ASFIT version 3.XII.2004 _______________________________________________________________________________ Benzaldehyde, ground state of the parent species _______________________________________________________________________________ Fit of Watson's Hamiltonian --> reduction-A, representation-I.r : A = 5234.3643657071979760076 +- 0.0000545571074814267 B = 1564.2743773831505222915 +- 0.0000221132570925995 C = 1204.6819154962170159706 +- 0.0000161683930780213 DJ = 0.0000685649573538437 +- 0.0000000035843243266 DJK = 0.0001627455512048959 +- 0.0000000283607149843 DK = 0.0007394507595661538 +- 0.0000001662938850992 dJ = 0.0000179591023221445 +- 0.0000000014888414038 dK = 0.0002892867503155672 +- 0.0000001123894289045 Deviation of fit = 0.068282 Weighted deviation of fit = 0.755257 ------------------------------------------------------------------------------------------------------ TRANSITION Observed Obs-Calc Error Note Blend components ------------------------------------------------------------------------------------------------------ ! ! Merged FTMW measurements from Warsaw and Harvard ! ! aR_0,1-type lines ! 1. 3 1 3 2 1 2 7752.2719 -0.0002 0.0020 2. 3 0 3 2 0 2 8207.0738 -0.0004 0.0020 3. 3 2 2 2 2 1 8306.8593 0.0017 0.0020 4. 3 2 1 2 2 0 8406.6476 0.0028 0.0020 5. 3 1 2 2 1 1 8829.9395 -0.0001 0.0020 6. 4 1 4 3 1 3 10309.4761 0.0002 0.0020 7. 4 0 4 3 0 3 10831.4034 0.0000 0.0020 8. 4 2 3 3 2 2 11056.2202 0.0007 0.0020 9. 4 3 2 3 3 1 11122.9490 0.0007 0.0020 10. 4 3 1 3 3 0 11129.5434 0.0011 0.0020 11. 4 2 2 3 2 1 11300.5835 -0.0001 0.0020 12. 4 1 3 3 1 2 11741.2378 -0.0001 0.0020 13. 5 1 5 4 1 4 12846.7075 -0.0004 0.0020 14. 5 0 5 4 0 4 13375.1072 0.0002 0.0020 15. 5 2 4 4 2 3 13788.8803 -0.0007 0.0020 16. 5 4 2 4 4 1 13900.5830 0.0022 0.0030 17. 5 4 1 4 4 0 13900.9034 0.0027 0.0030 18. 5 3 3 4 3 2 13920.1747 0.0000 0.0020 19. 5 3 2 4 3 1 13943.0987 0.0007 0.0020 20. 5 2 3 4 2 2 14258.2008 -0.0004 0.0020 21. 5 1 4 4 1 3 14621.7220 0.0001 0.0020 ! 22. 6 1 6 5 1 5 15362.4557 -0.0002 0.0020 23. 6 0 6 5 0 5 15843.1646 0.0004 0.0020 24. 6 2 5 5 2 4 16500.8965 0.0004 0.0020 25. 6 4 3 5 4 2 16698.7032 0.0015 0.0020 26. 6 4 2 5 4 1 16700.1348 -0.0013 0.0020 27. 6 3 4 5 3 3 16723.1202 0.0008 0.0020 28. 6 3 3 5 3 2 16783.4913 0.0016 0.0020 29. 6 2 4 5 2 3 17269.9756 -0.0004 0.0020 30. 6 1 5 5 1 4 17459.5886 -0.0007 0.0020 ! 31. 7 1 7 6 1 6 17856.9156 -0.0002 0.0020 32. 7 0 7 6 0 6 18255.4059 0.0005 0.0020 33. 7 2 6 6 2 5 19188.6406 -0.0006 0.0020 34. 7 5 3 6 5 2 19471.9805 0.0029 0.0030 35. 7 5 2 6 5 1 19472.0498 0.0001 0.0030 36. 7 4 4 6 4 3 19505.9502 0.0005 0.0020 37. 7 4 3 6 4 2 19510.7022 0.0005 0.0020 38. 7 3 5 6 3 4 19528.4336 -0.0005 0.0020 39. 7 3 4 6 3 3 19661.4268 -0.0010 0.0020 40. 7 1 6 6 1 5 20240.9395 -0.0003 0.0020 41. 7 2 5 6 2 4 20311.0830 -0.0003 0.0020 ! 42. 8 1 8 7 1 7 20331.7354 -0.0001 0.0020 43. 8 0 8 7 0 7 20637.3965 -0.0002 0.0020 44. 8 2 7 7 2 6 21849.0264 0.0008 0.0020 45. 8 5 4 7 5 3 22274.6455 -0.0010 0.0020 46. 8 5 3 7 5 2 22274.9346 0.0007 0.0020 47. 8 4 5 7 4 4 22322.8838 0.0003 0.0020 48. 8 3 6 7 3 5 22331.3311 -0.0005 0.0020 49. 8 4 4 7 4 3 22335.8272 -0.0006 0.0020 50. 