freon133a:13C1 Fri Feb 03 12:45:39 2017 -------------------------------------------------------------------------------------========= obs o-c error blends Notes o-c wt / instead of : below denotes (o-c)>3*err -------------------------------------------------------------------------------------========= ! 1: 1 1 1 1 0 0 0 2 7062.4899 0.0061 0.005 2: 1 1 1 2 0 0 0 2 7064.8620 0.0045 0.005 3: 1 1 1 3 0 0 0 2 7063.5112 0.0119 0.005 ! 4: 2 1 2 1 1 0 1 1 10618.7235 -0.0037 0.005 5: 2 1 2 1 1 0 1 2 10639.2965 0.0006 0.005 6: 2 1 2 2 1 0 1 1 10608.6255 -0.0012 0.005 7: 2 1 2 2 1 0 1 2 10629.1920 -0.0034 0.005 8: 2 1 2 2 1 0 1 3 10617.7352 -0.0048 0.005 9: 2 1 2 3 1 0 1 2 10621.9579 -0.0017 0.005 10: 2 1 2 3 1 0 1 3 10610.5017 -0.0024 0.005 11: 2 1 2 4 1 0 1 3 10620.5979 -0.0007 0.005 ! 12: 2 2 0 1 1 1 1 1 17648.9887 0.0000 0.005 13: 2 2 0 2 1 1 1 1 17660.2098 0.0008 0.005 14: 2 2 0 2 1 1 1 2 17657.8333 -0.0020 0.005 15: 2 2 0 3 1 1 1 3 17667.5417 -0.0040 0.005 16: 2 2 0 4 1 1 1 3 17656.0123 -0.0025 0.005 ! 17: 2 2 0 1 2 1 1 1 10437.8331 0.0073 0.005 18: 2 2 0 1 2 1 1 2 10439.1677 -0.0031 0.005 19: 2 2 0 2 2 1 1 2 10450.3960 0.0049 0.005 20: 2 2 0 2 2 1 1 3 10451.3408 -0.0016 0.005 21: 2 2 0 3 2 1 1 3 10459.6928 -0.0018 0.005 22: 2 2 0 4 2 1 1 4 10446.8503 -0.0009 0.005 ! 23: 2 2 1 1 1 1 0 1 17633.7403 -0.0045 0.005 24: 2 2 1 2 1 1 0 1 17644.7901 -0.0006 0.005 25: 2 2 1 2 1 1 0 2 17626.5940 0.0004 0.005 26: 2 2 1 3 1 1 0 2 17635.0149 -0.0021 0.005 27: 2 2 1 3 1 1 0 3 17645.1057 -0.0042 0.005 28: 2 2 1 4 1 1 0 3 17633.5662 -0.0011 0.005 ! 29: 2 2 1 2 2 1 2 1 10512.0321 0.0025 0.005 30: 2 2 1 2 2 1 2 2 10522.1341 0.0040 0.005 31: 2 2 1 3 2 1 2 3 10537.7905 0.0012 0.005 32: 2 2 1 3 2 1 2 4 10527.6980 0.0031 0.005 33: 2 2 1 4 2 1 2 3 10526.2417 -0.0049 0.005 ! 34: 3 0 3 3 2 0 2 2 10737.9156 -0.0103 0.005 35: 3 0 3 5 2 0 2 4 10740.8244 0.0023 0.005 ! 36: 3 0 3 2 2 1 2 1 7279.7795 0.0089 0.005 37: 3 0 3 2 2 1 2 2 7289.8796 0.0086 0.005 38: 3 0 3 4 2 1 2 3 7280.2119 0.0050 0.005 39: 3 0 3 5 2 1 2 4 7281.6114 0.0051 0.005 ! 