2-aminopyridine...water Fri Sep 17 17:14:51 2021 -------------------------------------------------------------------------------------========= obs o-c error blends Notes o-c wt / instead of : below denotes (o-c)>3*err -------------------------------------------------------------------------------------========= ! 1: 2 0 2 2 3 1 0 1 2 2 4749.4884 0.0039 0.002 2: 2 0 2 2 4 1 0 1 2 3 4749.6075 0.0018 0.002 0.0010 0.64 3: 2 0 2 0 2 1 0 1 0 1 4749.6075 -0.0005 0.002 0.0010 0.36 4: 2 0 2 1 3 1 0 1 1 2 4749.8401 0.0022 0.002 ! 5: 3 1 3 1 3 2 1 2 1 2 6602.2743 0.0010 0.002 6: 3 1 3 1 2 2 1 2 1 1 6602.4091 0.0005 0.002 7: 3 1 3 2 4 2 1 2 2 3 6602.3590 0.0009 0.002 8: 3 1 3 2 3 2 1 2 2 2 6602.0157 0.0015 0.002 9: 3 1 3 2 5 2 1 2 2 4 6602.0906 0.0021 0.002 -0.0029 0.62 10: 3 1 3 0 3 2 1 2 0 2 6602.0906 -0.0110 0.002 -0.0029 0.38 ! 11: 3 0 3 2 3 2 0 2 1 3 7023.2959 0.0013 0.002 12: 3 0 3 1 3 2 0 2 1 2 7024.4677 0.0015 0.002 13: 3 0 3 2 4 2 0 2 2 4 7023.6000 -0.0002 0.002 14: 3 0 3 1 2 2 0 2 2 2 7024.1486 0.0011 0.002 15: 3 0 3 2 5 2 0 2 2 4 7024.6601 0.0005 0.002 16: 3 0 3 0 3 2 0 2 0 2 7024.6935 -0.0036 0.002 17: 3 0 3 2 2 2 0 2 1 2 7025.1880 -0.0004 0.002 18: 3 0 3 1 4 2 0 2 2 4 7025.6503 0.0003 0.002 19: 3 0 3 2 1 2 0 2 1 1 7025.9804 -0.0014 0.002 20: 3 0 3 1 3 2 0 2 2 3 7026.2588 -0.0005 0.002 ! 21: 3 2 2 2 2 2 2 1 1 1 7184.9974 -0.0033 0.002 22: 3 2 2 2 4 2 2 1 2 3 7185.2360 -0.0001 0.002 23: 3 2 2 2 5 2 2 1 2 4 7186.2372 0.0004 0.002 24/ 3 2 2 2 4 2 2 1 1 3 7186.8411 0.0065 0.002 25: 3 2 2 1 3 2 2 1 1 2 7186.9756 -0.0007 0.002 26: 3 2 2 1 2 2 2 1 2 1 7187.2958 0.0008 0.002 ! 27: 3 1 3 2 4 2 0 2 1 3 8609.3613 0.0005 0.002 28/ 3 1 3 2 2 2 0 2 1 1 8608.4776 -0.0068 0.002 29: 3 1 3 2 5 2 0 2 2 4 8608.5518 0.0010 0.002 ! 30: 4 1 4 1 4 3 1 3 1 3 8761.0545 -0.0011 0.002 31: 4 1 4 1 5 3 1 3 1 4 8760.7827 0.0018 0.002 32: 4 1 4 2 2 3 1 3 2 1 8760.9791 -0.0016 0.002 ! 33: 4 0 4 2 6 3 0 3 2 5 9196.7805 0.0022 0.002 34: 4 0 4 0 4 3 0 3 0 3 9196.8389 -0.0003 0.002 35: 4 0 4 1 4 3 0 3 2 3 9196.9149 0.0015 0.002 36: 4 0 4 1 3 3 0 3 2 2 9196.9926 0.0012 0.002 37: 4 0 4 2 5 3 0 3 1 4 9197.0600 -0.0002 0.002 38: 4 0 4 2 4 3 0 3 2 4 9198.4162 0.0000 0.002 ! 