8 3 5 7 3 4 22588.5284 0.0005 0.0020 51. 8 1 7 7 1 6 22950.9083 -0.0005 0.0020 52. 8 2 6 7 2 5 23350.1915 0.0001 0.0020 ! 53. 9 1 9 8 1 8 22789.5635 0.0001 0.0020 54. 9 0 9 8 0 8 23010.0547 0.0002 0.0020 55. 9 2 8 8 2 7 24479.7373 -0.0007 0.0020 56. 9 3 6 8 3 5 25574.2305 -0.0013 0.0020 57. 9 1 8 8 1 7 25576.6846 -0.0008 0.0020 58. 9 2 7 8 2 6 26359.4424 -0.0006 0.0020 ! 59. 10 1 10 9 1 9 25233.5244 0.0006 0.0020 60. 10 0 10 9 0 9 25385.3106 0.0006 0.0020 61. 10 2 9 9 2 8 27079.4902 -0.0008 0.0020 62. 10 3 8 9 3 7 27906.5049 -0.0016 0.0020 ! ! bR-type lines ! 63. 1 1 1 0 0 0 6439.0467 0.0011 0.0030 ! 64. 2 1 2 1 0 1 8848.4092 0.0006 0.0020 65. 2 2 1 1 1 0 16907.7569 -0.0019 0.0020 66. 2 2 0 1 1 1 17292.4971 -0.0018 0.0020 ! 67. 3 1 3 2 0 2 11087.9190 -0.0002 0.0020 68. 3 2 2 2 1 1 19317.1172 0.0013 0.0020 69. 3 2 1 2 1 2 20520.8223 -0.0024 0.0020 70. 3 3 1 2 2 0 27546.2871 0.0018 0.0020 71. 3 3 0 2 2 1 27572.5371 0.0003 0.0020 ! 72. 4 1 4 3 0 3 13190.3209 0.0001 0.0020 73. 4 0 4 3 1 3 7950.5584 -0.0001 0.0020 74. 4 2 3 3 1 2 21543.3965 0.0007 0.0020 75. 4 2 2 3 1 3 24069.1348 -0.0014 0.0020 76. 4 4 1 3 3 0 38028.1231 -0.0011 0.0020 ! 77. 5 1 5 4 0 4 15205.6257 0.0004 0.0020 78. 5 0 5 4 1 4 11016.1890 -0.0007 0.0020 79. 5 2 4 4 1 3 23591.0401 0.0011 0.0020 80. 5 4 2 4 3 1 40799.1641 0.0014 0.0020 81. 5 4 1 4 3 2 40807.2188 -0.0004 0.0020 ! 82. 6 1 6 5 0 5 17192.9746 0.0004 0.0020 83. 6 0 6 5 1 5 14012.6456 -0.0003 0.0020 84. 6 2 5 5 1 4 25470.2139 0.0008 0.0020 85. 6 3 4 5 2 3 35347.0996 0.0014 0.0020 86. 6 3 3 5 2 4 36276.7090 0.0004 0.0020 ! 87. 7 1 7 6 0 6 19206.7266 0.0008 0.0020 88. 7 0 7 6 1 6 16905.5948 -0.0006 0.0020 89. 7 2 6 6 1 5 27199.2647 -0.0003 0.0020 90. 7 3 4 6 2 5 39437.2403 0.0000 0.0020 ! 91. 8 1 8 7 0 7 21283.0567 0.0008 0.0020 92. 8 0 8 7 1 7 19686.0752 -0.0011 0.0020 ! 93. 9 1 9 8 0 8 23435.2227 0.0001 0.0020 94. 9 0 9 8 1 8 22364.3955 0.0002 0.0020 ! 95. 10 1 10 9 0 9 25658.6924 0.0005 0.0020 ! ! bQ-type lines ! 96. 2 2 0 2 1 1 11035.4050 -0.0023 0.0020 97. 2 2 1 2 1 2 12089.0284 -0.0025 0.0020 ! 98. 3 2 1 3 1 2 10612.1121 -0.0004 0.0020 99. 3 2 2 3 1 3 12643.6164 0.0000 0.0020 ! 100. 4 2 2 4 1 3 10171.4581 -0.0001 0.0020 101. 4 2 3 4 1 4 13390.3609 0.0008 0.0020 102. 4 3 1 4 2 2 18969.7022 0.0005 0.0020 103. 4 3 2 4 2 3 19331.3047 -0.0008 0.0020 ! 104. 5 1 4 5 0 5 7193.7346 0.0001 0.0020 105. 5 2 3 5 1 4 9807.9390 0.0015 0.0020 106. 5 2 4 5 1 5 14332.5327 -0.0005 0.0020 107. 5 3 2 5 2 3 18654.5987 0.0002 0.0020 108. 5 3 3 5 2 4 19462.5977 -0.0015 0.0020 ! 109. 6 1 5 6 0 6 8810.1602 0.0006 0.0030 110. 6 2 4 6 1 5 9618.3242 0.0001 0.0020 111. 6 2 5 6 1 6 15470.9727 -0.0007 0.0020 112. 6 3 3 6 2 4 18168.1124 0.0002 0.0020 113. 6 3 4 6 2 5 19684.8223 -0.0003 0.0020 114. 6 4 2 6 3 3 26773.0703 -0.0009 0.0020 ! 115. 7 1 6 7 0 7 10795.6934 -0.0007 0.0030 116. 7 2 5 7 1 6 9688.4673 -0.0003 0.0020 117. 7 2 6 7 1 7 16802.7002 0.0014 0.0020 118. 7 3 4 7 2 5 17518.4571 0.0004 0.0020 119. 7 3 5 7 2 6 20024.6163 0.0009 0.0020 120. 7 4 3 7 3 4 26622.3457 0.0006 0.0020 ! 121. 8 2 6 8 1 7 10087.7495 -0.0006 0.0020 122. 8 2 7 8 1 8 18319.9893 0.0004 0.0020 ! !