CF3CCl3 = CFC113a, 1x37Cl lowest excited vibrational state ----------------------+++++------------------------------------------------------------- number of transitions: 296 number of constants : 8 -----++++++++++++++++++++++++++++++----------------------------------------------------- 1 1307.9973902721819740691 A Reduction-A, Representation-I.r 1 1105.5038584666308452142 B 1 1092.7027860407929438225 C 1 0.0000554315839097456 DJ 1 0.0000201541391406454 DJK 0 -0.0000252600000000000 DK 1 0.0000008905667898190 dJ 1 0.0000314311177334187 dK ---------------------------------------------------------------------------------------- J' K-1' K+1' J K-1 K+1 frequency error fit? blend Note +++++-----+++++-----+++++-----++++++++++++++++++++---------------+++++----------++++++++ 70 11 59 69 11 58 154275.857514 0.050000 1 70 12 59 69 12 58 154043.905618 0.050000 1 70 13 58 69 13 57 154025.972504 0.050000 1 70 15 55 69 15 54 153966.961467 0.050000 1 ! 81 2 79 80 2 78 177166.301324 0.050000 1 81 3 78 80 3 77 177271.638331 0.050000 1 81 4 77 80 4 76 177377.645652 0.050000 1 81 5 76 80 5 75 177484.451159 0.050000 1 81 8 74 80 8 73 177702.695939 0.050000 1 81 13 68 80 13 67 178477.859419 0.050000 1 81 13 69 80 13 68 178226.254041 0.050000 1 81 14 68 80 14 67 178235.127476 0.050000 1 81 16 65 80 16 64 178174.271974 0.050000 1 81 16 66 80 16 65 178171.141657 0.050000 1 81 18 63 80 18 62 178115.644561 0.050000 2 2.22E-05 81 18 64 80 18 63 178115.644561 0.050000 2 2.22E-05 81 19 62 80 19 61 178095.822817 0.050000 1 81 20 61 80 20 60 178079.413696 0.050000 1 81 21 60 80 21 59 178065.775537 0.050000 1 81 23 58 80 23 57 178044.101418 0.050000 1 81 24 57 80 24 56 178035.395271 0.050000 1 81 25 56 80 25 55 178027.739754 0.050000 1 81 26 55 80 26 54 178021.116230 0.050000 1 81 28 53 80 28 52 178009.730208 0.050000 1 81 29 52 80 29 51 178004.894326 0.050000 1 81 30 51 80 30 50 178000.551494 0.050000 1 81 31 50 80 31 49 177996.514660 0.050000 1 81 32 49 80 32 48 177992.958312 0.050000 1 81 33 48 80 33 47 177989.612385 0.050000 1 81 34 47 80 34 46 177986.651612 0.050000 1 81 35 46 80 35 45 177983.729173 0.050000 1 81 36 45 80 36 44 177981.103714 0.050000 1 81 37 44 80 37 43 177978.703981 0.050000 1 81 38 43 80 38 42 177976.442839 0.050000 1 81 39 42 80 39 41 177974.288009 0.050000 1 81 40 41 80 40 40 177972.346209 0.050000 1 81 41 40 80 41 39 177970.460505 0.050000 1 81 42 39 80 42 38 177968.710117 0.050000 1 81 43 38 80 43 37 177966.990046 0.050000 1 81 44 37 80 44 36 177965.433661 0.050000 1 81 45 36 80 45 35 177963.986598 0.050000 1 81 46 35 80 46 34 177962.586449 0.050000 1 81 47 34 80 47 33 177961.080941 0.050000 1 81 48 33 80 48 32 177959.709632 0.050000 1 81 49 32 80 49 31 177958.577654 0.050000 1 81 53 28 80 53 27 177953.743668 0.050000 1 81 54 27 80 54 26 177952.714633 0.050000 1 81 56 25 80 56 24 177950.819055 0.050000 1 ! 