39: 4 1 3 1 3 3 1 2 1 3 10235.2587 -0.0006 0.002 40: 4 1 3 2 5 3 1 2 2 5 10235.3219 -0.0011 0.002 41: 4 1 3 2 5 3 1 2 1 4 10235.7385 0.0006 0.002 42: 4 1 3 2 4 3 1 2 2 4 10235.8256 -0.0018 0.002 43: 4 1 3 1 3 3 1 2 1 2 10236.0991 0.0000 0.002 44: 4 1 3 2 5 3 1 2 2 4 10236.1222 0.0005 0.002 45: 4 1 3 1 4 3 1 2 1 3 10236.1443 0.0010 0.002 46: 4 1 3 1 5 3 1 2 1 4 10236.2957 0.0000 0.002 47: 4 1 3 1 3 3 1 2 2 3 10236.5499 0.0008 0.002 48: 4 1 3 2 2 3 1 2 2 2 10236.5904 -0.0015 0.002 49: 4 1 3 1 5 3 1 2 2 4 10236.6770 -0.0025 0.002 50: 4 1 3 0 4 3 1 2 2 4 10237.2107 0.0002 0.002 51: 4 1 3 2 3 3 1 2 2 3 10237.2803 0.0006 0.002 ! 52: 4 1 4 2 2 3 0 3 2 1 10344.6095 0.0002 0.002 53: 4 1 4 2 6 3 0 3 2 5 10344.8132 -0.0007 0.002 54: 4 1 4 1 5 3 0 3 2 4 10344.8692 0.0007 0.002 55: 4 1 4 2 3 3 0 3 1 2 10344.7582 0.0025 0.002 56: 4 1 4 1 4 3 0 3 2 3 10344.8971 -0.0005 0.002 57: 4 1 4 0 4 3 0 3 0 3 10344.9577 0.0001 0.002 58: 4 1 4 2 4 3 0 3 1 3 10345.1643 -0.0009 0.002 59: 4 1 4 1 3 3 0 3 2 2 10345.4539 0.0030 0.002 60: 4 1 4 2 5 3 0 3 1 4 10345.5431 0.0002 0.002 ! 61: 5 1 5 1 5 4 1 4 2 5 10889.2329 0.0028 0.002 62: 5 1 5 2 3 4 1 4 1 3 10889.2862 -0.0008 0.002 63: 5 1 5 2 4 4 1 4 1 4 10890.4974 0.0001 0.002 64: 5 1 5 1 6 4 1 4 1 5 10891.3214 -0.0018 0.002 65: 5 1 5 2 4 4 1 4 2 3 10891.3748 -0.0037 0.002 66: 5 1 5 2 3 4 1 4 2 2 10891.4280 -0.0014 0.002 67: 5 1 5 2 6 4 1 4 2 5 10891.5399 -0.0031 0.002 68: 5 1 5 2 6 4 1 4 2 6 10893.2599 -0.0024 0.002 ! 69: 5 0 5 0 5 4 0 4 0 4 11271.2720 -0.0035 0.002 70: 5 0 5 1 4 4 0 4 1 3 11271.4556 -0.0029 0.002 71: 5 0 5 1 4 4 0 4 2 4 11272.4228 0.0047 0.002 72: 5 0 5 2 6 4 0 4 2 5 11271.5027 -0.0002 0.002 ! 73: 2 2 0 2 4 1 1 1 2 3 12593.9338 0.0015 0.002 74: 2 2 0 2 3 1 1 1 1 2 12594.6856 -0.0002 0.002 ! 75: 2 2 1 2 4 1 1 0 2 3 12179.3719 0.0011 0.002 76: 2 2 1 2 1 1 1 0 1 1 12179.9093 -0.0039 0.002 ! 77: 5 2 3 2 5 4 2 2 2 4 12589.5276 0.0015 0.002 ! 78: 6 0 6 1 5 5 0 5 1 4 13282.0397 -0.0011 0.002 79: 6 0 6 2 7 5 0 5 2 6 13282.0747 0.0026 0.002 80: 6 0 6 2 6 5 0 5 2 5 13281.9582 0.0016 0.002 ! 81: 6 2 4 2 7 5 2 3 2 6 15272.8698 0.0017 0.002 0.0008 0.58 82: 6 2 4 1 5 5 2 3 1 4 15272.8698 -0.0003 0.002 0.0008 0.42 83: 6 2 4 2 4 5 2 3 2 3 15272.9920 0.0025 0.002 -0.0003 0.16 84: 6 2 4 2 8 5 2 3 2 7 15272.9920 -0.0010 0.002 -0.0003 0.34 85: 6 2 4 0 6 5 2 3 0 5 15272.9920 -0.0006 0.002 -0.0003 0.25 86: 6 2 4 1 6 5 2 3 1 5 15272.9920 -0.0006 0.002 -0.0003 0.25 ! 87: 3 2 1 2 5 2 1 2 2 4 15523.9622 -0.0015 0.003 ! 88: 6 2 5 1 7 5 2 4 1 6 14188.6415 0.0000 0.002 -0.0006 0.59 89: 6 2 5 2 5 5 2 4 2 4 14188.6415 -0.0015 0.002 -0.0006 0.41 90: 6 2 5 2 8 5 2 4 2 7 14188.4864 0.0023 0.002 0.0017 0.40 91: 6 2 5 0 6 5 2 4 0 5 14188.4864 0.0015 0.002 0.0017 0.30 92: 6 2 5 2 6 5 2 4 2 5 14188.4864 0.0010 0.002 0.0017 0.29 ! 