------------------------------------------------------------------------------ ! ! Data from R.K.Kakar, E.A.Reinhart, C.R.Quade, T.Kojima, J.Chem.Phys. ! 52,3803-3813(1970) ! ! Table I = Oklahoma spectrometer ! 123.B 7 6 1 6 6 0 19453.1000 B 0.0183 0.2000 1.0E+00 19453.0819 124.B 7 6 2 6 6 1 19453.1000 B 0.0183 0.2000 1.0E+00 19453.0814 125.B 7 5 2 6 5 1 19472.1000 B 0.0863 0.2000 1.0E+00 19472.0497 126.B 7 5 3 6 5 2 19472.1000 B 0.0863 0.2000 1.0E+00 19471.9776 127. 7 4 3 6 4 2 19511.0000 0.2983 0.2000 128. 7 4 4 6 4 3 19506.1000 0.1503 0.2000 129.E 7 3 4 6 3 3 19661.9000 0.4722 0.2000--excl 130. 7 3 5 6 3 4 19528.3000 -0.1341 0.2000 131.E 7 2 5 6 2 4 20311.5000 0.4167 0.2000--excl 132. 7 2 6 6 2 5 19188.9000 0.2588 0.2000 133. 7 1 6 6 1 5 20240.9000 -0.0398 0.2000 134.E 7 1 7 6 1 6 17857.6000 0.6842 0.2000--excl 135. 7 0 7 6 0 6 18255.7000 0.2946 0.2000 136.B 8 7 1 7 7 0 22230.1000 B 0.3211 0.2000 1.0E+00 22229.7789 137.B 8 7 2 7 7 1 22230.1000 B 0.3211 0.2000 1.0E+00 22229.7788 138.B 8 6 2 7 6 1 22246.7000 B 0.2179 0.2000 1.0E+00 22246.4837 139.B 8 6 3 7 6 2 22246.7000 B 0.2179 0.2000 1.0E+00 22246.4805 140.E 8 5 3 7 5 2 22275.2000 0.2661 0.2000--excl 141.E 8 5 4 7 5 3 22275.2000 0.5535 0.2000--excl 142. 8 4 4 7 4 3 22336.1000 0.2722 0.2000 143. 8 4 5 7 4 4 22322.9000 0.0165 0.2000 144. 8 3 5 7 3 4 22588.6000 0.0721 0.2000 145. 8 3 6 7 3 5 22331.5000 0.1684 0.2000 146. 8 2 6 7 2 5 23350.2000 0.0086 0.2000 147. 8 2 7 7 2 6 21849.2000 0.1744 0.2000 148. 8 1 7 7 1 6 22951.1000 0.1912 0.2000 149. 8 1 8 7 1 7 20331.9000 0.1645 0.2000 150.E 8 0 8 7 0 7 20637.8000 0.4033 0.2000--excl 151.B 9 8 1 8 8 0 25006.7000 B 0.0932 0.2000 1.0E+00 25006.6068 152.B 9 8 2 8 8 1 25006.7000 B 0.0932 0.2000 1.0E+00 25006.6068 153.B 9 7 2 8 7 1 25021.9000 B 0.0369 0.2000 1.0E+00 25021.8632 154.B 9 7 3 8 7 2 25021.9000 B 0.0369 0.2000 1.0E+00 25021.8630 155.B 9 6 3 8 6 2 25045.8000 B 0.1361 0.2000 1.0E+00 25045.6713 156.B 9 6 4 8 6 3 25045.8000 B 0.1361 0.2000 1.0E+00 25045.6566 157.B 9 5 4 8 5 3 25086.2000 B 0.1075 0.2000 1.0E+00 25086.5567 158.B 9 5 5 8 5 4 25086.2000 B 0.1075 0.2000 1.0E+00 25085.6283 159. 9 4 5 8 4 4 25179.8000 -0.1064 0.2000 160. 9 4 6 8 4 5 25149.4000 0.1261 0.2000 161. 9 3 6 8 3 5 25574.1000 -0.1318 0.2000 162. 9 3 7 8 3 6 25126.1000 0.0347 0.2000 163. 9 2 7 8 2 6 26359.5000 0.0570 0.2000 164. 9 2 8 8 2 7 24479.8000 0.0620 0.2000 165. 9 1 8 8 1 7 25576.7000 0.0146 0.2000 166. 9 1 9 8 1 8 22789.6000 0.0366 0.2000 167.E 9 0 9 8 0 8 23010.5000 0.4455 0.2000--excl ! ! Table I = Wyoming spectrometer ! 168.B 10 9 1 9 9 0 27783.5500 B 0.0486 0.1000 1.0E+00 27783.5014 169.B 10 9 2 9 9 1 27783.5500 B 0.0486 0.1000 1.0E+00 27783.5014 170.E 10 8 2 9 8 1 27798.0200 0.2730 0.1000--excl 171.E 10 8 3 9 8 2 27798.0200 0.2730 0.1000--excl 172.B 10 7 3 9 7 2 27818.6600 B -0.0193 0.1000 1.0E+00 27818.6797 173.B 10 7 4 9 7 3 27818.6600 B -0.0193 0.1000 1.0E+00 27818.6790 174.B 10 6 4 9 6 3 27851.3500 B -0.0301 0.1000 1.0E+00 27851.4076 175.B 10 6 5 9 6 4 27851.3500 B -0.0301 0.1000 1.0E+00 27851.3527 176. 10 5 5 9 5 4 27908.4000 0.0109 0.1000 177.E 10 5 6 9 5 5 27906.5000 0.6892 0.1000--excl 178. 