____________________________________________________________________________ | | | QSTARK - Fully diagonalizing fit of Stark shifts in a rotor | | with zero or one quadrupolar nuclei | |____________________________________________________________________________| version 4.X.2017 Zbigniew KISIEL ------------------------------------------------------------------------------ tertiary butyl cyanide, fitted constants ------------------------------------------------------------------------------ Calculation for J and F exceeding the value in data by at least 1 The fit will be made to TRANSITION FREQUENCIES 135 Lines read in 71 Lines fitted ---> 25 field free and 46 at non-zero field 1 Constants fitted TRANSITIONS (F and MF in units of 1/2): J K K <- J K K F MF<- F MF Volts Obs Obs-Calc Calc Field Field**2 -1 +1 -1 +1 1. 1 0 1 0 0 0 2 0 2 0 0.0 5498.76380 -0.00058 5498.7644 0.0000 0.00 2. 1 0 1 0 0 0 4 0 2 0 0.0 5500.02940 0.00081 5500.0286 0.0000 0.00 3. 1 0 1 0 0 0 0 0 2 0 0.0 5501.92360 -0.00151 5501.9251 0.0000 0.00 4. 2 0 2 1 0 1 4 0 4 0 0.0 10998.36350 -0.00030 10998.3638 0.0000 0.00 5. 2 0 2 1 0 1 2 0 0 0 0.0 10998.57460 0.00004 10998.5746 0.0000 0.00 6. 2 0 2 1 0 1 4 0 2 0 0.0 10999.62840 0.00040 10999.6280 0.0000 0.00 7. 2 0 2 1 0 1 6 0 4 0 0.0 10999.71980 0.00147 10999.7183 0.0000 0.00 8. 2 0 2 1 0 1 2 0 2 0 0.0 11001.73460 -0.00068 11001.7353 0.0000 0.00 9. 2 1 1 1 1 0 4 0 2 0 0.0 10998.55840 -0.00083 10998.5592 0.0000 0.00 10. 2 1 1 1 1 0 4 0 4 0 0.0 10999.19060 -0.00065 10999.1913 0.0000 0.00 11. 2 1 1 1 1 0 2 0 2 0 0.0 10999.61450 0.00146 10999.6130 0.0000 0.00 12. 2 1 1 1 1 0 6 0 4 0 0.0 10999.86970 0.00121 10999.8685 0.0000 0.00 13. 2 1 1 1 1 0 2 0 0 0 0.0 11001.19250 -0.00068 11001.1932 0.0000 0.00 14. 3 0 3 2 0 2 6 0 6 0 0.0 16498.06800 -0.00034 16498.0683 0.0000 0.00 15. 3 0 3 2 0 2 4 0 2 0 0.0 16499.21140 -0.00071 16499.2121 0.0000 0.00 16. 3 0 3 2 0 2 6 0 4 0 0.0 16499.42430 0.00143 16499.4229 0.0000 0.00 17. 3 0 3 2 0 2 8 0 6 0 0.0 16499.47620 0.00314 16499.4731 0.0000 0.00 18. 3 0 3 2 0 2 4 0 4 0 0.0 16501.31880 -0.00059 16501.3194 0.0000 0.00 19. 3 1 2 2 1 1 6 0 6 0 0.0 16498.45890 -0.00024 16498.4591 0.0000 0.00 20. 3 1 2 2 1 1 6 0 4 0 0.0 16499.13730 0.00093 16499.1364 0.0000 0.00 21. 3 1 2 2 1 1 8 0 6 0 0.0 16499.51410 0.00144 16499.5127 0.0000 0.00 22. 3 1 2 2 1 1 4 0 2 0 0.0 16499.51410 0.00910-- 16499.5050 0.0000 0.00 23. 3 1 2 2 1 1 4 0 4 0 0.0 16500.55950 0.00069 16500.5588 0.0000 0.00 24. 