88 2 86 87 2 85 192431.866766 0.050000 1 88 3 85 87 3 84 192537.120297 0.050000 1 88 4 84 87 4 83 192642.810218 0.050000 1 88 5 83 87 5 82 192749.198827 0.050000 1 88 6 82 87 6 81 192856.515270 0.050000 1 88 7 81 87 7 80 192965.259100 0.050000 1 88 9 80 87 9 79 193076.347069 0.050000 1 88 10 78 87 10 77 193312.597657 0.050000 1 88 11 77 87 11 76 193452.346739 0.050000 1 88 12 77 87 12 76 193431.071874 0.050000 1 88 15 74 87 15 73 193626.493611 0.050000 2 2.37E-05 88 16 72 87 16 71 193626.493611 0.050000 2 2.36E-05 88 14 75 87 14 74 193613.595339 0.050000 1 88 17 71 87 17 70 193564.032842 0.050000 1 88 17 72 87 17 71 193559.533760 0.050000 1 88 18 70 87 18 69 193525.993869 0.050000 1 88 19 69 87 19 68 193497.843595 0.050000 2 2.31E-05 88 19 70 87 19 69 193497.843595 0.050000 2 2.31E-05 88 20 68 87 20 67 193475.538975 0.050000 1 88 21 67 87 21 66 193457.170080 0.050000 1 88 22 66 87 22 65 193441.716165 0.050000 1 88 23 65 87 23 64 193428.420045 0.050000 1 88 24 64 87 24 63 193417.048456 0.050000 1 88 25 63 87 25 62 193407.104489 0.050000 1 88 26 62 87 26 61 193398.361163 0.050000 1 88 27 61 87 27 60 193390.617838 0.050000 1 88 29 59 87 29 58 193377.466506 0.050000 1 88 30 58 87 30 57 193371.915064 0.050000 1 88 31 57 87 31 56 193366.874969 0.050000 1 88 32 56 87 32 55 193362.179214 0.050000 1 88 33 55 87 33 54 193357.991243 0.050000 1 88 35 53 87 35 52 193350.509971 0.050000 1 88 36 52 87 36 51 193347.324142 0.050000 1 88 37 51 87 37 50 193344.140726 0.050000 1 88 38 50 87 38 49 193341.231831 0.050000 1 88 39 49 87 39 48 193338.631364 0.050000 1 88 40 48 87 40 47 193336.059254 0.050000 1 88 41 47 87 41 46 193333.669538 0.050000 1 88 42 46 87 42 45 193331.445071 0.050000 1 88 43 45 87 43 44 193329.510989 0.050000 1 88 45 43 87 45 42 193325.578053 0.050000 1 88 47 41 87 47 40 193322.175660 0.050000 1 88 49 39 87 49 38 193318.956771 0.050000 1 88 50 38 87 50 37 193317.560782 0.050000 1 88 52 36 87 52 35 193314.599450 0.050000 1 88 53 35 87 53 34 193313.279433 0.050000 1 88 54 34 87 54 33 193311.888040 0.050000 1 88 55 33 87 55 32 193310.679683 0.050000 1 88 58 30 87 58 29 193307.084577 0.050000 1 88 60 28 87 60 27 193304.805187 0.050000 1 ! 92 2 90 91 2 89 201152.557578 0.050000 1 92 3 89 91 3 88 201257.775401 0.050000 1 92 4 88 91 4 87 201363.381562 0.050000 1 92 5 87 91 5 86 201469.439352 0.050000 1 92 6 86 91 6 85 201576.611586 0.050000 1 92 8 84 91 8 83 201794.898185 0.050000 1 92 11 81 91 11 80 202153.074263 0.050000 1 92 13 80 91 13 79 202267.084154 0.050000 1 92 15 78 91 15 77 202417.625209 0.050000 1 92 16 77 91 16 76 202410.636214 0.050000 1 92 17 76 91 17 75 202373.900424 0.050000 1 92 18 74 91 18 73 202336.882887 0.050000 1 92 20 72 91 20 