10 4 6 9 4 5 28048.8300 -0.0780 0.1000 179. 10 4 7 9 4 6 27983.8600 0.0036 0.1000 180. 10 3 7 9 3 6 28620.8300 0.1230 0.1000 181. 10 3 8 9 3 7 27906.5000 -0.0065 0.1000 182. 10 2 8 9 2 7 29318.3000 -0.0632 0.1000 183. 10 2 9 9 2 8 27079.5500 0.0590 0.1000 184. 10 1 9 9 1 8 28112.5700 0.0562 0.1000 185.B 11 10 1 10 10 0 30560.4000 B -0.0252 0.1000 1.0E+00 30560.4252 186.B 11 10 2 10 10 1 30560.4000 B -0.0252 0.1000 1.0E+00 30560.4252 187.E 11 9 2 10 9 1 30574.2800 0.3519 0.1000--excl 188.E 11 9 3 10 9 2 30574.2800 0.3519 0.1000--excl 189.E 11 8 3 10 8 2 30593.1700 0.2840 0.1000--excl 190.E 11 8 4 10 8 3 30593.1700 0.2841 0.1000--excl 191.E 11 7 4 10 7 3 30620.4400 -0.3315 0.1000--excl 192.E 11 7 5 10 7 4 30620.4400 -0.3286 0.1000--excl 193.B 11 6 5 10 6 4 30664.5700 B 0.1636 0.1000 1.0E+00 30664.4937 194.B 11 6 6 10 6 5 30664.5700 B 0.1636 0.1000 1.0E+00 30664.3192 195. 11 5 6 10 5 5 30742.3200 0.0543 0.1000 196.E 11 5 7 10 5 6 30736.2400 0.3489 0.1000--excl 197. 11 4 7 10 4 6 30950.6600 0.0011 0.1000 198. 11 4 8 10 4 7 30824.2200 0.0714 0.1000 199. 11 3 8 10 3 7 31717.8300 0.1240 0.1000 200. 11 3 9 10 3 8 30666.7600 0.0566 0.1000 201. 11 2 9 10 2 8 32212.0900 0.0459 0.1000 202. 11 2 10 10 2 9 29648.3400 0.1357 0.1000 203. 11 1 10 10 1 9 30564.9000 0.2207 0.1000 204. 11 1 11 10 1 10 27666.7800 0.0338 0.1000 205. 11 0 11 10 0 10 27767.7000 0.0705 0.1000 206.B 12 6 6 11 6 5 33485.5500 B -0.0012 0.1000 1.0E+00 33485.7966 207.B 12 6 7 11 6 6 33485.5500 B -0.0012 0.1000 1.0E+00 33485.3057 208. 12 5 7 11 5 6 33590.4000 -0.1999 0.1000 209. 12 5 8 11 5 7 33576.3500 0.1070 0.1000 210. 12 4 8 11 4 7 33894.7500 0.0987 0.1000 211. 12 4 9 11 4 8 33666.5500 0.1562 0.1000 212. 12 3 9 11 3 8 34841.4800 0.0066 0.1000 213. 12 3 10 11 3 9 33401.3800 0.0393 0.1000 214. 12 2 10 11 2 9 35028.0200 0.0268 0.1000 215. 12 2 11 11 2 10 32187.1500 0.0834 0.1000 216. 12 1 11 11 1 10 32952.4700 0.0886 0.1000 217. 12 1 12 11 1 11 30092.0500 0.0162 0.1000 218. 12 0 12 11 0 11 30157.4500 0.1236 0.1000 219.B 13 12 1 12 12 0 36114.4100 B 0.1382 0.1000 1.0E+00 36114.2718 220.B 13 12 2 12 12 1 36114.4100 B 0.1382 0.1000 1.0E+00 36114.2718 221.B 13 11 2 12 11 1 36126.8300 B 0.0653 0.1000 1.0E+00 36126.7647 222.B 13 11 3 12 11 2 36126.8300 B 0.0653 0.1000 1.0E+00 36126.7647 223.B 13 10 3 12 10 2 36143.2800 B 0.0794 0.1000 1.0E+00 36143.2006 224.B 13 10 4 12 10 3 36143.2800 B 0.0794 0.1000 1.0E+00 36143.2006 225.B 13 9 4 12 9 3 36165.5700 B 0.0921 0.1000 1.0E+00 36165.4779 226.B 13 9 5 12 9 4 36165.5700 B 0.0921 0.1000 1.0E+00 36165.4779 227.E 13 8 5 12 8 4 36197.1300 0.3226 0.1000--excl 228.E 13 8 6 12 8 5 36197.1300 0.3231 0.1000--excl 229.B 13 7 6 12 7 5 36243.0900 B 0.0849 0.1000 1.0E+00 36243.0210 230.B 13 7 7 12 7 6 36243.0900 B 0.0849 0.1000 1.0E+00 36242.9891 231.B 13 6 7 12 6 6 36315.7100 B 0.0413 0.1000 1.0E+00 36316.2939 232.B 13 6 8 12 6 7 36315.7100 B 0.0413 0.1000 1.0E+00 36315.0436 233. 13 5 8 12 5 7 36456.7500 0.0795 0.1000 234. 13 5 9 12 5 8 36426.8400 0.0953 0.1000 235. 13 4 9 12 4 8 36890.9000 0.0544 0.1000 236. 13 4 10 12 4 9 36505.7100 0.0327 0.1000 237. 13 3 10 12 3 9 37960.2300 0.0999 0.1000 238. 