Camphor ground state, combined supersonic FTMW and room-temperature MMW ------------------------------------------------------------------------------- number of transitions: 257 number of constants : 8 ------------------------------------------------------------------------------- 1 1446.9689772607293889450 A Reduction-A, Representation-I.r 1 1183.3671109882027394633 B 1 1097.1010318493258637318 C 1 0.0000334804308358217 DJ 1 0.0000836810803296517 DJK 1 -0.0000655816166213157 DK 1 0.0000028637806086817 dJ 1 0.0000248585130111498 dK ------------------------------------------------------------------------ J' K-1' K+1' J K-1 K+1 frequency error fit ? ------------------------------------------------------------------------ ! ! Supersonic expansion FTMW spectra ! ! a-type transitions ! 3 1 3 2 1 2 6701.752600 0.002000 1 3 0 3 2 0 2 6774.254200 0.002000 1 3 1 2 2 1 1 6958.158500 0.002000 1 4 1 4 3 1 3 8919.513400 0.002000 1 4 0 4 3 0 3 8975.681800 0.002000 1 4 2 3 3 2 2 9107.763900 0.002000 1 4 3 2 3 3 1 9151.676100 0.002000 1 4 1 3 3 1 2 9250.654900 0.002000 1 4 2 2 3 2 1 9253.678500 0.002000 1 5 1 5 4 1 4 11128.703500 0.002000 1 5 0 5 4 0 4 11162.934800 0.002000 1 5 2 4 4 2 3 11362.617200 0.002000 1 5 3 3 4 3 2 11443.138400 0.002000 1 5 3 2 4 3 1 11488.681700 0.002000 1 5 1 4 4 1 3 11514.458800 0.002000 1 5 2 3 4 2 2 11599.937300 0.002000 1 6 1 6 5 1 5 13331.410200 0.002000 1 6 0 6 5 0 5 13349.164000 0.002000 1 6 2 5 5 2 4 13604.411200 0.002000 1 6 3 4 5 3 3 13729.708800 0.002000 1 6 4 3 5 4 2 13741.014300 0.002000 1 6 1 5 5 1 4 13741.902100 0.002000 1 6 4 2 5 4 1 13749.988200 0.002000 1 6 3 3 5 3 2 13836.546300 0.002000 1 6 2 4 5 2 3 13929.050400 0.002000 1 7 1 7 6 1 6 15529.952800 0.002000 1 7 0 7 6 0 6 15538.285100 0.002000 1 7 1 6 6 1 5 15937.009000 0.002000 1 7 2 6 6 2 5 15833.025200 0.002000 1 7 3 5 6 3 4 16006.992900 0.002000 1 7 5 3 6 5 2 16027.667800 0.002000 1 7 4 4 6 4 3 16042.195800 0.002000 1 7 4 3 6 4 2 16070.314700 0.002000 1 7 3 4 6 3 3 16202.403300 0.002000 1 7 2 5 6 2 4 16229.824900 0.002000 1 8 1 8 7 1 7 17726.167100 0.002000 1 8 0 8 7 0 7 17729.837400 0.002000 1 8 2 7 7 2 6 18049.912800 0.002000 1 8 1 7 7 1 6 18116.163000 0.002000 1 8 3 6 7 3 5 18271.528500 0.002000 1 8 4 4 7 4 3 18411.915700 0.002000 1 8 2 6 7 2 5 18493.912700 0.002000 1 ! ! b-type transitions ! 4 0 4 3 1 3 8852.916700 0.002000 1 4 1 4 3 0 3 9042.281500 0.002000 1 4 3 2 3 2 1 10610.516800 0.002000 1 4 3 1 3 2 2 10711.909300 0.002000 1 5 0 5 4 1 4 11096.336900 0.002000 1 5 1 5 4 0 4 11195.302500 0.002000 1 4 4 0 3 3 1 11273.113800 0.002000 1 5 2 4 4 1 3 11893.771900 0.002000 1 5 3 3 4 2 2 12799.976300 0.002000 1 5 3 2 4 2 3 13092.829700 0.002000 1 6 0 6 5 1 5 13316.796900 0.002000 1 6 1 6 5 0 5 13363.776200 0.002000 1 5 4 2 4 3 1 13546.874500 0.002000 1 5 4 1 4 3 2 13565.520500 0.002000 1 5 5 1 4 4 0 14165.703400 0.002000 1 7 0 7 6 1 6 15523.677500 0.002000 1 7 1 7 6 0 6 15544.565300 0.002000 1 6 4 3 5 3 2 15799.205700 0.002000 1 6 4 2 5 3 3 15872.369800 0.002000 1 ! ! c-type transitions ! 