3 2 1 2 2 0 6 0 4 0 0.0 16498.27540 -0.00156 16498.2770 0.0000 0.00 25. 3 2 1 2 2 0 8 0 6 0 0.0 16499.63290 0.00145 16499.6314 0.0000 0.00 26. 3 2 1 2 2 0 4 0 2 0 0.0 16500.38470 0.00058 16500.3841 0.0000 0.00 27. 2 0 2 1 0 1 2 0 0 0 0.0 10998.57460 0.00004-- 10998.5746 0.0000 0.00 28. 2 0 2 1 0 1 2 0 0 0 1742.9 10998.56550 -0.00157 10998.5671 64.6476 4179.32 29. 2 0 2 1 0 1 4 0 2 0 0.0 10999.62840 0.00040-- 10999.6280 0.0000 0.00 30. 2 0 2 1 0 1 4 4 2 2 5023.1 11000.68140 0.00001 11000.6814 186.3168 34713.94 31. 2 0 2 1 0 1 6 0 4 0 0.0 10999.71980 0.00147-- 10999.7183 0.0000 0.00 32. 2 0 2 1 0 1 6 0 4 0 1742.9 10999.64000 0.00223 10999.6378 64.6476 4179.32 33. 2 0 2 1 0 1 6 0 4 0 2004.5 10999.66550 0.00461 10999.6609 74.3509 5528.05 34. 2 0 2 1 0 1 6 0 4 0 2996.0 11000.03440 0.00384 11000.0306 111.1276 12349.34 35. 2 0 2 1 0 1 6 0 4 0 3497.1 11000.38540 -0.00159 11000.3870 129.7144 16825.82 36. 2 0 2 1 0 1 6 0 4 0 4015.3 11000.86080 0.00678 11000.8540 148.9355 22181.77 37. 2 0 2 1 0 1 6 2 4 2 1308.1 10999.62700 -0.00246 10999.6295 48.5200 2354.19 38. 2 0 2 1 0 1 6 2 4 2 1742.9 10999.50140 -0.00005 10999.5014 64.6476 4179.32 39. 2 0 2 1 0 1 6 2 4 2 2004.5 10999.38470 0.00024 10999.3845 74.3509 5528.05 40. 2 0 2 1 0 1 6 2 4 2 2996.0 10998.66350 0.00112 10998.6624 111.1276 12349.34 41. 2 0 2 1 0 1 6 2 4 2 3497.1 10998.15060 0.00407 10998.1465 129.7144 16825.82 42. 2 0 2 1 0 1 6 2 4 2 4018.0 10997.51720 0.00080 10997.5164 149.0356 22211.61 43. 2 0 2 1 0 1 6 2 4 2 4499.8 10996.85240 -0.00213 10996.8545 166.9065 27857.79 44. 2 0 2 1 0 1 6 2 4 2 5023.1 10996.05500 0.00098 10996.0540 186.3168 34713.94 45. 2 0 2 1 0 1 6 2 4 2 5495.9 10995.26310 0.00309 10995.2600 203.8539 41556.40 46. 2 0 2 1 0 1 6 4 4 4 2004.5 11000.14430 0.00280 11000.1415 74.3509 5528.05 47. 2 0 2 1 0 1 6 4 4 4 2996.0 11000.69600 0.00308 11000.6929 111.1276 12349.34 48. 2 0 2 1 0 1 6 4 4 4 3497.1 11001.06960 0.00213 11001.0675 129.7144 16825.82 49. 2 0 2 1 0 1 6 4 4 4 4018.2 11001.52680 -0.00093 11001.5277 149.0430 22213.82 50. 2 0 2 1 0 1 6 4 4 4 4499.8 11002.01850 0.00059 11002.0179 166.9065 27857.79 ! ! Unidentified ! 51. 2 0 2 1 0 1 6 4 4 4 4499.8 11001.81000 -0.20791-- 11002.0179 166.9065 27857.79 52. 2 0 2 1 0 1 6 4 4 4 5023.1 11002.44080 -0.18038-- 11002.6212 186.3168 34713.94 53. 2 0 2 1 0 1 6 4 4 4 5495.9 11003.06800 -0.16122-- 11003.2292 203.8539 41556.40 54. 2 0 2 1 0 1 6 4 4 4 6002.6 11003.79900 -0.14780-- 11003.9468 222.6484 49572.30 55. 