13 3 11 12 3 10 36106.1700 0.0917 0.1000 239. 13 2 11 12 2 10 37754.8100 0.0588 0.1000 240. 13 2 12 12 2 11 34698.4600 0.0249 0.1000 241. 13 1 12 12 1 11 35302.1700 0.1141 0.1000 242. 13 1 13 12 1 12 32511.7500 0.0558 0.1000 243. 13 0 13 12 0 12 32553.2400 0.1459 0.1000 244.B 14 13 1 13 13 0 38891.3400 B 0.1745 0.1000 1.0E+00 38891.1655 245.B 14 13 2 13 13 1 38891.3400 B 0.1745 0.1000 1.0E+00 38891.1655 246.B 14 12 2 13 12 1 38903.3600 B 0.0569 0.1000 1.0E+00 38903.3031 247.B 14 12 3 13 12 2 38903.3600 B 0.0569 0.1000 1.0E+00 38903.3031 248.B 14 11 3 13 11 2 38918.9100 B 0.0187 0.1000 1.0E+00 38918.8913 249.B 14 11 4 13 11 3 38918.9100 B 0.0187 0.1000 1.0E+00 38918.8913 250.B 14 10 4 13 10 3 38939.6000 B 0.1874 0.1000 1.0E+00 38939.4126 251.B 14 10 5 13 10 4 38939.6000 B 0.1874 0.1000 1.0E+00 38939.4126 252.B 14 9 5 13 9 4 38967.3800 B 0.1327 0.1000 1.0E+00 38967.2473 253.B 14 9 6 13 9 5 38967.3800 B 0.1327 0.1000 1.0E+00 38967.2472 254.B 14 8 6 13 8 5 39006.4900 B 0.0593 0.1000 1.0E+00 39006.4316 255.B 14 8 7 13 8 6 39006.4900 B 0.0593 0.1000 1.0E+00 39006.4297 256.B 14 7 7 13 7 6 39064.3200 B 0.0115 0.1000 1.0E+00 39064.3538 257.B 14 7 8 13 7 7 39064.3200 B 0.0115 0.1000 1.0E+00 39064.2632 258.E 14 6 8 13 6 7 39155.5000 -1.6439 0.1000--excl 259.E 14 6 9 13 6 8 39155.5000 1.2898 0.1000--excl 260. 14 5 9 13 5 8 39344.9200 -0.0412 0.1000 261. 14 5 10 13 5 9 39286.7400 0.1612 0.1000 262. 14 4 10 13 4 9 39946.8100 -0.0466 0.1000 263. 14 4 11 13 4 10 39336.3300 0.1094 0.1000 264. 14 3 12 13 3 11 38777.8000 0.0172 0.1000 265. 14 2 13 13 2 12 37185.6200 0.0460 0.1000 266. 14 1 13 13 1 12 37638.4800 0.1005 0.1000 267. 14 1 14 13 1 13 34927.5700 0.0655 0.1000 268. 14 0 14 13 0 13 34953.5000 0.1678 0.1000 269. 15 1 14 14 1 13 39978.1500 0.0585 0.1000 270. 15 1 15 14 1 14 37340.8800 0.1187 0.1000 271. 15 0 15 14 0 14 37356.7500 0.0862 0.1000 272. 16 1 16 15 1 15 39752.5200 0.1498 0.1000 273. 16 0 16 15 0 15 39762.2200 0.1644 0.1000 ! ! Table V = Q-branch b-dipole transitions ! 274.E 12 5 7 12 4 8 33726.7500 -0.3854 0.1500--excl 275. 12 5 8 12 4 9 34172.5900 0.1240 0.1500 276. 13 4 10 13 3 11 27753.7900 -0.1999 0.1500 277. 13 5 9 13 4 10 34093.5100 -0.0234 0.1500 278. 14 5 9 14 4 10 32691.2100 0.1451 0.1500 279.E 15 2 14 15 1 15 32687.4800 -1.4728 0.1500--excl 280.E 16 2 15 16 1 16 35037.7400 -1.3340 0.1500--excl 281. 16 5 12 16 4 13 34126.3200 0.1261 0.1500 282. 17 5 13 17 4 14 34311.8400 -0.0457 0.1500 283. 18 5 14 18 4 15 34630.8800 0.0856 0.1500 284. 19 4 16 19 3 17 33964.5500 0.0837 0.1500 285. 20 5 16 20 4 17 35766.0000 0.0628 0.1500 ! !------------------------------------------------------------------------------ ! ! MMW measurements in Warsaw ! ! aR_0,1 type-II bandheads ! 286. 72 0 72 71 0 71 174628.3940 0.0036 0.0500 287. 71 1 70 70 1 69 174627.6710 -0.0154 0.0500 288. 70 2 68 69 2 67 174630.2020 0.0012 0.0500 289. 69 3 66 68 3 65 174639.4230 -0.0188 0.0500 290. 68 4 64 67 4 63 174660.6100 -0.0324 0.0500 291. 67 5 62 66 5 61 174701.7960 -0.0533 0.0500 292. 66 6 60 65 6 59 174775.9440 -0.0622 0.0500 293. 65 7 58 64 7 57 174905.7120 0.0551 0.0500 ! 294. 73 0 73 72 0 72 177035.6400 -0.0234 0.0500 295. 