isoquinoline ground state Tue Oct 03 09:14:02 2017 -------------------------------------------------------------------------------------========= obs o-c error blends Notes o-c wt / instead of : below denotes (o-c)>3*err -------------------------------------------------------------------------------------========= ! ! supersonic expansion, cavity FTMW ! 1: 3 2 2 3 2 2 1 2 6391.1739 0.0011 0.002 2: 3 2 2 4 2 2 1 3 6392.3034 0.0010 0.002 3: 3 2 2 2 2 2 1 1 6392.9288 -0.0015 0.002 ! 4: 3 2 1 3 2 2 0 2 6554.0833 -0.0005 0.002 5: 3 2 1 4 2 2 0 3 6555.1015 -0.0011 0.002 ! 6: 4 1 4 4 3 1 3 3 7757.6001 0.0011 0.002 7: 4 1 4 3 3 1 3 2 7757.6961 -0.0002 0.002 8: 4 1 4 5 3 1 3 4 7757.7819 0.0006 0.002 ! 9: 4 0 4 4 3 0 3 3 8137.9483 0.0000 0.002 10: 4 0 4 3 3 0 3 2 8138.0201 0.0005 0.002 11: 4 0 4 5 3 0 3 4 8138.1049 -0.0001 0.002 12: 4 0 4 3 3 0 3 3 8139.8444 -0.0018 0.002 ! 13: 4 2 3 4 3 2 2 3 8489.8384 0.0000 0.002 14: 4 2 3 5 3 2 2 4 8490.3343 -0.0004 0.002 15: 4 2 3 3 3 2 2 2 8490.4612 -0.0005 0.002 ! 16: 4 3 2 4 3 3 1 3 8596.6388 -0.0007 0.002 17: 4 3 2 5 3 3 1 4 8597.6540 0.0022 0.002 18: 4 3 2 3 3 3 1 2 8598.0487 -0.0006 0.002 19: 4 3 1 4 3 3 0 3 8615.5022 0.0012 0.002 20: 4 3 1 5 3 3 0 4 8616.5030 0.0022 0.002 ! 21: 5 1 5 5 4 1 4 4 9638.0676 0.0006 0.002 22: 5 1 5 4 4 1 4 3 9638.1259 0.0010 0.002 23: 5 1 5 6 4 1 4 5 9638.1884 0.0000 0.002 ! 24: 5 0 5 5 4 0 4 4 9956.7203 0.0009 0.002 25: 5 0 5 4 4 0 4 3 9956.8142 -0.0010 0.002 26: 5 0 5 6 4 0 4 5 9956.8662 0.0001 0.002 ! 27: 5 3 3 5 4 3 2 4 10766.0418 -0.0010 0.002 28: 5 3 3 6 4 3 2 5 10766.5647 0.0015 0.002 29: 5 3 3 4 4 3 2 3 10766.6963 0.0011 0.002 30: 5 3 2 5 4 3 1 4 10830.6879 0.0000 0.002 31: 5 3 2 6 4 3 1 5 10831.1787 -0.0001 0.002 32: 5 3 2 4 4 3 1 3 10831.3034 -0.0013 0.002 ! 33: 2 2 0 1 1 1 1 1 10875.6347 -0.0047 0.002 34: 2 2 0 1 1 1 1 2 10875.6831 0.0045 0.002 35: 2 2 0 1 1 1 1 0 10875.7339 -0.0019 0.002 36: 2 2 0 3 1 1 1 2 10876.3455 0.0000 0.002 37: 2 2 0 2 1 1 1 1 10877.5054 -0.0021 0.002 38: 2 2 0 2 1 1 1 2 10877.5471 0.0005 0.002 ! 39: 5 1 4 5 4 1 3 4 11299.2970 0.0005 0.002 40: 5 1 4 4 4 1 3 3 11299.4285 0.0014 0.002 0.0006 0.50 41: 5 1 4 6 4 1 3 5 11299.4285 -0.0002 0.002 0.0006 0.50 ! 42: 6 1 6 6 5 1 5 5 11492.2680 -0.0003 0.002 43: 6 1 6 5 5 1 5 4 11492.3139 0.0002 0.002 44: 6 1 6 7 5 1 5 6 11492.3592 -0.0001 0.002 ! 45: 6 0 6 6 5 0 5 5 11722.8793 0.0016 0.002 46: 6 0 6 5 5 0 5 4 11722.9641 -0.0001 0.002 47: 6 0 6 7 5 0 5 6 11723.0013 0.0000 0.002 ! 48: 6 2 5 6 5 2 4 5 12598.3146 -0.0006 0.002 49: 6 2 5 7 5 2 4 6 12598.5040 0.0042 0.002 0.0013 0.50 50: 6 2 5 5 5 2 4 4 12598.5040 -0.0017 0.002 0.0013 0.50 ! 51: 7 1 7 7 6 1 6 6 13324.2708 0.0008 0.002 52: 7 1 7 6 6 1 6 5 13324.3098 0.0013 0.002 53: 7 1 7 8 6 1 6 7 13324.3433 0.0001 0.002 ! 54: 6 1 5 6 5 1 4 5 13397.5366 0.0013 0.002 55: 6 1 5 5 5 1 4 4 13397.6613 0.0005 0.002 -0.0003 0.50 56: 6 1 5 7 5 1 4 6 13397.6613 -0.0012 0.002 -0.0003 0.50 ! 