2 0 2 1 0 1 6 4 4 4 6501.7 11004.58990 -0.12991-- 11004.7198 241.1610 58158.62 56. 2 0 2 1 0 1 6 4 4 4 7026.5 11005.48470 -0.11825-- 11005.6030 260.6269 67926.36 ! ! DM=+1 ! 57. 2 0 2 1 0 1 6 6 4 4 4015.3 11000.58780 0.00751-- 11000.5803 148.9355 22181.77 58. 2 0 2 1 0 1 6 6 4 4 4499.8 11000.80330 0.00240-- 11000.8009 166.9065 27857.79 59. 2 0 2 1 0 1 2 0 2 0 0.0 11001.73460 -0.00068-- 11001.7353 0.0000 0.00 60. 2 0 2 1 0 1 2 2 2 2 4932.6 11003.67780 0.00128 11003.6765 182.9599 33474.34 61. 2 0 2 1 0 1 2 2 2 2 5450.7 11004.30530 -0.00007 11004.3054 202.1773 40875.66 62. 2 0 2 1 0 1 2 2 2 2 5915.8 11004.93570 -0.00216 11004.9379 219.4288 48148.99 ! ! Second order for K=1 ! ! Beaty 63. 2 1 1 1 1 0 6 0 4 0 0.0 10999.86970 0.00121-- 10999.8685 0.0000 0.00 64. 2 1 1 1 1 0 6 0 4 0 1640.1 11000.67790 0.00294 11000.6750 60.8346 3700.84 65. 2 1 1 1 1 0 6 0 4 0 2318.0 11001.01700 0.00296 11001.0140 85.9792 7392.43 66. 2 1 1 1 1 0 6 0 4 0 2847.2 11001.36140 0.00199 11001.3594 105.6083 11153.11 67. 2 1 1 1 1 0 6 0 4 0 3289.8 11001.70400 0.00141 11001.7026 122.0252 14890.15 68. 2 1 1 1 1 0 6 0 4 0 3669.8 11002.03830 0.00160 11002.0367 136.1202 18528.70 69. 2 1 1 1 1 0 6 0 4 0 4351.0 11002.73060 0.00367 11002.7269 161.3872 26045.84 70. 2 1 1 1 1 0 6 0 4 0 4932.6 11003.41090 0.00195 11003.4090 182.9599 33474.34 71. 2 1 1 1 1 0 6 0 4 0 5450.7 11004.08900 0.00057 11004.0884 202.1773 40875.66 72. 2 1 1 1 1 0 6 0 4 0 5915.8 11004.75570 -0.00041 11004.7561 219.4288 48148.99 73. 2 1 1 1 1 0 6 0 4 0 6361.9 11005.44420 -0.00359 11005.4478 235.9755 55684.45 ! ! Saszy 74. 2 1 2 1 1 1 4 2 2 2 2950.8 11000.35450 0.00564 11000.3489 109.4510 11979.53 75. 2 1 1 1 1 0 4 2 4 2 2950.8 11000.35450 -0.00078 11000.3553 109.4510 11979.53 76. 2 1 2 1 1 1 4 2 2 2 3499.4 11000.79660 0.00006 11000.7965 129.7997 16847.96 77. 2 1 1 1 1 0 4 2 4 2 3499.4 11000.79660 -0.00535 11000.8020 129.7997 16847.96 78. 2 1 2 1 1 1 4 2 2 2 4045.3 11001.32340 0.00604 11001.3174 150.0482 22514.47 79. 2 1 1 1 1 0 4 2 4 2 4045.3 11001.32340 0.00136 11001.3220 150.0482 22514.47 80. 2 1 1 1 1 0 4 2 2 2 4913.1 11002.30770 0.00379 11002.3039 182.2366 33210.20 81. 2 1 2 1 1 1 4 2 4 2 4913.1 11002.30770 0.00764 11002.3001 182.2366 33210.20 82. 2 1 1 1 1 0 4 2 2 2 5463.5 11003.02320 -0.00209 11003.0253 202.6521 41067.86 83. 2 1 2 1 1 1 4 2 4 2 5463.5 11003.02320 0.00138 11003.0218 202.6521 41067.86 84. 