S(CN)2 v_4=5 ----------------------+++++------------------------------------------------------------- number of transitions: 163 number of constants : 15 -----++++++++++++++++++++++++++++++----------------------------------------------------- 1 10778.6217210536688071443 A Reduction-A, Representation-I.r 1 2887.0187688295995940280 B 1 2227.7973166620436131780 C 1 0.0020993955883599293 DJ 0 -0.0321000000000000035 DJK 0 0.2099999999999999922 DK 1 0.0008296184391307663 dJ 1 0.0061253463107724861 dK 1 0.0000000036595407719 HJ 0 -0.0000001000000000000 HJK 0 -0.0000013000000000000 HKJ 0 0.0000145000000000000 HK 0 0.0000000020000000000 hJ 0 -0.0000001000000000000 hJK 0 0.0000016000000000000 hK ---------------------------------------------------------------------------------------- J' K-1' K+1' J K-1 K+1 frequency error fit? blend Note +++++-----+++++-----+++++-----++++++++++++++++++++---------------+++++----------++++++++ ! ! Reference constants from extrapolation ! ! 1 10785.79590000000 A Reduction-A, Representation-I.r ! 1 2886.09800000000 B ! 1 2227.79800000000 C ! 1 0.00206900000 DJ ! 0 -0.03221070000 DJK ! 0 0.21008500000 DK ! 1 0.00081100000 dJ ! 0 0.00626400000 dK ! 0 0.00000001000 HJ ! 0 0.00000001000 HJK ! 0 -0.00000175 HKJ ! 0 0.00001349 HK ! 0 0.00000000450 hJ ! 0 0.00000000600 hJK ! 0 0.00000244000 hK ! ! ! Measurements from recalibrated and up/down averaged FASSST RT spectrum of ! Oct2005 ! ! R-type K-1=1-0 ! 24 0 24 23 1 23 109285.772600 0.100000 1 25 0 25 24 1 24 113738.292200 0.100000 1 26 0 26 25 1 25 118190.405490 0.100000 1 ! 26 1 26 25 0 25 118191.552380 0.100000 1 ! 27 0 27 26 1 26 122642.576400 0.100000 2 1.53E-05 27 1 27 26 0 26 122642.576400 0.100000 2 1.53E-05 28 0 28 27 1 27 127093.586510 0.100000 2 1.69E-05 28 1 28 27 0 27 127093.586510 0.100000 2 1.69E-05 29 0 29 28 1 28 131544.858640 0.100000 2 1.83E-05 29 1 29 28 0 28 131544.858640 0.100000 2 1.83E-05 30 0 30 29 1 29 135995.469780 0.100000 2 1.99E-05 30 1 30 29 0 29 135995.469780 0.100000 2 1.99E-05 31 0 31 30 1 30 140445.936780 0.100000 2 2.14E-05 31 1 31 30 0 30 140445.936780 0.100000 2 2.14E-05 32 0 32 31 1 31 144896.227280 0.100000 2 2.31E-05 32 1 32 31 0 31 144896.227280 0.100000 2 2.31E-05 33 0 33 32 1 32 149346.429910 0.100000 0 2.49E-05 33 1 33 32 0 32 149346.429910 0.100000 0 2.49E-05 34 1 34 33 0 33 153794.141700 0.100000 0 3.25E-05 34 0 34 33 1 33 153794.141700 0.100000 0 6.50E-05 35 0 35 34 1 34 158244.830420 0.100000 2 2.85E-05 35 1 35 34 0 34 158244.830420 0.100000 2 2.85E-05 36 0 36 35 1 35 162693.484960 0.100000 2 3.02E-05 36 1 36 35 0 35 162693.484960 0.100000 2 3.02E-05 37 0 37 36 1 36 167141.765680 0.100000 2 3.19E-05 37 1 37 36 0 36 167141.765680 0.100000 2 3.19E-05 38 0 38 37 1 37 171589.769480 0.100000 2 3.38E-05 38 1 38 37 0 37 171589.769480 0.100000 2 3.38E-05 39 0 39 38 1 38 176037.394440 0.100000 2 3.55E-05 39 1 39 38 0 38 176037.394440 0.100000 2 3.55E-05 40 0 40 39 1 39 180484.576610 0.100000 2 3.72E-05 40 1 40 39 0 39 180484.576610 0.100000 2 3.72E-05 41 0 41 40 1 40 184931.342320 0.100000 2 3.89E-05 41 1 41 40 0 40 184931.342320 0.100000 2 3.89E-05 43 0 43 42 1 