4 2 2 3 1 2 10012.805100 0.002000 1 4 3 1 3 2 1 10626.828800 0.002000 1 4 3 2 3 2 2 10695.597500 0.002000 1 5 2 3 4 1 3 12362.091100 0.002000 1 5 3 3 4 2 3 13030.971800 0.003000 1 5 4 2 4 3 2 13563.187600 0.002000 1 5 4 1 4 3 1 13549.209300 0.002000 1 ! ! Room-temperature MMW spectra ! ! a-type transitions in order of increasing K-1 ! 84 0 84 83 0 83 184420.458000 0.050000 1 85 0 85 84 0 84 186612.268000 0.050000 1 89 0 89 88 0 88 195379.026000 0.050000 1 90 0 90 89 0 89 197570.468000 0.050000 1 92 0 92 91 0 91 201953.327000 0.050000 1 93 0 93 92 0 92 204144.691000 0.050000 1 94 0 94 93 0 93 206335.936000 0.050000 1 97 0 97 96 0 96 212909.417000 0.050000 1 98 0 98 97 0 97 215100.473000 0.050000 1 101 0 101 100 0 100 221673.121000 0.050000 1 79 1 78 78 1 77 173807.258000 0.050000 1 84 1 83 83 1 82 184766.981000 0.050000 1 88 1 87 87 1 86 193533.909000 0.050000 1 89 1 88 88 1 87 195725.419000 0.050000 1 90 1 89 89 1 88 197916.901000 0.050000 1 94 1 93 93 1 92 206682.316000 0.050000 1 96 1 95 95 1 94 211064.666000 0.050000 1 79 2 77 78 2 76 174153.985000 0.050000 1 84 2 82 83 2 81 185113.747000 0.050000 1 88 2 86 87 2 85 193880.360000 0.050000 1 89 2 87 88 2 86 196071.950000 0.050000 1 96 2 94 95 2 93 211410.986000 0.050000 1 98 2 96 97 2 95 215792.978000 0.050000 1 100 2 98 99 2 97 220174.734000 0.050000 1 84 3 81 83 3 80 185460.483000 0.050000 1 88 3 85 87 3 84 194226.986000 0.050000 1 95 3 92 94 3 91 209566.295000 0.050000 1 96 3 93 95 3 92 211757.410000 0.050000 1 79 4 75 78 4 74 174848.028000 0.050000 1 84 4 80 83 4 79 185807.441000 0.050000 1 89 4 85 88 4 84 196765.378000 0.050000 1 92 4 88 91 4 87 203339.417000 0.050000 1 93 4 89 92 4 88 205530.646000 0.050000 1 96 4 92 95 4 91 212103.945000 0.050000 1 84 5 79 83 5 78 186154.642000 0.050000 1 89 5 84 88 5 83 197112.356000 0.050000 1 93 5 88 92 5 87 205877.433000 0.050000 1 84 6 78 83 6 77 186502.276000 0.050000 1 93 6 87 92 6 86 206224.723000 0.050000 1 95 6 89 94 6 88 210606.767000 0.050000 1 78 7 71 77 7 70 173699.939000 0.050000 1 90 7 83 89 7 82 199998.787000 0.050000 1 93 7 86 92 7 85 206572.287000 0.050000 1 94 7 87 93 7 86 208763.260000 0.050000 1 98 7 91 97 7 90 217526.669000 0.050000 1 83 8 75 82 8 74 185007.470000 0.050000 1 87 8 79 86 8 78 193773.201000 0.050000 1 78 9 69 77 9 68 174399.382000 0.050000 1 83 9 74 82 9 73 185357.041000 