72 1 71 71 1 70 177034.9150 -0.0047 0.0500 296. 71 2 69 70 2 68 177037.2880 0.0060 0.0500 297. 70 3 67 69 3 66 177046.0890 -0.0358 0.0500 298. 69 4 65 68 4 64 177066.4280 -0.0200 0.0500 299. 68 5 63 67 5 62 177105.8540 -0.0263 0.0500 ! 300. 87 1 86 86 1 85 213136.2360 -0.0100 0.0500 301. 85 3 82 84 3 81 213141.5790 -0.0374 0.0500 302. 84 4 80 83 4 79 213152.9480 -0.0291 0.0500 303. 83 5 78 82 5 77 213174.9210 -0.0087 0.0500 304. 82 6 76 81 6 75 213212.9870 -0.0184 0.0500 305. 81 7 74 80 7 73 213275.3280 0.0088 0.0500 306. 80 8 72 79 8 71 213374.2090 -0.0471 0.0500 ! 307. 89 0 89 88 0 88 215543.6060 -0.0797 0.0500 308. 88 1 87 87 1 86 215542.4660 -0.0183 0.0500 309. 86 3 83 85 3 82 215547.5680 -0.0126 0.0500 310. 85 4 81 84 4 80 215558.5240 -0.0123 0.0500 311. 84 5 79 83 5 78 215579.7500 0.0218 0.0500 312. 83 6 77 82 6 76 215616.4110 -0.0396 0.0500 313. 82 7 75 81 7 74 215676.4140 -0.0060 0.0500 314. 81 8 73 80 8 72 215771.2550 -0.0600 0.0500 315. 80 9 71 79 9 70 215919.7200 -0.0987 0.0500 ! 316.B 105 0 105 104 0 104 254033.9580 B 0.0067 0.0500 1.0E+00 254033.7777 317.B 102 3 99 101 3 98 254033.9580 B 0.0067 0.0500 1.0E+00 254034.1249 318.B 104 1 103 103 1 102 254032.1530 B -0.0053 0.0500 1.0E+00 254032.3150 319.B 103 2 101 102 2 100 254032.1530 B -0.0053 0.0500 1.0E+00 254032.0017 320. 101 4 97 100 4 96 254040.3210 -0.0320 0.0500 321. 100 5 95 99 5 94 254052.8620 -0.0078 0.0500 322. 99 6 93 98 6 92 254074.5680 -0.0017 0.0500 323. 98 7 91 97 7 90 254109.3560 0.0056 0.0500 324. 97 8 89 96 8 88 254162.5810 0.0149 0.0500 325. 96 9 87 95 9 86 254241.7920 0.0299 0.0500 326. 95 10 85 94 10 84 254358.0280 0.0978 0.0500 327. 94 11 83 93 11 82 254527.7630 -0.0669 0.0500 ! 328. 134 0 134 133 0 133 323741.0140 0.0726 0.0500 329. 133 1 132 132 1 131 323739.2130 -0.0026 0.0500 330. 132 2 130 131 2 129 323737.9220 -0.0398 0.0500 331. 131 3 128 130 3 127 323737.9220 0.0308 0.0500 332. 130 4 126 129 4 125 323739.9110 0.0399 0.0500 333. 129 5 124 128 5 123 323745.0410 0.0770 0.0500 334. 128 6 122 127 6 121 323754.5180 0.0374 0.0500 335. 127 7 120 126 7 119 323770.0290 -0.0203 0.0500 336. 126 8 118 125 8 117 323793.7030 -0.0093 0.0500 337. 125 9 116 124 9 115 323828.0180 -0.0399 0.0500 338. 124 10 114 123 10 113 323876.4440 0.0347 0.0500 339. 121 13 108 120 13 107 324156.6030 -0.0012 0.0500 ! ! higher K-1 tails of aR_0,1-type lines for a given J ! 340. 59 11 48 58 11 47 174609.7730 -0.0477 0.0500 ! 341. 60 12 48 59 12 47 177091.2550 -0.0284 0.0500 ! 342. 61 10 51 60 10 50 175143.3980 -0.0355 0.0500 343. 61 12 50 60 12 49 174783.5970 0.0106 0.0500 344. 61 14 48 60 14 47 174551.3130 -0.0015 0.0500 345. 61 14 47 60 14 46 175065.8490 -0.0025 0.0500 ! 346. 62 11 52 61 11 51 175646.4830 0.0677 0.0500 347. 62 15 47 61 15 46 176931.9740 0.0023 0.0500 348. 62 15 48 61 15 47 176817.1910 -0.0354 0.0500 349. 62 17 46 61 17 45 175552.7230 -0.0366 0.0500 350. 62 17 45 61 17 44 175554.1150 -0.0276 0.0500 351. 62 18 45 61 18 44 175105.6360 0.0228 0.0500 352. 62 19 44 61 19 43 174741.9600 0.0134 0.0500 ! 353. 63 9 54 62 9 53 175649.3260 0.0306 0.0500 354. 63 10 54 62 10 53 175452.3780 -0.1051 0.0500 355. 