2 1 1 1 1 0 4 2 2 2 5898.5 11003.64590 -0.00364 11003.6495 218.7871 47867.79 85. 2 1 2 1 1 1 4 2 4 2 5898.5 11003.64590 -0.00043 11003.6463 218.7871 47867.79 ! ! Low voltage measurements (BUTCNB and BUTCNK) ! ! principal triplet to low frequency ! !--lowest frequency component - note switch in F, in either upper or lower ! energy level 86. 2 1 1 1 1 0 6 2 2 2 60.1 10997.93770 -0.00875-- 10997.9464 2.2311 4.98 87. 2 1 1 1 1 0 6 2 2 2 100.2 10996.96470 -0.01215-- 10996.9768 3.7148 13.80 88. 2 1 1 1 1 0 6 2 2 2 150.2 10995.73620 -0.01204-- 10995.7482 5.5705 31.03 89. 2 1 1 1 1 0 6 2 2 2 150.4 10995.73340 -0.01040-- 10995.7438 5.5772 31.10 90. 2 1 1 1 1 0 6 2 2 2 180.2 10994.99480 -0.01180-- 10995.0066 6.6843 44.68 91. 2 1 1 1 1 0 6 2 2 2 199.6 10994.51380 -0.01347-- 10994.5273 7.4028 54.80 92. 2 1 1 1 1 0 6 2 2 2 210.3 10994.25160 -0.00990-- 10994.2615 7.8008 60.85 93. 2 1 1 1 1 0 6 2 2 2 240.2 10993.51000 -0.01021-- 10993.5202 8.9099 79.39 94. 2 1 1 1 1 0 6 2 2 2 269.9 10992.77550 -0.00837-- 10992.7839 10.0104 100.21 95. 2 1 1 1 1 0 6 2 2 2 299.7 10992.02870 -0.01361-- 10992.0423 11.1180 123.61 ! !--intermediate frequency component 96. 2 1 1 1 1 0 4 4 4 4 60.1 10997.98180 -0.00852-- 10997.9903 2.2311 4.98 97. 2 1 1 1 1 0 4 4 4 4 100.2 10997.03770 -0.01372-- 10997.0514 3.7148 13.80 98. 2 1 1 1 1 0 4 4 4 4 150.2 10995.81860 -0.01620-- 10995.8348 5.5705 31.03 99. 2 1 1 1 1 0 4 4 4 4 150.4 10995.81700 -0.01339-- 10995.8304 5.5772 31.10 100. 2 1 1 1 1 0 6 4 4 4 180.2 10995.08350 -0.01271-- 10995.0962 6.6843 44.68 101. 2 1 1 1 1 0 6 4 4 4 199.6 10994.60240 -0.01576-- 10994.6182 7.4028 54.80 102. 2 1 1 1 1 0 6 4 4 4 210.3 10994.33970 -0.01326-- 10994.3530 7.8008 60.85 103. 2 1 1 1 1 0 6 4 4 4 240.2 10993.59720 -0.01569-- 10993.6129 8.9099 79.39 104. 2 1 1 1 1 0 6 4 4 4 269.9 10992.86060 -0.01683-- 10992.8774 10.0104 100.21 105. 2 1 1 1 1 0 6 4 4 4 299.7 10992.11440 -0.02214-- 10992.1365 11.1180 123.61 ! !--highest frequency component 106. 2 1 1 1 1 0 2 0 2 0 60.1 10998.18670 -0.01276-- 10998.1995 2.2311 4.98 107. 2 1 1 1 1 0 2 0 2 0 100.2 10997.15650 -0.01567-- 10997.1722 3.7148 13.80 108. 2 1 1 1 1 0 2 0 2 0 150.2 10995.89390 -0.01737-- 10995.9113 5.5705 31.03 109. 2 1 1 1 1 0 2 0 2 0 150.4 10995.89200 -0.01475-- 10995.9068 5.5772 31.10 110. 2 1 1 1 1 0 2 0 2 0 180.2 10995.14220 -0.01633-- 10995.1585 6.6843 44.68 111. 2 1 1 1 1 0 2 0 2 0 199.6 10994.65490 -0.01888-- 10994.6738 7.4028 54.80 112. 2 1 1 1 1 0 2 0 2 0 210.3 10994.39240 -0.01304-- 10994.4054 7.8008 60.85 113. 