40: 3 1 2 2 2 1 1 1 10778.9152 0.0031 0.005 41: 3 1 2 3 2 1 1 2 10775.8921 -0.0024 0.005 42: 3 1 2 4 2 1 1 3 10774.9410 -0.0008 0.005 43: 3 1 2 5 2 1 1 4 10777.6964 -0.0016 0.005 ! 44: 3 1 3 2 2 0 2 1 14163.4969 -0.0010 0.005 45: 3 1 3 2 2 0 2 2 14174.9464 -0.0020 0.005 46: 3 1 3 3 2 0 2 2 14161.7348 -0.0011 0.005 47: 3 1 3 3 2 0 2 3 14169.9605 -0.0019 0.005 48: 3 1 3 4 2 0 2 3 14163.9860 -0.0009 0.005 49: 3 1 3 4 2 0 2 4 14152.5408 -0.0031 0.005 50: 3 1 3 5 2 0 2 4 14165.3044 0.0003 0.005 ! 51: 3 1 3 3 2 1 2 2 10702.1635 0.0012 0.005 52: 3 1 3 4 2 1 2 3 10703.4275 0.0050 0.005 ! 53: 3 2 1 3 2 2 0 2 10741.4027 0.0002 0.005 ! 54: 3 2 1 2 3 1 2 2 10411.4961 -0.0007 0.005 55: 3 2 1 3 3 1 2 3 10415.8983 -0.0005 0.005 56: 3 2 1 4 3 1 2 4 10417.8585 0.0010 0.005 57: 3 2 1 5 3 1 2 5 10413.6925 0.0010 0.005 ! 58: 3 2 2 4 3 1 3 4 10566.9990 0.0026 0.005 59: 3 2 2 5 3 1 3 5 10554.2044 0.0005 0.005 ! 60: 3 3 0 4 3 2 1 4 17486.4316 0.0020 0.005 61: 3 3 0 5 3 2 1 5 17472.2144 -0.0041 0.005 ! 62: 3 3 1 4 3 2 2 4 17487.0933 -0.0080 0.005 ! 63: 4 0 4 6 3 0 3 5 14320.1092 0.0003 0.005 ! 64: 4 0 4 3 3 1 3 2 10893.3038 -0.0006 0.005 65: 4 0 4 3 3 1 3 3 10906.5133 -0.0036 0.005 66: 4 0 4 4 3 1 3 3 10894.9194 0.0000 0.005 67: 4 0 4 5 3 1 3 4 10896.8438 -0.0001 0.005 68: 4 0 4 5 3 1 3 5 10884.0788 -0.0050 0.005 69: 4 0 4 6 3 1 3 5 10895.6257 -0.0012 0.005 ! 70: 4 1 3 3 3 1 2 2 14369.0038 0.0063 0.005 71: 4 1 3 4 3 1 2 4 14369.8823 0.0053 0.005 72: 4 1 3 5 3 1 2 4 14368.0079 -0.0046 0.005 73: 4 1 3 6 3 1 2 5 14369.2715 -0.0007 0.005 ! 74: 4 1 4 4 3 1 3 3 14271.1300 -0.0035 0.005 75: 4 1 4 5 3 1 3 4 14272.1483 -0.0037 0.005 76: 4 1 4 6 3 1 3 5 14273.5040 -0.0011 0.005 ! 77: 4 2 2 6 3 2 1 5 14323.6838 0.0048 0.005 ! 78: 4 2 2 3 4 1 3 3 10367.7468 0.0020 0.005 79: 4 2 2 4 4 1 3 4 10368.6801 0.0003 0.005 80: 4 2 2 5 4 1 3 5 10368.9860 -0.0003 0.005 81: 4 2 2 6 4 1 3 6 10368.1006 0.0023 0.005 ! 82: 4 2 3 5 3 2 2 4 14317.8691 -0.0032 0.005 83: 4 2 3 6 3 2 2 5 14322.4805 0.0020 0.005 ! 84: 4 2 3 3 4 1 4 3 10599.8088 0.0050 0.005 85: 4 2 3 4 4 1 4 4 10609.3719 0.0092 0.005 86: 4 2 3 5 4 1 4 5 10612.7183 0.0016 0.005 87: 4 2 3 6 4 1 4 6 10603.1782 0.0009 0.005 ! 