H81Br...14N 14N, F1,I,F coupling Tue Sep 26 16:03:58 2017 -------------------------------------------------------------------------------------========= obs o-c error blends Notes o-c wt / instead of : below denotes (o-c)>3*err -------------------------------------------------------------------------------------========= 1: 1 1 2 3 0 2 2 4 2313.9438 -0.0022 0.002 2: 1 1 2 3 0 2 2 3 2313.9689 -0.010 UNFITTD 2313.9790 3: 1 1 1 1 0 2 1 2 2313.9689 -0.009 UNFITTD 2313.9786 4: 1 3 2 3 0 2 0 2 2374.6259 0.0020 0.002 5: 1 3 2 4 0 2 2 4 2375.1067 0.0012 0.002 6: 1 3 2 4 0 2 2 3 2375.1388 0.0003 0.002 7: 1 3 1 4 0 2 1 3 2375.6472 -0.007 UNFITTD 2375.6551 8: 1 3 2 2 0 2 2 1 2376.2344 0.0000 0.002 -0.0016 0.56 9: 1 3 2 2 0 2 2 2 2376.2344 -0.0035 0.002 -0.0016 0.44 10: 1 3 2 5 0 2 2 4 2376.2990 0.0026 0.002 11: 1 3 1 3 0 2 1 2 2376.5365 -0.008 UNFITTD 2376.5445 12: 1 3 1 3 0 2 1 3 2376.5588 -0.009 UNFITTD 2376.5681 13: 1 3 0 3 0 2 2 2 2376.6993 0.0013 0.002 14: 1 3 2 1 0 2 2 1 2377.1042 0.0016 0.002 15: 1 2 2 4 0 2 2 4 2453.7633 -0.0005 0.002 16: 1 2 1 3 0 2 1 2 2454.2763 0.011 UNFITTD 2454.2649 17: 1 2 1 3 0 2 1 3 2454.2763 -0.012 UNFITTD 2454.2885 ! 18: 2 1 2 3 1 2 2 4 4642.2858 -0.0003 0.002 19: 2 2 1 2 1 2 1 3 4720.5249 -0.017 UNFITTD 4720.5427 20: 2 2 1 3 1 2 1 3 4720.5609 -0.019 UNFITTD 4720.5808 21: 2 2 2 4 1 2 2 4 4721.0779 -0.0012 0.002 22: 2 2 2 3 1 2 2 4 4721.0995 0.0022 0.002 23: 2 3 2 3 1 2 0 2 4773.6360 0.0000 0.002 24: 2 3 2 3 1 2 2 3 4773.8885 0.0005 0.002 25: 2 3 2 4 1 2 2 3 4774.1576 -0.0005 0.002 26: 2 3 1 2 1 2 1 1 4774.2239 -0.017 UNFITTD 4774.2418 27: 2 4 2 5 1 3 2 5 4774.2608 -0.0004 0.002 28: 2 3 1 4 1 2 1 3 4775.1068 -0.008 UNFITTD 4775.1157 29: 2 4 2 4 1 3 2 3 4775.1324 0.0004 0.002 30: 2 4 2 3 1 3 2 2 4775.3441 0.0001 0.002 31: 2 4 2 5 1 3 2 4 4775.4380 -0.014 UNFITTD 4775.4522 32: 2 4 1 5 1 3 1 4 4775.4560 -0.0001 0.002 33: 2 4 0 4 1 3 0 3 4775.6476 0.0010 0.002 34: 2 4 2 6 1 3 2 5 4775.7298 -0.0028 0.002 -0.0050 0.62 35: 2 4 1 4 1 3 1 3 4775.7298 -0.0083 0.002 -0.0050 0.38 36: 2 3 2 5 1 2 2 4 4775.9692 0.0048 0.002 37: 2 3 1 3 1 2 1 2 4776.4233 -0.019 UNFITTD 4776.4426 38: 2 4 2 2 1 3 2 2 4776.4572 -0.0007 0.002 39: 2 3 0 3 1 2 2 2 4776.9406 -0.0007 0.002 40: 2 4 2 3 1 3 2 3 4777.0160 -0.0016 0.002 41: 2 3 0 3 1 3 0 3 4853.2333 0.0001 0.002 42: 2 3 1 3 1 3 1 3 4853.2931 -0.018 UNFITTD 4853.3116 43: 2 3 2 5 1 3 2 5 4853.4295 -0.0022 0.002 44: 2 3 1 4 1 3 1 4 4853.7307 -0.018 UNFITTD 4853.7491 ! 