42 193823.618660 0.100000 2 4.23E-05 43 1 43 42 0 42 193823.618660 0.100000 2 4.23E-05 44 0 44 43 1 43 198269.334920 0.100000 2 4.39E-05 44 1 44 43 0 43 198269.334920 0.100000 2 4.39E-05 45 0 45 44 1 44 202714.139900 0.100000 2 4.54E-05 45 1 45 44 0 44 202714.139900 0.100000 2 4.54E-05 47 0 47 46 1 46 211602.757670 0.100000 2 4.86E-05 47 1 47 46 0 46 211602.757670 0.100000 2 4.86E-05 48 0 48 47 1 47 216046.307680 0.100000 2 5.00E-05 48 1 48 47 0 47 216046.307680 0.100000 2 5.00E-05 50 0 50 49 1 49 224931.830210 0.100000 2 5.27E-05 50 1 50 49 0 49 224931.830210 0.100000 2 5.27E-05 51 0 51 50 1 50 229373.854740 0.100000 2 5.38E-05 51 1 51 50 0 50 229373.854740 0.100000 2 5.38E-05 52 1 52 51 0 51 233815.271840 0.100000 1 53 1 53 52 0 52 238256.229870 0.100000 1 54 1 54 53 0 53 242696.678370 0.100000 1 55 1 55 54 0 54 247136.256050 0.100000 1 57 1 57 56 0 56 256014.058260 0.100000 1 58 1 58 57 0 57 260451.868250 0.100000 1 59 1 59 58 0 58 264889.200880 0.100000 1 60 1 60 59 0 59 269325.806680 0.100000 1 61 1 61 60 0 60 273761.887230 0.100000 1 62 1 62 61 0 61 278197.188290 0.100000 1 63 1 63 62 0 62 282631.829520 0.100000 0 64 1 64 63 0 63 287065.768610 0.100000 0 65 1 65 64 0 64 291499.174300 0.100000 0 66 1 66 65 0 65 295931.208220 0.100000 0 67 1 67 66 0 66 300363.089140 0.100000 0 68 1 68 67 0 67 304793.664960 0.100000 0 71 1 71 70 0 70 318080.530760 0.100000 0 72 1 72 71 0 71 322507.243500 0.100000 0 73 1 73 72 0 72 326932.654110 0.100000 0 74 1 74 73 0 73 331356.490560 0.100000 0 ! ! R-type K-1=2-1 ! 30 1 29 29 2 28 140754.480070 0.100000 1 31 1 30 30 2 29 145204.529330 0.100000 1 32 1 31 31 2 30 149653.902050 0.100000 1 33 1 32 32 2 31 154102.903400 0.100000 1 34 1 33 33 2 32 158551.281350 0.100000 1 35 1 34 34 2 33 162999.735100 0.100000 0 ! 29 2 28 28 1 27 136317.525610 0.100000 1 30 2 29 29 1 28 140763.372380 0.100000 1 31 2 30 30 1 29 145210.090030 0.100000 1 33 2 32 32 1 31 154104.893710 0.100000 1 35 2 34 34 1 33 163000.286160 0.100000 1 ! 38 2 37 37 1 36 176342.307700 0.100000 0 4.12E-05 38 1 37 37 2 36 176342.307700 0.100000 0 8.25E-05 39 2 38 38 1 37 180788.295500 0.100000 2 8.69E-05 39 1 38 38 2 37 180788.295500 0.100000 2 4.34E-05 40 1 39 39 2 38 185234.313170 0.100000 2 1.08E-04 40 2 39 39 1 38 185234.313170 0.100000 2 5.40E-05 42 1 41 41 2 40 194125.767440 0.100000 2 3.76E-05 42 2 41 41 1 40 194125.767440 0.100000 2 3.76E-05 43 1 42 42 2 41 198570.999980 0.100000 2 3.92E-05 43 2 42 42 1 41 198570.999980 0.100000 2 3.92E-05 44 1 43 43 2 42 203015.696460 0.100000 2 4.06E-05 44 2 43 43 1 42 203015.696460 0.100000 2 4.06E-05 45 1 44 44 2 43 207459.931270 0.100000 2 4.22E-05 45 2 44 44 1 43 207459.931270 0.100000 2 4.22E-05 46 1 45 45 2 44 211903.683470 0.100000 2 4.36E-05 46 2 45 45 1 44 211903.683470 0.100000 2 4.36E-05 48 1 47 47 2 46 220790.063520 0.100000 2 4.63E-05 48 2 47 47 1 46 220790.063520 0.100000 2 4.63E-05 49 1 48 48 2 47 225232.428540 0.100000 2 4.76E-05 49 2 48 48 1 47 225232.428540 0.100000 2 4.76E-05 50 1 49 49 2 48 229674.278210 0.100000 2 4.88E-05 50 2 49 49 1 48 229674.278210 0.100000 2 4.88E-05 51 1 50 50 2 49 234115.679110 0.100000 