71 202274.969238 0.050000 1 92 21 71 91 21 70 202253.198076 0.050000 1 92 22 70 91 22 69 202235.018644 0.050000 1 92 23 69 91 23 68 202219.590846 0.050000 1 92 24 68 91 24 67 202206.324419 0.050000 1 92 25 67 91 25 66 202194.903301 0.050000 1 92 26 66 91 26 65 202184.708756 0.050000 1 92 27 65 91 27 64 202175.903337 0.050000 1 92 28 64 91 28 63 202167.889062 0.050000 1 92 29 63 91 29 62 202160.732131 0.050000 1 92 30 62 91 30 61 202154.348594 0.050000 1 92 31 61 91 31 60 202148.504266 0.050000 1 92 32 60 91 32 59 202143.328755 0.050000 1 92 33 59 91 33 58 202138.546394 0.050000 1 92 34 58 91 34 57 202134.091248 0.050000 1 92 35 57 91 35 56 202130.007273 0.050000 1 92 36 56 91 36 55 202126.103754 0.050000 1 92 37 55 91 37 54 202122.697597 0.050000 1 92 38 54 91 38 53 202119.476878 0.050000 1 92 40 52 91 40 51 202113.643852 0.050000 1 92 42 50 91 42 49 202108.452896 0.050000 1 92 43 49 91 43 48 202106.183663 0.050000 1 92 44 48 91 44 47 202103.959055 0.050000 1 92 46 46 91 46 45 202099.836617 0.050000 1 92 47 45 91 47 44 202097.825517 0.050000 1 92 49 43 91 49 42 202094.276670 0.050000 1 92 50 42 91 50 41 202092.612173 0.050000 1 92 53 39 91 53 38 202087.976608 0.050000 1 92 54 38 91 54 37 202086.488664 0.050000 1 92 56 36 91 56 35 202083.737649 0.050000 1 92 59 33 91 59 32 202079.956497 0.050000 1 92 62 30 91 62 29 202076.353271 0.050000 1 ! 93 2 91 92 2 90 203332.438291 0.050000 1 93 3 90 92 3 89 203437.645876 0.050000 1 93 4 89 92 4 88 203543.219616 0.050000 1 93 5 88 92 5 87 203649.345479 0.050000 1 93 6 87 92 6 86 203756.299991 0.050000 1 93 8 85 92 8 84 203974.359468 0.050000 1 93 9 84 92 9 83 204086.824888 0.050000 2 2.41E-05 93 10 84 92 10 83 204086.824888 0.050000 2 2.41E-05 93 14 80 92 14 79 204552.683175 0.050000 1 93 15 79 92 15 78 204612.133949 0.050000 2 2.39E-05 93 16 78 92 16 77 204612.133949 0.050000 2 2.38E-05 93 17 76 92 17 75 204598.414126 0.050000 1 93 18 75 92 18 74 204540.716579 0.050000 1 93 18 76 92 18 75 204537.316340 0.050000 1 93 21 73 92 21 72 204452.295154 0.050000 1 93 22 71 92 22 70 204433.465789 0.050000 1 93 23 70 92 23 69 204417.332778 0.050000 1 93 24 69 92 24 68 204403.629191 0.050000 1 93 25 68 92 25 67 204391.793623 0.050000 1 93 26 67 92 26 66 204381.265024 0.050000 1 93 27 66 92 27 65 204371.984584 0.050000 1 93 28 65 92 28 64 204363.812004 0.050000 1 93 29 64 92 29 63 204356.463652 0.050000 1 93 30 63 92 30 62 204349.806572 0.050000 1 93 31 62 92 31 61 204343.857376 0.050000 1 93 32 61 92 32 60 204338.395318 0.050000 1 93 33 60 92 33 59 204333.360275 0.050000 1 93 34 59 92 34 58 204328.844925 0.050000 1 93 35 58 92 35 57 204324.635702 0.050000 1 93 36 57 92 36 56 204320.728113 0.050000 1 93 37 56 92 37 55 204317.167746 0.050000 1 93 38 55 92 38 54 204313.794208 0.050000 1 93 39 54 92 