0.050000 1 94 9 85 93 9 84 209459.614000 0.050000 1 95 9 86 94 9 85 211650.547000 0.050000 1 78 10 68 77 10 67 174750.767000 0.050000 1 83 10 73 82 10 72 185707.553000 0.050000 1 92 10 82 91 10 81 205427.188000 0.050000 1 83 11 72 82 11 71 186059.279000 0.050000 1 92 11 81 91 11 80 205777.402000 0.050000 1 96 11 85 95 11 84 214539.806000 0.050000 1 82 12 70 81 12 69 184221.534000 0.050000 1 83 12 71 82 12 70 186412.351000 0.050000 1 90 12 79 89 12 78 201395.880000 0.050000 1 92 12 80 91 12 79 206128.666000 0.050000 1 87 13 74 86 13 73 195529.190000 0.050000 1 88 13 75 87 13 74 197719.631000 0.050000 1 92 13 79 91 13 78 206481.112000 0.050000 1 77 14 63 76 14 62 173985.153000 0.050000 1 86 14 72 85 14 71 193694.704000 0.050000 1 82 14 69 81 14 68 184576.925000 0.050000 1 87 14 73 86 14 72 195884.830000 0.050000 1 89 14 75 88 14 74 200264.964000 0.050000 1 90 14 76 89 14 75 202455.045000 0.050000 1 92 14 78 91 14 77 206835.107000 0.050000 1 93 14 79 92 14 78 209025.210000 0.050000 1 95 14 81 94 14 80 213405.221000 0.050000 1 82 15 67 81 15 66 185295.037000 0.050000 1 88 15 73 87 15 72 198432.330000 0.050000 1 93 15 78 92 15 77 209380.742000 0.050000 1 95 15 80 94 15 79 213760.120000 0.050000 1 96 15 81 95 15 80 215949.727000 0.050000 1 82 16 66 81 16 65 185659.138000 0.050000 1 91 16 75 90 16 74 205359.880000 0.050000 1 95 16 79 94 16 78 214116.887000 0.050000 1 82 17 65 81 17 64 186027.560000 0.050000 1 87 17 70 86 17 69 196967.250000 0.050000 1 91 17 74 90 17 73 205721.214000 0.050000 1 92 17 76 91 17 75 207549.105000 0.050000 1 94 17 77 93 17 76 212287.211000 0.050000 1 81 18 63 80 18 62 184215.859000 0.050000 1 82 18 64 81 18 63 186401.746000 0.050000 1 87 18 69 86 18 68 197335.540000 0.050000 1 91 18 73 90 18 72 206085.853000 0.050000 1 93 18 75 92 18 74 210461.753000 0.050000 1 94 18 76 93 18 75 212649.776000 0.050000 1 98 18 80 97 18 79 221402.679000 0.050000 1 81 19 62 80 19 61 184599.365000 0.050000 1 86 19 67 85 19 66 195523.126000 0.050000 1 87 19 68 86 19 67 197709.028000 0.050000 1 91 19 72 90 19 71 206454.660000 0.050000 1 93 19 74 92 19 73 210828.764000 0.050000 1 76 20 57 75 20 56 173689.893000 0.050000 1 81 20 61 80 20 60 184993.412000 0.050000 1 88 20 68 87 20 67 200273.414000 0.050000 1 89 20 69 88 20 68 202458.246000 0.050000 1 91 20 71 90 20 70 206828.780000 0.050000 1 92 20 72 91 20 71 209014.390000 0.050000 1 94 20 74 93 20 73 213386.495000 0.050000 1 76 21 55 75 21 54 174551.608000 0.050000 1 76 21 56 75 21 55 174103.739000 0.050000 1 92 21 71 91 21 70 209393.284000 0.050000 1 94 21 73 93 21 72 213762.353000 0.050000 1 95 21 74 94 21 73 215947.366000 0.050000 1 97 21 76 96 21 75 220318.054000 0.050000 1 76 22 