45: 3 2 0 2 2 2 2 3 7108.6856 0.0124 0.002 -0.0023 0.28 46: 3 2 0 2 2 2 1 3 7108.6856 0.0068 0.002 -0.0023 0.15 47: 3 2 0 2 2 2 2 2 7108.6856 -0.0091 0.002 -0.0023 0.36 48: 3 2 0 2 2 2 2 1 7108.6856 -0.0178 0.002 -0.0023 0.21 49: 3 2 2 3 2 2 2 3 7108.9294 0.0158 0.002 0.0053 0.32 50: 3 2 2 3 2 2 0 2 7108.9294 0.0111 0.002 0.0053 0.19 51: 3 2 2 3 2 2 2 4 7108.9294 -0.0022 0.002 0.0053 0.31 52: 3 2 2 3 2 2 2 2 7108.9294 -0.0056 0.002 0.0053 0.19 53: 3 2 1 3 2 2 1 3 7109.5882 -0.030 UNFITTD 7109.6184 54: 3 2 2 4 2 2 1 3 7110.1108 -0.020 UNFITTD 7110.1317 55: 3 2 2 4 2 2 2 4 7110.1448 0.0005 0.002 56: 3 2 1 2 2 2 1 1 7110.4146 -0.029 UNFITTD 7110.4444 57: 3 2 1 2 2 2 1 3 7110.4518 -0.024 UNFITTD 7110.4762 58: 3 2 1 2 2 2 1 2 7110.4842 -0.030 UNFITTD 7110.5144 59: 3 2 2 2 2 2 2 3 7110.8803 0.001 UNFITTD 7110.8785 60: 3 2 2 2 2 2 0 2 7110.8803 -0.002 UNFITTD 7110.8832 61: 3 2 2 2 2 2 2 2 7110.8803 -0.019 UNFITTD 7110.9000 62: 3 2 2 2 2 2 2 1 7110.8803 -0.028 UNFITTD 7110.9088 63: 3 3 2 3 2 3 2 2 7132.0971 -0.0017 0.002 64: 3 3 2 4 2 3 0 3 7132.3586 0.0006 0.002 65: 3 3 2 3 2 3 2 3 7133.0009 -0.0007 0.002 66: 3 3 1 4 2 3 1 4 7133.3050 -0.029 UNFITTD 7133.3343 67: 3 3 2 5 2 3 2 5 7133.4969 0.0009 0.002 68: 3 3 1 3 2 3 1 3 7133.5316 -0.029 UNFITTD 7133.5616 69: 3 3 0 3 2 3 0 3 7133.6050 -0.0007 0.002 70: 3 3 2 2 2 3 2 3 7134.3711 -0.0013 0.002 71: 3 3 0 3 2 3 2 4 7134.4140 -0.0004 0.002 72: 3 4 2 4 2 3 2 3 7168.4634 -0.0001 0.002 73: 3 4 2 5 2 3 2 4 7168.8565 0.0002 0.002 74: 3 4 1 5 2 3 1 4 7168.9757 -0.027 UNFITTD 7169.0029 75: 3 5 2 5 2 4 2 4 7169.0106 -0.0004 0.002 76: 3 5 2 4 2 4 2 3 7169.0456 -0.0002 0.002 77: 3 4 2 3 2 3 2 2 7169.0780 -0.0002 0.002 78: 3 5 0 5 2 4 0 4 7169.2527 -0.0037 0.002 79: 3 5 2 7 2 4 2 6 7169.2967 0.0011 0.002 80: 3 4 2 6 2 3 2 5 7169.3931 0.0013 0.002 81: 3 4 0 4 2 3 0 3 7169.4621 0.0003 0.002 -0.0018 0.50 82: 3 4 1 4 2 3 1 3 7169.4621 -0.0038 0.002 -0.0018 0.50 83: 3 4 0 4 2 3 1 3 7169.5473 0.0002 0.002 84: 3 4 2 2 2 3 2 2 7169.9079 -0.0019 0.002 85: 3 4 2 3 2 3 2 3 7169.9803 -0.0007 0.002 86: 3 5 1 5 2 4 1 5 7170.4388 -0.027 UNFITTD 7170.4667 87: 3 5 2 4 2 4 2 4 7170.9328 0.0012 0.002 88: 3 5 0 5 2 4 2 5 7171.0284 -0.034 UNFITTD 7171.0634 89: 3 3 2 3 2 2 2 3 7187.0102 -0.0026 0.002 90: 3 3 2 3 2 2 2 2 7187.0346 0.0001 0.002 91: 3 3 2 4 2 2 2 3 7187.4460 -0.0021 0.002 92: 3 3 2 4 2 2 2 4 7187.4704 0.0041 0.002 93: 3 2 0 2 2 1 0 1 7187.5042 -0.0004 0.002 0.0008 0.55 94: 3 2 0 2 2 1 2 2 7187.5042 0.0023 0.002 0.0008 0.45 95: 3 3 1 4 2 2 1 3 7187.8402 -0.028 UNFITTD 7187.8692 96: 3 3 2 5 2 2 2 4 7188.3834 0.0022 0.002 97: 3 3 1 3 2 2 1 3 7188.5464 -0.025 UNFITTD 7188.5720 98: 3 3 1 3 2 2 1 2 7188.5820 -0.028 UNFITTD 7188.6101 99: 3 3 0 3 2 2 0 2 7188.7022 0.0016 0.002 100: 3 2 2 4 2 1 2 3 7188.9371 -0.0001 0.002 101: 3 4 1 4 2 4 1 4 7247.0134 -0.026 UNFITTD 7247.0394 102: 3 4 0 4 2 4 0 4 7247.0465 -0.0019 0.002 103: 3 4 2 6 2 4 2 6 7247.0930 0.0021 0.002 104: 3 4 1 5 2 4 1 5 7247.2698 -0.026 UNFITTD 7247.2958 105: 3 4 1 3 2 4 1 3 7247.3721 -0.028 UNFITTD 7247.4006 106: 3 4 2 5 2 4 2 5 7247.4427 0.0015 0.002 107: 