39 53 204310.769109 0.050000 1 93 40 53 92 40 52 204307.794859 0.050000 1 93 41 52 92 41 51 204305.092231 0.050000 1 93 43 50 92 43 49 204300.121048 0.050000 1 93 44 49 92 44 48 204297.801788 0.050000 1 93 45 48 92 45 47 204295.525239 0.050000 1 93 46 47 92 46 46 204293.623321 0.050000 1 93 47 46 92 47 45 204291.572261 0.050000 1 93 50 43 92 50 42 204286.221307 0.050000 1 93 51 42 92 51 41 204284.545938 0.050000 1 93 52 41 92 52 40 204283.031795 0.050000 1 93 53 40 92 53 39 204281.393300 0.050000 1 93 54 39 92 54 38 204279.975087 0.050000 1 93 57 36 92 57 35 204275.781156 0.050000 1 93 61 32 92 61 31 204270.561469 0.050000 1 93 64 29 92 64 28 204267.013184 0.050000 1 93 65 28 92 65 27 204265.951193 0.050000 1 ! ! 97 2 95 96 2 94 212050.765143 0.050000 1 97 3 94 96 3 93 212155.873430 0.050000 1 97 4 93 96 4 92 212261.321534 0.050000 1 97 5 92 96 5 91 212367.320644 0.050000 1 97 6 91 96 6 90 212474.023389 0.050000 1 97 7 90 96 7 89 212581.801309 0.050000 1 97 9 89 96 9 88 212691.054243 0.050000 1 97 10 88 96 10 87 212802.324415 0.050000 1 97 11 87 96 11 86 212916.783627 0.050000 1 97 11 86 96 11 85 213037.403545 0.050000 1 97 12 86 96 12 85 213035.749892 0.050000 2 2.38E-05 97 66 31 96 66 30 213035.749892 0.050000 2 2.28E-05 97 15 83 96 15 82 213372.304875 0.050000 1 97 15 82 96 15 81 213707.101253 0.050000 1 97 16 82 96 16 81 213408.337447 0.050000 1 97 17 81 96 17 80 213390.645042 0.050000 1 97 18 80 96 18 79 213350.127777 0.050000 1 97 19 78 96 19 77 213311.505399 0.050000 1 97 22 75 96 22 74 213227.414597 0.050000 1 97 23 74 96 23 73 213208.781311 0.050000 1 97 25 72 96 25 71 213179.132607 0.050000 1 97 26 71 96 26 70 213167.064536 0.050000 1 97 27 70 96 27 69 213156.510809 0.050000 1 97 28 69 96 28 68 213147.122125 0.050000 1 97 29 68 96 29 67 213138.722075 0.050000 1 97 30 67 96 30 66 213131.144794 0.050000 1 97 31 66 96 31 65 213124.304994 0.050000 1 97 32 65 96 32 64 213118.093662 0.050000 1 97 33 64 96 33 63 213112.450954 0.050000 1 97 34 63 96 34 62 213107.253010 0.050000 1 97 36 61 96 36 60 213098.198370 0.050000 1 97 37 60 96 37 59 213094.031182 0.050000 1 97 38 59 96 38 58 213090.367888 0.050000 1 97 39 58 96 39 57 213086.783620 0.050000 1 97 40 57 96 40 56 213083.554578 0.050000 1 97 43 54 96 43 53 213074.886657 0.050000 1 97 45 52 96 45 51 213069.842123 0.050000 1 97 46 51 96 46 50 213067.528643 0.050000 1 97 47 50 96 47 49 213065.389650 0.050000 1 97 49 48 96 49 47 213061.337107 0.050000 1 97 51 46 96 51 45 213057.502735 0.050000 1 97 52 45 96 52 44 213055.677326 0.050000 1 97 53 44 96 53 43 213054.075650 0.050000 1 97 54 43 96 54 42 213052.312831 0.050000 1 97 55 42 96 55 41 213050.714933 0.050000 1 97 56 41 96 56 40 213049.167016 0.050000 1 97 59 38 96 59 37 213044.955053 0.050000 1 97 60 37 96 60 36 213043.535087 0.050000 1 97 62 35 96 62 34 213040.946237 0.050000 1 97 64 33 96 64 32 213038.215684 0.050000 1 97 67 30 96 67 29 213034.556750 0.050000 1 97 72 25 96 72 24 213028.837312 0.050000 1 97 74 23 96 74 22 213026.597084 0.050000 1 ! 