57: 3 2 1 2 2 1 2 1 13514.3358 -0.0044 0.002 58: 3 2 1 4 2 1 2 3 13515.0080 0.0000 0.002 59: 3 2 1 3 2 1 2 2 13516.2772 0.0002 0.002 ! 60: 6 2 4 6 5 2 3 5 13652.4525 0.0020 0.002 61: 6 2 4 7 5 2 3 6 13652.5291 -0.0001 0.002 -0.0008 0.50 62: 6 2 4 5 5 2 3 4 13652.5291 -0.0013 0.002 -0.0008 0.50 -------------------------------------------------------------------------------- PARAMETERS IN FIT (values truncated and Nlines statistics): 10000 /MHz [3199.000208195] 1 20000 /MHz [1237.931586883] 2 30000 /MHz [892.753595089] 3 200 /MHz [-0.0000188548] 4 1100 /MHz [-0.000047004] 5 2000 /MHz [-0.0001572] 6 40100 /MHz [-0.0000054543] 7 41000 /MHz [-0.000061465] 8 110010000 /MHz -5.2671(32) 9 110040000 /MHz -0.8126(11) 10 110610000 /MHz 2.81(57) 11 MICROWAVE AVG = 0.000069 MHz, IR AVG = 0.00000 MICROWAVE RMS = 0.001455 MHz, IR RMS = 0.00000 END OF ITERATION 1 OLD, NEW RMS ERROR= 0.72738 0.72738 distinct frequency lines in fit: 58 distinct parameters of fit: 3 upper state lower state overall limits of quantum number 1: 2 7 1 6 1 7 limits of quantum number 2: 0 3 0 3 0 3 limits of quantum number 3: 0 7 0 6 0 7 limits of quantum number 4: 1 8 0 7 0 8 frequency range: 6391 13652 PARAMETERS IN FIT WITH STANDARD ERRORS ON THOSE THAT ARE FITTED: (values rounded and degrees of freedom, Ndegf=Nlines-Nconst, statistics) 10000 /MHz [3199.000208195] 1 20000 /MHz [1237.931586883] 2 30000 /MHz [892.753595089] 3 200 /MHz [-0.0000188548] 4 1100 /MHz [-0.000047004] 5 2000 /MHz [-0.0001572] 6 40100 /MHz [-0.0000054543] 7 41000 /MHz [-0.000061465] 8 110010000 /MHz -5.2671(23) 9 110040000 /MHz -0.81264(87) 10 110610000 /MHz 2.81(42) 11 CORRELATION COEFFICIENTS, C.ij: 1.0000 -0.1416 1.0000 0.0079 0.0541 1.0000 Mean value of |C.ij|, i.ne.j = 0.0679 Mean value of C.ij, i.ne.j = -0.0265 No correlations with absolute value greater than 0.9950 Worst fitted lines (obs-calc/error): 33: -2.4 34: 2.2 57: -2.2 17: 1.1 20: 1.1 37: -1.0 60: 1.0 35: -0.9 12: -0.9 45: 0.8 3: -0.8 28: 0.8 54: 0.6 32: -0.6 52: 0.6 49: 0.6 19: 0.6 1: 0.6 6: 0.6 29: 0.6 5: -0.6 25: -0.5 22: 0.5 27: -0.5 2: 0.5 24: 0.4 51: 0.4 61: -0.4 16: -0.3 40: 0.3 8: 0.3 21: 0.3 18: -0.3 48: -0.3 4: -0.2 10: 0.2 15: -0.2 39: 0.2 38: 0.2 14: -0.2 55: -0.2 42: -0.1 43: 0.1 59: 0.1 7: -0.1 46: -0.1 44: -0.1 11: -0.1 53: 0.1 26: 0.1 33: 2 2 0 1 1 1 1 1 10875.6347 -0.0047 0.002 34: 2 2 0 1 1 1 1 2 10875.6831 0.0045 0.002 57: 3 2 1 2 2 1 2 1 13514.3358 -0.0044 0.002 17: 4 3 2 5 3 3 1 4 8597.6540 0.0022 0.002 20: 4 3 1 5 3 3 0 4 8616.5030 0.0022 0.002 37: 2 2 0 2 1 1 1 1 10877.5054 -0.0021 0.002 60: 6 2 4 6 5 2 3 5 13652.4525 0.0020 0.002 35: 2 2 0 1 1 1 1 0 10875.7339 -0.0019 0.002 12: 4 0 4 3 3 0 3 3 8139.8444 -0.0018 0.002 45: 6 0 6 6 5 0 5 5 11722.8793 0.0016 0.002 _____________________________________ __________________________________________/ SPFIT output reformatted with PIFORM