2 1 1 1 1 0 2 0 2 0 240.2 10993.63920 -0.01901-- 10993.6582 8.9099 79.39 114. 2 1 1 1 1 0 2 0 2 0 269.9 10992.89780 -0.01952-- 10992.9173 10.0104 100.21 115. 2 1 1 1 1 0 2 0 2 0 299.7 10992.14760 -0.02453-- 10992.1721 11.1180 123.61 ! ! principal multiplet to high frequency ! !--highest frequency component 116. 2 1 2 1 1 1 6 4 4 4 60.1 11001.25060 0.01035-- 11001.2403 2.2311 4.98 117. 2 1 2 1 1 1 6 4 4 4 100.2 11002.22570 0.01502-- 11002.2107 3.7148 13.80 118. 2 1 2 1 1 1 6 4 4 4 150.2 11003.46010 0.01766-- 11003.4424 5.5705 31.03 119. 2 1 2 1 1 1 6 4 4 4 150.4 11003.46110 0.01420-- 11003.4469 5.5772 31.10 120. 2 1 2 1 1 1 6 4 4 4 179.3 11004.18070 0.01628-- 11004.1644 6.6517 44.25 121. 2 1 2 1 1 1 6 4 4 4 199.6 11004.68640 0.01933-- 11004.6671 7.4028 54.80 122. 2 1 2 1 1 1 6 4 4 4 210.3 11004.94720 0.01350-- 11004.9337 7.8008 60.85 123. 2 1 2 1 1 1 6 4 4 4 240.2 11005.69430 0.01681-- 11005.6775 8.9099 79.39 124. 2 1 2 1 1 1 6 4 4 4 269.8 11006.42790 0.01339-- 11006.4145 10.0074 100.15 125. 2 1 2 1 1 1 6 4 4 4 299.7 11007.15850 -0.00249-- 11007.1610 11.1180 123.61 ! !--lowest frequency, strong component 126. 2 1 2 1 1 1 6 2 4 2 60.1 0.00000 -11001.65634-- 11001.6563 2.2311 4.98 127. 2 1 2 1 1 1 6 2 4 2 100.2 0.00000 -11002.15709-- 11002.1571 3.7148 13.80 128. 2 1 2 1 1 1 4 2 4 2 150.2 11003.38870 0.01459-- 11003.3741 5.5705 31.03 129. 2 1 2 1 1 1 4 2 4 2 150.4 11003.39020 0.01167-- 11003.3785 5.5772 31.10 130. 2 1 2 1 1 1 4 2 4 2 179.3 11004.10470 0.01282-- 11004.0919 6.6517 44.25 131. 2 1 2 1 1 1 6 2 4 2 199.6 11004.60710 0.01458-- 11004.5925 7.4028 54.80 132. 2 1 2 1 1 1 6 2 4 2 210.3 11004.87160 0.01331-- 11004.8583 7.8008 60.85 133. 2 1 2 1 1 1 6 2 4 2 240.2 11005.61380 0.01355-- 11005.6002 8.9099 79.39 134. 2 1 2 1 1 1 6 2 4 2 269.8 11006.34860 0.01258-- 11006.3360 10.0074 100.15 135. 2 1 2 1 1 1 6 2 4 2 299.7 11007.09210 0.01048-- 11007.0816 11.1180 123.61 Standard deviation = 0.002513 ITERATION NO = 1 CONSTANTS, deviations and changes: Mu.a = 4.012850166 +- 0.000288444 0.000176166 TRANSITIONS (F and MF in units of 1/2): J K K <- J K K F MF<- F MF Volts Obs Obs-Calc Calc Field Field**2 -1 +1 -1 +1 1. 1 0 1 0 0 0 2 0 2 0 0.0 5498.76380 -0.00058 5498.7644 0.0000 0.00 2. 1 0 1 0 0 0 4 0 2 0 0.0 5500.02940 0.00081 5500.0286 0.0000 0.00 3. 1 0 1 0 0 0 0 0 2 0 0.0 5501.92360 -0.00151 5501.9251 0.0000 0.00 4. 2 0 2 1 0 1 4 0 4 0 0.0 10998.36350 -0.00030 10998.3638 0.0000 0.00 5. 