93: 3 2 2 2 5 2 1 1 2 4 14201.6209 0.0022 0.002 ! 94: 6 3 4 1 6 5 3 3 0 5 14527.5119 0.0010 0.002 95: 6 3 4 1 7 5 3 3 1 6 14527.6070 -0.0036 0.002 96: 6 3 4 2 5 5 3 3 2 4 14527.6522 0.0006 0.002 ! 97: 7 0 7 1 7 6 0 6 1 6 15268.1402 0.0010 0.002 98: 7 0 7 2 7 6 0 6 2 6 15268.2171 0.0000 0.002 99: 7 0 7 1 6 6 0 6 1 5 15268.2660 0.0008 0.002 100: 7 0 7 2 8 6 0 6 2 7 15268.2872 -0.0010 0.002 ! 101: 6 2 4 2 6 5 2 3 2 5 15272.8010 0.0003 0.002 102: 6 2 4 2 7 5 2 3 2 6 15272.8684 0.0003 0.002 -0.0006 0.58 103: 6 2 4 1 5 5 2 3 1 4 15272.8684 -0.0017 0.002 -0.0006 0.42 104: 6 2 4 2 5 5 2 3 2 4 15272.9264 0.0035 0.002 0.0002 0.41 105: 6 2 4 1 7 5 2 3 1 6 15272.9264 -0.0020 0.002 0.0002 0.59 106: 6 2 4 2 4 5 2 3 2 3 15272.9923 0.0028 0.002 0.0000 0.16 107: 6 2 4 2 8 5 2 3 2 7 15272.9923 -0.0007 0.002 0.0000 0.34 108: 6 2 4 1 6 5 2 3 1 5 15272.9923 -0.0003 0.002 0.0000 0.25 109: 6 2 4 0 6 5 2 3 0 5 15272.9923 -0.0003 0.002 0.0000 0.25 ! 110: 7 2 6 2 6 6 2 5 2 5 16453.9408 0.0011 0.002 -0.0022 0.43 111: 7 2 6 1 8 6 2 5 1 7 16453.9408 -0.0047 0.002 -0.0022 0.57 112: 7 2 6 1 6 6 2 5 1 5 16453.7140 0.0053 0.002 0.0025 0.43 113: 7 2 6 2 8 6 2 5 2 7 16453.7140 0.0004 0.002 0.0025 0.57 -------------------------------------------------------------------------------- PARAMETERS IN FIT (values truncated and Nlines statistics): 10000 A /MHz 3722.8200(13) 1 20000 B /MHz 1384.23544(24) 2 30000 C /MHz 1011.15835(17) 3 200 DJ /kHz 0.2058(19) 4 1100 DJK /kHz 0.419(15) 5 2000 DK /kHz 2.20(27) 6 40100 delJ /kHz 0.0588(13) 7 41000 delK /kHz 0.612(45) 8 110010000 1:X.aa*3/2 /MHz 3.0091(31) 9 110040000 1:X(b-c)/4 /MHz 1.55556(95) 10 110610000 1:Xab /MHz [ 0.] 11 220010000 2:X.aa*3/2 /MHz -4.8756(27) 12 220040000 2:X(b-c)/4 /MHz -0.1283(10) 13 220610000 2:Xab /MHz 1.43(18) 14 MICROWAVE AVG = 0.000023 MHz, IR AVG = 0.00000 MICROWAVE RMS = 0.001960 MHz, IR RMS = 0.00000 END OF ITERATION 1 OLD, NEW RMS ERROR= 0.97796 0.97796 distinct frequency lines in fit: 97 distinct parameters of fit: 13 upper state lower state overall limits of quantum number 1: 2 7 1 6 1 7 limits of quantum number 2: 0 3 0 3 0 3 limits of quantum number 3: 0 7 0 6 0 7 limits of quantum number 4: 0 2 0 2 0 2 limits of quantum number 5: 1 8 1 7 1 8 frequency range: 4749 16453 PARAMETERS IN FIT WITH STANDARD ERRORS ON THOSE THAT ARE FITTED: (values rounded and degrees of freedom, Ndegf=Nlines-Nconst, statistics) 10000 A /MHz 3722.8201(14) 1 20000 B /MHz 1384.23544(25) 2 30000 C /MHz 1011.15836(18) 3 200 DJ /kHz 0.2058(20) 4 1100 DJK /kHz 0.419(16) 5 2000 DK /kHz 2.21(29) 6 40100 delJ /kHz 0.0588(14) 7 41000 delK /kHz 0.612(47) 8 110010000 1:X.aa*3/2 /MHz 3.0091(33) 9 110040000 1:X(b-c)/4 /MHz 1.55556(100) 10 110610000 1:Xab /MHz [ 0.] 