Comparison of results of fitting the newly measured transition frequencies for the 2nu9 dyad in 35ClONO2 with two different fitting schemes. -------------------------------------------------------------------------------------------------------------------------------- 2nu9 dyad SPFIT new data, JMS2002 scheme(modified) new scheme with fixed gs sextics 2v9 estimate index 2v9 v7 2v9 v7 from gs and v9=1 -------------------------------------------------------------------------------------------------------------------------------- A /MHz 100vv 11933.0077(72) 12116.9247(82) 11906.720(25) 12143.309(23) 11903.50 B /MHz 200vv 2776.26461(21) 2771.27217(20) 2776.7359(12) 2770.7929(11) 2776.628 C /MHz 300vv 2264.61090(17) 2251.95564(16) 2266.22014(35) 2250.34576(35) 2266.115 DJ /kHz 2vv 0.533140(27) 0.482773(26) 0.516077(20) 0.499975(20) 0.51625 DJK /kHz 11vv 2.92717(84) 4.8375(10) 3.83003(22) 3.92230(23) 3.8373 DK /kHz 20vv 18.577(40) -1.896(54) 7.188(19) 10.683(20) 6.740 d1 /kHz 401vv -0.086337(27) -0.105647(26) -0.0956221(72) -0.0964201(72) -0.09593 d2 /kHz 500vv -0.019246(15) -0.016015(18) -0.0163485(60) -0.0188995(69) -0.01610 HJ /Hz 3vv -0.0003623(26) 0.0000742(25)^** [-0.0001362] [-0.0001362] HJK /Hz 12vv 0.01564(10) 0.4883(15) [-0.005812] [-0.005812] HKJ /Hz 21vv -0.5239(13) -0.021149(93) [-0.01504] [-0.01504] HK /Hz 30vv [ 0.]^*** -7.735(84) [ 0.03915] [ 0.03915] h1 /Hz 402vv 0.0003081(28) -0.0003428(27) [-0.00002388] [-0.00002388] h2 /Hz 501vv -0.0001770(21) 0.0001781(22) [-0.000004463] [-0.000004463] h3 /Hz 600vv 0.00003300(68) -0.00003639(81) [ 0.000004716] [ 0.000004716] LKJ /mHz 22vv 0.1187(12) 0.00769(13) LKKJ /mHz 31vv -0.00741(11) -0.1225(13) DE_0 =v7-2v9 11 411733.435(89000) DEeff 11 503806.77(30) [ 503804.79(15)^* ] F+- /MHz 40001 -0.34115(56) F+-J /MHz 40101 -0.00000634(15) F+-K /MHz 41001 0.0001004(33) F+-JK /MHz 41101 0.00000002410(90) Gc /MHz 600001 335.977(21) GcJ /MHz 600101 -0.0006434(26) GcK /MHz 601001 -0.004261(59) Fab /MHz 610001 5.183(22) FabJ /MHz 610101 0.00008129(83) FabK /MHz 611001 -0.001476(20) C3 /MHz 620001 -0.001924(40) W_F /MHZ 1 145167.871(63000) W_F^J /MHz 101 -0.1138(25) W_F^K /MHz 1001 -8.0684(69) Nconst 42 23 Nlines 3800 3800 sigma /MHz 0.0614 0.0453 -------------------------------------------------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------------------------------------------------- * Calculated from DE_0 and W_F by accounting for correlation coefficient C(DE_0,W_F)=-0.999998 ** fitted here and fixed in the original paper (J.Mol.Spectrosc. 213 (2002) 8-14 ) *** fixed here and fitted in the original paper.