63 21 42 62 21 41 177074.3260 0.0234 0.0500 356. 63 22 41 62 22 40 176845.6790 0.0010 0.0500 357. 63 32 31 62 32 30 175647.8960 0.0791 0.0500 358. 63 33 30 62 33 29 175584.4170 0.0764 0.0500 359. 63 34 29 62 34 28 175526.2890 0.0129 0.0500 360. 63 35 28 62 35 27 175473.0140 0.0223 0.0500 361. 63 36 27 62 36 26 175423.9810 0.0355 0.0500 362. 63 37 26 62 37 25 175378.7720 0.1013 0.0500 363. 63 38 25 62 38 24 175336.8390 0.0762 0.0500 364. 63 40 23 62 40 22 175261.7550 0.0696 0.0500 365. 63 41 22 62 41 21 175228.0460 0.1066 0.0500 366. 63 42 21 62 42 20 175196.4810 0.0860 0.0500 367. 63 43 20 62 43 19 175166.8770 0.0340 0.0500 368. 63 45 18 62 45 17 175113.0470 0.0516 0.0500 ! 369. 72 14 58 71 14 57 213377.3360 0.0150 0.0500 ! 370. 73 13 60 72 13 59 214035.1040 0.0195 0.0500 371. 73 15 58 72 15 57 214016.1520 0.0564 0.0500 ! 372. 74 15 60 73 15 59 212972.5870 -0.0129 0.0500 373. 74 16 58 73 16 57 214136.7430 -0.0388 0.0500 374. 74 16 59 73 16 58 212685.8170 -0.0109 0.0500 ! 375. 75 12 63 74 12 62 213087.4630 -0.0235 0.0500 376. 75 17 58 74 17 57 215294.4330 0.0110 0.0500 377. 75 18 57 74 18 56 214053.0240 -0.0396 0.0500 378. 75 18 58 74 18 57 213994.3860 -0.0100 0.0500 379. 75 19 57 74 19 56 213227.3930 -0.0340 0.0500 380. 75 19 56 74 19 55 213234.5740 -0.0052 0.0500 ! 381. 76 12 64 75 12 63 215244.9840 0.0215 0.0500 382. 76 20 57 75 20 56 215592.0950 0.0111 0.0500 383. 76 24 52 75 24 51 213927.6440 -0.0056 0.0500 384. 76 25 51 75 25 50 213651.3170 -0.0012 0.0500 385. 76 27 49 75 27 48 213196.9940 0.0184 0.0500 386. 76 28 48 75 28 47 213008.2100 -0.0140 0.0500 387. 76 29 47 75 29 46 212839.8260 0.0231 0.0500 388. 76 30 46 75 30 45 212688.7180 -0.0065 0.0500 389. 76 31 45 75 31 44 212552.5570 0.0009 0.0500 390. 76 32 44 75 32 43 212429.3120 0.0178 0.0500 ! 391. 77 25 52 76 25 51 216545.3070 -0.0051 0.0500 392. 77 30 47 76 30 46 215541.0090 -0.0354 0.0500 393. 77 31 46 76 31 45 215399.1990 -0.0077 0.0500 394. 77 32 45 76 32 44 215270.8400 -0.0142 0.0500 395. 77 48 29 76 48 28 214178.0600 -0.0223 0.0500 396. 77 49 28 76 49 27 214141.5090 0.0811 0.0500 397. 77 50 27 76 50 26 214106.6960 -0.0296 0.0500 398. 77 51 26 76 51 25 214073.7890 -0.0282 0.0500 399. 77 53 24 76 53 23 214012.7860 -0.0384 0.0500 400. 77 58 19 76 58 18 213883.1510 -0.0722 0.0500 401. 77 59 18 76 59 17 213860.4690 -0.0252 0.0500 402. 77 60 17 76 60 16 213838.6370 -0.0186 0.0500 403. 77 61 16 76 61 15 213817.5840 -0.0611 0.0500 404. 77 62 15 76 62 14 213797.4000 -0.0056 0.0500 405. 77 65 12 76 65 11 213740.7810 -0.0257 0.0500 ! 406. 78 10 68 77 10 67 213779.1980 -0.0151 0.0500 407. 78 11 68 77 11 67 213773.9860 0.0054 0.0500 408. 78 11 67 77 11 66 216558.3480 -0.0469 0.0500 ! 409. 112 22 91 111 22 90 323756.6480 0.0546 0.0500 410. 114 29 85 113 29 84 323734.1380 -0.0248 0.0500 411. 115 34 81 114 34 80 324197.8400 -0.0416 0.0500 412. 115 35 80 114 35 79 323844.1850 -0.0299 0.0500 ! ! ! Miscellaneous bR-type lines ! 413. 18 17 2 17 16 1 176881.6280 -0.0532 0.0500 414. 20 16 5 19 15 4 174744.4370 -0.0100 0.0500 415. 23 15 9 22 14 8 175370.7270 -0.0649 0.0500 416. 23 20 3 22 19 4 213828.6560 -0.0297 0.0500 417. 