101 2 99 100 2 98 220767.028541 0.050000 1 101 3 98 100 3 97 220872.181052 0.050000 1 101 4 97 100 4 96 220977.593872 0.050000 1 101 5 96 100 5 95 221083.384411 0.050000 1 101 6 95 100 6 94 221189.884144 0.050000 1 101 7 94 100 7 93 221297.231732 0.050000 1 101 8 93 100 8 92 221405.864300 0.050000 1 101 11 91 100 11 90 221629.368996 0.050000 2 2.34E-05 101 10 91 100 10 90 221629.368996 0.050000 2 2.34E-05 101 12 90 100 12 89 221746.432274 0.050000 2 2.34E-05 101 11 90 100 11 89 221746.432274 0.050000 2 2.34E-05 101 17 85 100 17 84 222194.543699 0.050000 1 101 16 86 100 16 85 222181.685926 0.050000 1 101 18 84 100 18 83 222163.236258 0.050000 1 101 15 87 100 15 86 222107.770233 0.050000 1 101 20 81 100 20 80 222081.152348 0.050000 1 101 20 82 100 20 81 222080.496714 0.050000 1 101 22 80 100 22 79 222022.270435 0.050000 1 101 23 78 100 23 77 222000.487132 0.050000 1 101 24 77 100 24 76 221982.185407 0.050000 1 101 25 76 100 25 75 221966.200071 0.050000 1 101 26 75 100 26 74 221952.394436 0.050000 1 101 27 74 100 27 73 221940.340081 0.050000 1 101 28 73 100 28 72 221929.524511 0.050000 1 101 29 72 100 29 71 221920.042913 0.050000 1 101 31 70 100 31 69 221903.784604 0.050000 1 101 32 69 100 32 68 221896.679654 0.050000 1 101 33 68 100 33 67 221890.428685 0.050000 1 101 34 67 100 34 66 221884.478089 0.050000 1 101 35 66 100 35 65 221879.089957 0.050000 1 101 37 64 100 37 63 221869.635693 0.050000 1 101 38 63 100 38 62 221865.411571 0.050000 1 101 39 62 100 39 61 221861.464951 0.050000 1 101 40 61 100 40 60 221857.730091 0.050000 1 101 41 60 100 41 59 221854.276107 0.050000 1 101 42 59 100 42 58 221851.108604 0.050000 1 101 43 58 100 43 57 221848.032108 0.050000 1 101 44 57 100 44 56 221845.188181 0.050000 1 101 45 56 100 45 55 221842.379335 0.050000 1 101 47 54 100 47 53 221837.403259 0.050000 1 101 48 53 100 48 52 221835.237180 0.050000 1 101 49 52 100 49 51 221832.957406 0.050000 1 101 50 51 100 50 50 221830.720896 0.050000 1 101 53 48 100 53 47 221824.938019 0.050000 1 101 58 43 100 58 42 221816.348699 0.050000 1 101 59 42 100 59 41 221814.766879 0.050000 1 101 62 39 100 62 38 221810.461063 0.050000 1 101 63 38 100 63 37 221808.942272 0.050000 1 101 64 37 100 64 36 221807.663081 0.050000 1 101 65 36 100 65 35 221806.313732 0.050000 1 101 70 31 100 70 30 221799.842033 0.050000 1 101 71 30 100 71 29 221798.635195 0.050000 1 +++++-----+++++-----+++++-----++++++++++++++++++++---------------+++++----------++++++++ ----------------------------------------------------------------------------------------