55 75 22 54 174538.905000 0.050000 1 90 22 68 89 22 67 205416.994000 0.050000 1 94 22 72 93 22 71 214145.075000 0.050000 1 95 22 73 94 22 72 216328.298000 0.050000 1 97 22 75 96 22 74 220695.951000 0.050000 1 81 23 59 80 23 58 185829.202000 0.050000 1 90 23 67 89 23 66 205820.108000 0.050000 1 91 23 68 90 23 67 207997.934000 0.050000 1 94 23 71 93 23 70 214536.470000 0.050000 1 95 23 72 94 23 71 216717.364000 0.050000 1 97 23 74 96 23 73 221080.849000 0.050000 1 75 24 51 74 24 50 174632.860000 0.050000 1 86 24 62 85 24 61 197571.755000 0.050000 1 90 24 67 89 24 66 205820.108000 0.050000 1 92 24 68 91 24 67 210586.761000 0.050000 1 95 24 71 94 24 70 217116.770000 0.050000 1 75 25 50 74 25 49 174786.977000 0.050000 1 80 25 56 79 25 55 184570.320000 0.050000 1 86 25 62 85 25 61 197562.851000 0.050000 1 92 25 67 91 25 66 211016.164000 0.050000 1 92 25 68 91 25 67 210586.761000 0.050000 1 95 25 70 94 25 69 217530.175000 0.050000 1 75 26 49 74 26 48 174128.490000 0.050000 1 84 26 59 83 26 58 193701.891000 0.050000 1 90 26 65 89 26 64 206679.341000 0.050000 1 92 26 67 91 26 66 211014.642000 0.050000 1 93 26 68 92 26 67 213184.806000 0.050000 1 95 26 69 94 26 68 217963.380000 0.050000 1 93 27 66 92 27 65 214134.340000 0.050000 1 93 27 67 92 27 66 213629.530000 0.050000 1 94 27 68 93 27 67 215794.744000 0.050000 1 95 27 69 94 27 68 217961.860000 0.050000 1 96 27 69 95 27 68 220585.640000 0.050000 1 92 28 64 91 28 63 212693.454000 0.050000 1 93 28 66 92 28 65 214099.433000 0.050000 1 94 28 67 93 28 66 216257.904000 0.050000 1 96 28 69 95 28 68 220579.477000 0.050000 1 96 28 68 95 28 67 221091.209000 0.050000 1 96 29 68 95 29 67 221054.277000 0.050000 1 96 29 67 95 29 66 221723.856000 0.050000 1 93 30 63 92 30 62 216637.468000 0.050000 1 96 30 67 95 30 66 221539.911000 0.050000 1 ! ! high-K sequences for a given J ! 76 31 46 75 31 45 175020.931000 0.050000 1 76 33 44 75 33 43 174796.444000 0.050000 1 76 35 41 75 35 40 174624.709000 0.050000 1 76 36 40 75 36 39 174552.600000 0.050000 1 76 39 37 75 39 36 174375.092000 0.050000 1 76 41 35 75 41 34 174280.857000 0.050000 1 76 44 32 75 44 31 174164.936000 0.050000 1 76 45 31 75 45 30 174131.664000 0.050000 1 76 46 30 75 46 29 174100.560000 0.050000 1 76 47 29 75 47 28 174071.384000 0.050000 1 76 48 28 75 48 27 174044.169000 0.050000 1 76 50 26 75 50 25 173994.312000 0.050000 1 86 38 48 85 38 47 197711.285000 0.050000 1 87 36 52 86 36 51 200262.883000 0.050000 1 93 38 56 92 38 55 214118.315000 0.050000 1 93 43 50 92 43 49 213627.552000 0.050000 1 ------------------------------------------------------------------------------- -------------------------------------------------------------------------------