.7182 -0.0154 0.050 391: 47 13 34 47 12 35 364984.3417 0.0096 0.050 392: 48 14 34 48 13 35 364774.5842 -0.0025 0.050 -------------------------------------------------------------------------------------========= 1 Lines rejected from fit PARAMETERS IN FIT (values truncated and Nlines statistics): 10000 A_6 /MHz 11196.24497(99) 1 20000 B /MHz 10317.8057(11) 2 30000 C /MHz 5417.55118(35) 3 200 DJ /kHz 10.4786(16) 4 1100 DJK /kHz -19.6266(95) 5 2000 DK /kHz 9.8858(81) 6 40100 dJ /kHz -0.3356(12) 7 41000 dK /kHz 11.676(42) 8 300 HJ /Hz 0.00089(20) 9 1200 HJK /Hz [ 0.] 10 2100 HKJ /Hz 0.04511(82) 11 3000 HK /Hz -0.04446(74) 12 40200 hJ /Hz [ 0.] 13 41100 hJK /Hz [ 0.] 14 42000 hK /Hz [ 0.] 15 MICROWAVE AVG = -0.000147 MHz, IR AVG = 0.00000 MICROWAVE RMS = 0.094178 MHz, IR RMS = 0.00000 END OF ITERATION 1 OLD, NEW RMS ERROR= 1.88357 1.88357 distinct frequency lines in fit: 377 distinct parameters of fit: 11 lines rejected from fit: 1 (ERRTST = 1.00E+01) upper state lower state overall limits of quantum number 1: 10 50 9 50 9 50 limits of quantum number 2: 1 21 0 20 0 21 limits of quantum number 3: 0 45 0 44 0 45 frequency range: 210250 492622 PARAMETERS IN FIT WITH STANDARD ERRORS ON THOSE THAT ARE FITTED: (values rounded and degrees of freedom, Ndegf=Nlines-Nconst, statistics) 10000 A_6 /MHz 11196.2450(19) 1 20000 B /MHz 10317.8057(20) 2 30000 C /MHz 5417.55118(67) 3 200 DJ /kHz 10.4786(30) 4 1100 DJK /kHz -19.627(18) 5 2000 DK /kHz 9.886(15) 6 40100 dJ /kHz -0.3356(22) 7 41000 dK /kHz 11.676(80) 8 300 HJ /Hz 0.00090(37) 9 1200 HJK /Hz [ 0.] 10 2100 HKJ /Hz 0.0451(16) 11 3000 HK /Hz -0.0445(14) 12 40200 hJ /Hz [ 0.] 13 41100 hJK /Hz [ 0.] 14 42000 hK /Hz [ 0.] 15 ------------------------------------------------------------------------------------------ Worst fitted parameters, with greater than 20% uncertainty: % 300 HJ /Hz 0.00090(37) 9 41.4 ------------------------------------------------------------------------------------------ CORRELATION COEFFICIENTS, C.ij: A_6 B C -DJ -DJK -DK -dJ -dK A_6 1.0000 B -0.4709 1.0000 C -0.0255 0.4771 1.0000 -DJ 0.2569 -0.6421 -0.2825 1.0000 -DJK -0.5437 0.5376 0.1094 -0.9129 1.0000 -DK 0.5893 -0.5178 -0.1138 0.8831 -0.9969 1.0000 -dJ 0.8815 -0.6127 -0.1375 0.3340 -0.5542 0.5890 1.0000 -dK 0.6072 -0.5456 -0.1282 0.8807 -0.9944 0.9977 0.6208 1.0000 HJ 0.5231 0.3280 0.4851 -0.1109 -0.2744 0.3273 0.3103 0.3114 HKJ -0.7191 0.4265 0.1954 -0.6299 0.8337 -0.8639 -0.7036 -0.8815 HK 0.6575 -0.5466 -0.2365 0.7278 -0.8620 0.8774 0.6957 0.9021 HJ HKJ HK HJ 1.0000 HKJ -0.4653 1.0000 HK 0.2864 -0.9733 1.0000 Mean value of |C.ij|, i.ne.j = 0.5527 Mean value of C.ij, i.ne.j = 0.0165 Worst correlations, with absolute value greater than 0.9950: 2000 -DK <-> 1100 -DJK -0.996919 41000 -dK <-> 2000 -DK 0.997694 Worst fitted lines (obs-calc/error): 341: 8.4 76: 7.6 371: 7.3 292: 6.9 77: -6.8 190: 6.2 340: 6.0 324: 5.7 291: 5.4 281: -5.2 323: 4.8 280: -4.8 165: -4.7 163: -4.7 339: 4.7 278: -4.5 80: -4.5 191: 4.4 101: 4.4 365: -4.2 45: 4.0 293: 3.9 364: -3.8 38: -3.8 282: -3.7 338: 3.5 289: 3.5 308: 3.4 262: -3.4 306: 3.4 167: -3.3 325: 3.2 20: -3.1 307: 3.1 389: -2.9 295: -2.9 290: 2.8 164: -2.8 283: -2.8 359: -2.7 229: -2.7 350: -2.7 388: -2.7 245: -2.7 303: -2.6 32: 2.6 267: 2.6 114: -2.6 322: -2.6 142: -2.5 341/ 41 19 22 41 18 23 236309.7837 0.4182 0.050 76/ 30 4 27 29 3 26 362172.8315 0.3804 0.050 371/ 47 16 32 47 15 33 343406.0008 0.3658 0.050 292/ 22 3 20 22 2 21 218002.8598 0.3471 0.050 77/ 31 4 28 30 3 27 372996.0123 -0.3422 0.050 190/ 14 10 5 13 9 4 259891.5923 0.3113 0.050 340/ 40 18 22 40 17 23 236597.8615 0.3020 0.050 324/ 24 2 22 24 1 23 239268.1338 0.2843 0.050 291/ 21 2 20 21 1 21 218078.1374 0.2723 0.050 281/ 11 11 0 10 10 1 244053.3328 -0.2608 0.050 _____________________________________ __________________________________________/ SPFIT output reformatted with PIFORM