88: 4 3 1 3 4 2 2 3 17469.9061 -0.0015 0.005 89: 4 3 1 5 4 2 2 5 17481.3275 -0.0026 0.005 90: 4 3 1 6 4 2 2 6 17472.7600 -0.0029 0.005 ! 91: 4 3 2 5 4 2 3 5 17483.2652 -0.0031 0.005 ! 92: 5 0 5 4 4 1 4 3 14519.4052 -0.0004 0.005 93: 5 0 5 5 4 1 4 4 14521.8967 -0.0013 0.005 94: 5 0 5 6 4 1 4 5 14523.5685 -0.0015 0.005 95: 5 0 5 7 4 1 4 6 14521.0873 -0.0013 0.005 ! 96: 5 1 4 6 4 2 3 5 7593.3216 0.0063 0.005 ! 97: 5 2 3 4 5 1 4 4 10311.7015 0.0018 0.005 98: 5 2 3 5 5 1 4 5 10310.8603 0.0133 0.005 99: 5 2 3 6 5 1 4 6 10310.7394 0.0134 0.005 100: 5 2 3 7 5 1 4 7 10311.3565 0.0044 0.005 ! 101: 5 2 4 6 5 1 5 6 10671.7897 -0.0019 0.005 102: 5 2 4 7 5 1 5 7 10663.8449 0.0033 0.005 ! 103: 5 3 2 4 5 2 3 4 17470.1806 0.0047 0.005 104: 5 3 2 6 5 2 3 6 17477.3545 -0.0037 0.005 ! 105: 6 1 5 7 5 2 4 6 11245.9299 0.0006 0.005 ! 106: 6 2 4 5 6 1 5 5 10244.7581 0.0017 0.005 107: 6 2 4 6 6 1 5 6 10243.1447 0.0031 0.005 108: 6 2 4 8 6 1 5 8 10244.3695 0.0026 0.005 ! 109: 6 2 5 7 6 1 6 7 10743.3518 0.0034 0.005 110: 6 2 5 8 6 1 6 8 10736.4599 -0.0040 0.005 ! 111: 6 3 3 8 6 2 4 8 17469.2586 -0.0017 0.005 ! 112: 6 3 4 8 6 2 5 8 17477.7539 -0.0075 0.005 ! 113: 7 1 6 8 6 2 5 7 14909.7964 0.0042 0.005 114: 7 1 6 9 6 2 5 8 14908.1286 0.0004 0.005 ! 115: 7 2 5 8 7 1 6 8 10165.9543 0.0012 0.005 116: 7 2 5 9 7 1 6 9 10168.0542 -0.0006 0.005 ! 117: 7 2 6 8 7 1 7 8 10827.4670 0.0037 0.005 118: 7 2 6 9 7 1 7 9 10821.1907 0.0024 0.005 ! 119: 8 2 6 7 8 1 7 7 10083.8334 0.0012 0.005 -------------------------------------------------------------------------------- PARAMETERS IN FIT (values truncated and Nlines statistics): 10000 A /MHz 5285.63733(20) 1 20000 B /MHz 1802.134983(93) 2 30000 C /MHz 1778.12585(11) 3 200 DJ /kHz [ 0.2759] 4 1100 DJK /kHz [ 2.6053] 5 2000 DK /kHz [-1.5562] 6 40100 deltaJ /kHz [ 0.001491] 7 41000 deltaK /kHz [ 0.1066] 8 110010000 chi.aa*3/2 /MHz -68.6061(64) 9 110040000 chi(b-c)/4 /MHz -8.7766(18) 10 110610000 chi.ab /MHz 52.29(10) 11 MICROWAVE AVG = 0.000456 MHz, IR AVG = 0.00000 MICROWAVE RMS = 0.004050 MHz, IR RMS = 0.00000 END OF ITERATION 1 OLD, NEW RMS ERROR= 0.80998 0.80998 distinct frequency lines in fit: 119 distinct