11 220010000 2:X.aa*3/2 /MHz -4.8756(28) 12 220040000 2:X(b-c)/4 /MHz -0.1284(11) 13 220610000 2:Xab /MHz 1.43(19) 14 CORRELATION COEFFICIENTS, C.ij: A B C -DJ -DJK -DK -delJ -delK A 1.0000 B 0.5547 1.0000 C -0.7223 -0.7836 1.0000 -DJ -0.0731 -0.7241 0.4022 1.0000 -DJK -0.1060 0.1583 -0.1127 -0.4983 1.0000 -DK -0.9722 -0.5559 0.7074 0.1101 0.0125 1.0000 -delJ -0.3993 -0.7927 0.6023 0.5043 -0.3389 0.4215 1.0000 -delK -0.3275 -0.5647 0.6669 0.6477 -0.0915 0.3219 0.0996 1.0000 1:X.aa*3/2 0.0443 0.0924 -0.0677 -0.0372 -0.0803 -0.0398 -0.0527 -0.0558 1:X(b-c)/4 -0.0571 -0.1619 0.1095 0.0785 0.0483 0.0387 0.1290 0.0618 2:X.aa*3/2 0.0001 0.0326 0.0011 -0.0512 0.0060 0.0066 -0.0010 -0.0321 2:X(b-c)/4 -0.0711 -0.1007 0.0869 0.0488 -0.0301 0.1122 0.1107 0.0297 2:Xab -0.2627 0.1316 0.0309 -0.1692 0.1308 0.2561 -0.2049 0.0669 1:X.aa*3 1:X(b-c) 2:X.aa*3 2:X(b-c) 2:Xab 1:X.aa*3/2 1.0000 1:X(b-c)/4 -0.2645 1.0000 2:X.aa*3/2 0.2674 -0.0719 1.0000 2:X(b-c)/4 -0.0107 0.1323 0.1941 1.0000 2:Xab 0.0270 -0.1552 -0.0187 -0.0153 1.0000 Mean value of |C.ij|, i.ne.j = 0.2123 Mean value of C.ij, i.ne.j = -0.0204 No correlations with absolute value greater than 0.9950 Worst fitted lines (obs-calc/error): 28: -3.4 24: 3.2 71: 2.4 1: 1.9 76: -1.9 65: -1.9 95: -1.8 16: -1.8 69: -1.8 21: -1.6 67: -1.5 59: 1.5 70: -1.4 9: -1.4 61: 1.4 79: 1.3 112: 1.3 49: -1.2 55: 1.2 68: -1.2 110: -1.1 4: 1.1 33: 1.1 93: 1.1 42: -0.9 64: -0.9 31: 0.9 90: 0.9 80: 0.8 32: -0.8 8: 0.8 12: 0.8 73: 0.8 35: 0.8 48: -0.8 77: 0.8 66: -0.7 19: -0.7 11: 0.6 36: 0.6 14: 0.6 40: -0.6 30: -0.6 78: -0.6 75: 0.6 97: 0.5 29: 0.5 94: 0.5 87: -0.5 100: -0.5 28/ 3 1 3 2 2 2 0 2 1 1 8608.4776 -0.0068 0.002 24/ 3 2 2 2 4 2 2 1 1 3 7186.8411 0.0065 0.002 71: 5 0 5 1 4 4 0 4 2 4 11272.4228 0.0047 0.002 1: 2 0 2 2 3 1 0 1 2 2 4749.4884 0.0039 0.002 76: 2 2 1 2 1 1 1 0 1 1 12179.9093 -0.0039 0.002 65: 5 1 5 2 4 4 1 4 2 3 10891.3748 -0.0037 0.002 95: 6 3 4 1 7 5 3 3 1 6 14527.6070 -0.0036 0.002 16: 3 0 3 0 3 2 0 2 0 2 7024.6935 -0.0036 0.002 69: 5 0 5 0 5 4 0 4 0 4 11271.2720 -0.0035 0.002 21: 3 2 2 2 2 2 2 1 1 1 7184.9974 -0.0033 0.002 _____________________________________ __________________________________________/ SPFIT output reformatted with PIFORM