2 5.00E-05 51 2 50 50 1 49 234115.679110 0.100000 2 5.00E-05 52 1 51 51 2 50 238556.530680 0.100000 2 5.10E-05 52 2 51 51 1 50 238556.530680 0.100000 2 5.10E-05 53 1 52 52 2 51 242996.759770 0.100000 2 5.20E-05 53 2 52 52 1 51 242996.759770 0.100000 2 5.20E-05 54 1 53 53 2 52 247436.393210 0.100000 2 5.30E-05 54 2 53 53 1 52 247436.393210 0.100000 2 5.30E-05 55 1 54 54 2 53 251875.415310 0.100000 0 5.38E-05 55 2 54 54 1 53 251875.415310 0.100000 0 5.38E-05 56 1 55 55 2 54 256313.864470 0.100000 0 5.45E-05 56 2 55 55 1 54 256313.864470 0.100000 0 5.45E-05 57 1 56 56 2 55 260751.589970 0.100000 0 5.52E-05 57 2 56 56 1 55 260751.589970 0.100000 0 5.52E-05 58 1 57 57 2 56 265188.640830 0.100000 0 5.58E-05 58 2 57 57 1 56 265188.640830 0.100000 0 5.58E-05 59 2 58 58 1 57 269624.935560 0.100000 0 1.38E-04 59 1 58 58 2 57 269624.935560 0.100000 0 6.89E-05 60 2 59 59 1 58 274060.457680 0.100000 0 6.94E-05 60 1 59 59 2 58 274060.457680 0.100000 0 1.39E-04 61 2 60 60 1 59 278495.069530 0.100000 0 1.40E-04 61 1 60 60 2 59 278495.069530 0.100000 0 6.98E-05 ! ! R-type K-1=3-2 ! 31 2 29 30 3 28 149953.285820 0.100000 1 32 2 30 31 3 29 154419.658570 0.100000 1 33 2 31 32 3 30 158877.643430 0.100000 1 34 2 32 33 3 31 163330.423400 0.100000 1 35 2 33 34 3 32 167779.886750 0.100000 1 36 2 34 35 3 33 172227.234160 0.100000 1 37 2 35 36 3 34 176673.248980 0.100000 0 38 2 36 37 3 35 181118.939800 0.100000 0 ! 32 3 30 31 2 29 154517.090580 0.100000 0 33 3 31 32 2 30 158940.789500 0.100000 0 34 3 32 33 2 31 163371.043130 0.100000 1 35 3 33 34 2 32 167805.916100 0.100000 1 36 3 34 35 2 33 172243.644930 0.100000 1 37 3 35 36 2 34 176683.200700 0.100000 1 38 3 36 37 2 35 181124.453480 0.100000 1 39 3 37 38 2 36 185566.127300 0.100000 1 ! 43 2 41 42 3 40 203334.455680 0.100000 2 3.58E-05 43 3 41 42 2 40 203334.455680 0.100000 2 3.58E-05 44 2 42 43 3 41 207776.172580 0.100000 0 3.72E-05 44 3 42 43 2 41 207776.172580 0.100000 0 3.72E-05 45 2 43 44 3 42 212218.080860 0.100000 0 3.86E-05 45 3 43 44 2 42 212218.080860 0.100000 0 3.86E-05 46 2 44 45 3 43 216659.506690 0.100000 0 9.75E-05 46 3 44 45 2 43 216659.506690 0.100000 0 4.87E-05 47 2 45 46 3 44 221100.596540 0.100000 0 5.03E-05 47 3 45 46 2 44 221100.596540 0.100000 0 1.01E-04 48 2 46 47 3 45 225541.265810 0.100000 0 1.04E-04 48 3 46 47 2 45 225541.265810 0.100000 0 5.19E-05 49 2 47 48 3 46 229981.480140 0.100000 0 5.34E-05 49 3 47 48 2 46 229981.480140 0.100000 0 1.07E-04 51 2 49 50 3 48 238860.378570 0.100000 0 5.61E-05 51 3 49 50 2 48 238860.378570 0.100000 0 1.12E-04 52 2 50 51 3 49 243298.934840 0.100000 0 1.15E-04 52 3 50 51 2 49 243298.934840 0.100000 0 5.74E-05 53 2 51 52 3 50 247736.805430 0.100000 0 5.85E-05 53 3 51 52 2 50 247736.805430 0.100000 0 1.17E-04 54 2 52 53 3 51 252173.886120 0.100000 0 1.19E-04 54 3 52 53 2 51 252173.886120 0.100000 0 5.96E-05 55 2 53 54 3 52 256610.044110 0.100000 0 6.06E-05 55 3 53 54 2 52 256610.044110 0.100000 0 1.21E-04 +++++-----+++++-----+++++-----++++++++++++++++++++---------------+++++----------++++++++ ----------------------------------------------------------------------------------------