24 20 4 23 19 5 216604.4540 -0.0155 0.0500 418. 31 17 15 30 16 14 212905.9230 0.0020 0.0500 419. 37 15 23 36 14 22 213830.6090 0.0125 0.0500 420.B 40 14 27 39 13 26 213979.3690 B 0.0283 0.0500 1.0E+00 213979.2276 421.B 40 14 26 39 13 27 213979.3690 B 0.0283 0.0500 1.0E+00 213979.4539 422. 73 13 61 72 12 60 213181.3470 0.0103 0.0500 423. 76 12 64 75 13 63 213014.8500 -0.0117 0.0500 424. 77 11 66 76 12 65 214003.9920 0.0261 0.0500 425. 78 10 68 77 11 67 213763.9040 0.0031 0.0500 426. 78 11 68 77 10 67 213789.2350 -0.0579 0.0500 427. 49 25 25 48 24 24 324264.8440 -0.0124 0.0500 ! ! bQ-type lines ! 428. 68 24 44 68 23 45 177026.2490 0.0227 0.0500 429. 69 24 45 69 23 46 176796.3060 0.0648 0.0500 430. 74 24 50 74 23 51 175468.3780 0.0621 0.0500 431. 71 29 42 71 28 43 216728.2230 -0.0274 0.0500 432. 72 29 43 72 28 44 216586.2190 -0.0041 0.0500 433. 78 29 49 78 28 50 215594.6970 0.0312 0.0500 434. 79 29 50 79 28 51 215404.0240 -0.0403 0.0500 435. 80 29 51 80 28 52 215205.6450 0.0693 0.0500 436. 85 29 56 85 28 57 214085.4240 0.0434 0.0500 437. 86 29 57 86 28 58 213833.6710 -0.0943 0.0500 438. 89 29 60 89 28 61 213018.0840 0.0249 0.0500 439. 90 29 61 90 28 62 212724.6700 -0.0383 0.0500 440. 91 29 62 91 28 63 212419.9960 -0.0200 0.0500 441. 104 8 96 104 7 97 212761.6770 0.0736 0.0500 ------------------------------------------------------------------------------------------------------ Sigma = 0.068282 387 Distinct lines in fit Sigma.w = 0.755257 379 Degrees of freedom A /MHz 5234.364365(54) LJK /mHz 0.0 B /MHz 1564.274377(22) LKKJ/mHz 0.0 C /MHz 1204.681915(16) LK /mHz 0.0 DJ /kHz 0.0685649(35) lJ /mHz 0.0 DJK /kHz 0.162745(28) lJK /mHz 0.0 DK /kHz 0.73945(16) lKJ /mHz 0.0 dJ /kHz 0.0179591(14) lK /mHz 0.0 dK /kHz 0.28928(11) PJ /microHz 0.0 HJ / Hz 0.0 PJJK /microHz 0.0 HJK / Hz 0.0 PJK /microHz 0.0 HKJ / Hz 0.0 PKJ /microHz 0.0 HK / Hz 0.0 PKKJ /microHz 0.0 hJ / Hz 0.0 PK /microHz 0.0 hJK / Hz 0.0 pJ /microHz 0.0 hK / Hz 0.0 pJJK /microHz 0.0 LJ /mHz 0.0 pJK /microHz 0.0 LJJK/mHz 0.0 pKKJ /microHz 0.0 pK /microHz 0.0 CORRELATION COEFFICIENTS, C.ij: A B C DJ DJK DK dJ dK A 1.0000 B -0.0066 1.0000 C 0.0203 -0.1243 1.0000 DJ -0.0153 0.2686 -0.0095 1.0000 DJK 0.0027 -0.0264 0.1066 -0.6868 1.0000 DK 0.2575 -0.0683 -0.0504 0.2857 -0.6030 1.0000 dJ -0.0137 0.3494 -0.1949 0.8202 -0.5671 0.2807 1.0000 dK -0.0249 0.1066 -0.0910 0.8334 -0.5509 0.1503 0.5457 1.0000 Mean value of |C.ij|, i.ne.j = 0.2522 Mean value of C.ij, i.ne.j = 0.0355 Distribution of values of |C.ij|, i.ne.j: 10 20 30 40 50 60 ....,....|....,....|....,....|....,....|....,....|....,....|....,.. 8 <0.05 ******** 3 <0.10 *** 3 <0.15 *** 2 <0.20 ** 0 <0.25 4 <0.30 **** 1 <0.35 * 0 <0.40 0 <0.45 0 <0.50 1 <0.55 * 2 <0.60 ** 1 <0.65 * 1 <0.70 * 0 <0.75 0 <0.80 2 <0.85 ** 0 <0.90 0 <0.95 0 <1.00 _______________________________________________________________________________ There are no influential transitions with hjj > 0.500 mean of all values = 0.0193 WORST FITTING LINES (line number=(o-c)/error): 203= 2.2 365= 2.1 354= -2.1 362= 2.0 208= -2.0 315= -2.0 326= 2.0 _______________________________________________________________________________