parameters of fit: 6 upper state lower state overall limits of quantum number 1: 1 8 0 8 0 8 limits of quantum number 2: 0 3 0 2 0 3 limits of quantum number 3: 0 6 0 7 0 7 limits of quantum number 4: 1 9 1 9 1 9 frequency range: 7062 17667 PARAMETERS IN FIT WITH STANDARD ERRORS ON THOSE THAT ARE FITTED: (values rounded and degrees of freedom, Ndegf=Nlines-Nconst, statistics) 10000 A /MHz 5285.63733(17) 1 20000 B /MHz 1802.134983(77) 2 30000 C /MHz 1778.125852(96) 3 200 DJ /kHz [ 0.2759] 4 1100 DJK /kHz [ 2.6053] 5 2000 DK /kHz [-1.5562] 6 40100 deltaJ /kHz [ 0.001491] 7 41000 deltaK /kHz [ 0.1066] 8 110010000 chi.aa*3/2 /MHz -68.6061(53) 9 110040000 chi(b-c)/4 /MHz -8.7767(15) 10 110610000 chi.ab /MHz 52.294(85) 11 CORRELATION COEFFICIENTS, C.ij: A B C chi.aa*3 chi(b-c) chi.ab A 1.0000 B 0.4883 1.0000 C 0.2828 0.5515 1.0000 chi.aa*3/2 0.0436 0.0173 -0.0113 1.0000 chi(b-c)/4 0.0629 0.0402 0.0140 0.1047 1.0000 chi.ab 0.2708 0.1221 -0.0605 -0.0398 0.1096 1.0000 Mean value of |C.ij|, i.ne.j = 0.1480 Mean value of C.ij, i.ne.j = 0.1331 No correlations with absolute value greater than 0.9950 Worst fitted lines (obs-calc/error): 99: 2.7 98: 2.7 3: 2.4 34: -2.1 85: 1.8 36: 1.8 37: 1.7 62: -1.6 112: -1.5 17: 1.5 96: 1.3 70: 1.3 1: 1.2 71: 1.1 39: 1.0 68: -1.0 52: 1.0 84: 1.0 38: 1.0 33: -1.0 19: 1.0 77: 1.0 8: -1.0 103: 0.9 72: -0.9 23: -0.9 2: 0.9 100: 0.9 113: 0.8 27: -0.8 61: -0.8 15: -0.8 110: -0.8 30: 0.8 75: -0.7 4: -0.7 117: 0.7 104: -0.7 65: -0.7 74: -0.7 109: 0.7 7: -0.7 102: 0.7 82: -0.6 18: -0.6 107: 0.6 32: 0.6 40: 0.6 49: -0.6 91: -0.6 99: 5 2 3 6 5 1 4 6 10310.7394 0.0134 0.005 98: 5 2 3 5 5 1 4 5 10310.8603 0.0133 0.005 3: 1 1 1 3 0 0 0 2 7063.5112 0.0119 0.005 34: 3 0 3 3 2 0 2 2 10737.9156 -0.0103 0.005 85: 4 2 3 4 4 1 4 4 10609.3719 0.0092 0.005 36: 3 0 3 2 2 1 2 1 7279.7795 0.0089 0.005 37: 3 0 3 2 2 1 2 2 7289.8796 0.0086 0.005 62: 3 3 1 4 3 2 2 4 17487.0933 -0.0080 0.005 112: 6 3 4 8 6 2 5 8 17477.7539 -0.0075 0.005 17: 2 2 0 1 2 1 1 1 10437.8331 0.0073 0.005 _____________________________________ __________________________________________/ SPFIT output reformatted with PIFORM