3 4 2 4 2 4 2 4 7247.6197 0.0001 0.002 -------------------------------------------------------------------------------------========= 30 Lines rejected from fit PARAMETERS IN FIT (values truncated and Nlines statistics): 100 B /MHz 1195.55685(20) 1 200 DJ /kHz 4.812(12) 2 110010000 Br:3Chi/2 /MHz 467.6287(49) 3 110010100 Br:3ChiJ/2 /MHz 0.00313(59) 4 220010000 N:3Chi/2 /MHz -6.5096(21) 5 -330010000 . /MHz -6.5096(21) = 1.00000 * 5 10000000 Br:Mbb /MHz 0.00121(15) 6 MICROWAVE AVG = 0.000030 MHz, IR AVG = 0.00000 MICROWAVE RMS = 0.001822 MHz, IR RMS = 0.00000 END OF ITERATION 1 OLD, NEW RMS ERROR= 0.91111 0.91111 distinct frequency lines in fit: 62 distinct parameters of fit: 6 lines rejected from fit: 30 upper state lower state overall limits of quantum number 1: 1 3 0 2 0 3 limits of quantum number 2: 1 5 1 4 1 5 limits of quantum number 3: 0 2 0 2 0 2 limits of quantum number 4: 1 7 1 6 1 7 frequency range: 2313 7247 PARAMETERS IN FIT WITH STANDARD ERRORS ON THOSE THAT ARE FITTED: (values rounded and degrees of freedom, Ndegf=Nlines-Nconst, statistics) 100 B /MHz 1195.55686(19) 1 200 DJ /kHz 4.812(11) 2 110010000 Br:3Chi/2 /MHz 467.6287(46) 3 110010100 Br:3ChiJ/2 /MHz 0.00313(56) 4 220010000 N:3Chi/2 /MHz -6.5097(20) 5 -330010000 . /MHz -6.5097(20) = 1.00000 * 5 10000000 Br:Mbb /MHz 0.00121(14) 6 CORRELATION COEFFICIENTS, C.ij: B -DJ Br:3Chi/ Br:3ChiJ N:3Chi/2 Br:Mbb B 1.0000 -DJ -0.9610 1.0000 Br:3Chi/2 0.2866 -0.2218 1.0000 Br:3ChiJ/2 -0.1932 0.1194 -0.7733 1.0000 N:3Chi/2 -0.0967 0.0825 -0.1098 0.1038 1.0000 Br:Mbb -0.2654 0.3524 -0.1827 0.0906 0.1291 1.0000 Mean value of |C.ij|, i.ne.j = 0.2646 Mean value of C.ij, i.ne.j = -0.1093 No correlations with absolute value greater than 0.9950 Worst fitted lines (obs-calc/error): 49: 2.7 34: -2.5 36: 2.4 92: 2.1 78: -1.9 10: 1.3 89: -1.3 45: -1.2 22: 1.1 1: -1.1 43: -1.1 96: 1.1 103: 1.0 91: -1.0 4: 1.0 102: -0.9 84: -0.9 81: -0.9 63: -0.8 99: 0.8 14: 0.8 40: -0.8 8: -0.8 106: 0.8 70: -0.6 13: 0.6 80: 0.6 87: 0.6 21: -0.6 5: 0.6 79: 0.6 33: 0.5 67: 0.4 93: 0.4 39: -0.3 38: -0.3 85: -0.3 65: -0.3 69: -0.3 64: 0.3 15: -0.2 25: -0.2 55: 0.2 24: 0.2 75: -0.2 71: -0.2 27: -0.2 29: 0.2 6: 0.1 18: -0.1 49: 3 2 2 3 2 2 2 3 7108.9294 0.0158 0.002 0.0053 0.32 34: 2 4 2 6 1 3 2 5 4775.7298 -0.0028 0.002 -0.0050 0.62 36: 2 3 2 5 1 2 2 4 4775.9692 0.0048 0.002 92: 3 3 2 4 2 2 2 4 7187.4704 0.0041 0.002 78: 3 5 0 5 2 4 0 4 7169.2527 -0.0037 0.002 10: 1 3 2 5 0 2 2 4 2376.2990 0.0026 0.002 89: 3 3 2 3 2 2 2 3 7187.0102 -0.0026 0.002 45: 3 2 0 2 2 2 2 3 7108.6856 0.0124 0.002 -0.0023 0.28 22: 2 2 2 3 1 2 2 4 4721.0995 0.0022 0.002 1: 1 1 2 3 0 2 2 4 2313.9438 -0.0022 0.002 _____________________________________ __________________________________________/ SPFIT output reformatted with PIFORM