2 0 2 1 0 1 2 0 0 0 0.0 10998.57460 0.00004 10998.5746 0.0000 0.00 6. 2 0 2 1 0 1 4 0 2 0 0.0 10999.62840 0.00040 10999.6280 0.0000 0.00 7. 2 0 2 1 0 1 6 0 4 0 0.0 10999.71980 0.00147 10999.7183 0.0000 0.00 8. 2 0 2 1 0 1 2 0 2 0 0.0 11001.73460 -0.00068 11001.7353 0.0000 0.00 9. 2 1 1 1 1 0 4 0 2 0 0.0 10998.55840 -0.00083 10998.5592 0.0000 0.00 10. 2 1 1 1 1 0 4 0 4 0 0.0 10999.19060 -0.00065 10999.1913 0.0000 0.00 11. 2 1 1 1 1 0 2 0 2 0 0.0 10999.61450 0.00146 10999.6130 0.0000 0.00 12. 2 1 1 1 1 0 6 0 4 0 0.0 10999.86970 0.00121 10999.8685 0.0000 0.00 13. 2 1 1 1 1 0 2 0 0 0 0.0 11001.19250 -0.00068 11001.1932 0.0000 0.00 14. 3 0 3 2 0 2 6 0 6 0 0.0 16498.06800 -0.00034 16498.0683 0.0000 0.00 15. 3 0 3 2 0 2 4 0 2 0 0.0 16499.21140 -0.00071 16499.2121 0.0000 0.00 16. 3 0 3 2 0 2 6 0 4 0 0.0 16499.42430 0.00143 16499.4229 0.0000 0.00 17. 3 0 3 2 0 2 8 0 6 0 0.0 16499.47620 0.00314 16499.4731 0.0000 0.00 18. 3 0 3 2 0 2 4 0 4 0 0.0 16501.31880 -0.00059 16501.3194 0.0000 0.00 19. 3 1 2 2 1 1 6 0 6 0 0.0 16498.45890 -0.00024 16498.4591 0.0000 0.00 20. 3 1 2 2 1 1 6 0 4 0 0.0 16499.13730 0.00093 16499.1364 0.0000 0.00 21. 3 1 2 2 1 1 8 0 6 0 0.0 16499.51410 0.00144 16499.5127 0.0000 0.00 22. 3 1 2 2 1 1 4 0 2 0 0.0 16499.51410 0.00910-- 16499.5050 0.0000 0.00 23. 3 1 2 2 1 1 4 0 4 0 0.0 16500.55950 0.00069 16500.5588 0.0000 0.00 24. 3 2 1 2 2 0 6 0 4 0 0.0 16498.27540 -0.00156 16498.2770 0.0000 0.00 25. 3 2 1 2 2 0 8 0 6 0 0.0 16499.63290 0.00145 16499.6314 0.0000 0.00 26. 3 2 1 2 2 0 4 0 2 0 0.0 16500.38470 0.00058 16500.3841 0.0000 0.00 27. 2 0 2 1 0 1 2 0 0 0 0.0 10998.57460 0.00004-- 10998.5746 0.0000 0.00 28. 2 0 2 1 0 1 2 0 0 0 1742.9 10998.56550 -0.00156 10998.5671 64.6476 4179.32 29. 2 0 2 1 0 1 4 0 2 0 0.0 10999.62840 0.00040-- 10999.6280 0.0000 0.00 30. 2 0 2 1 0 1 4 4 2 2 5023.1 11000.68140 -0.00012 11000.6815 186.3168 34713.94 31. 2 0 2 1 0 1 6 0 4 0 0.0 10999.71980 0.00147-- 10999.7183 0.0000 0.00 32. 2 0 2 1 0 1 6 0 4 0 1742.9 10999.64000 0.00222 10999.6378 64.6476 4179.32 33. 2 0 2 1 0 1 6 0 4 0 2004.5 10999.66550 0.00459 10999.6609 74.3509 5528.05 34. 2 0 2 1 0 1 6 0 4 0 2996.0 11000.03440 0.00376 11000.0306 111.1276 12349.34 35. 2 0 2 1 0 1 6 0 4 0 3497.1 11000.38540 -0.00172 11000.3871 129.7144 16825.82 36. 2 0 2 1 0 1 6 0 4 0 4015.3 11000.86080 0.00660 11000.8542 148.9355 22181.77 37. 2 0 2 1 0 1 6 2 4 2 1308.1 10999.62700 -0.00245 10999.6294 48.5200 2354.19 38. 2 0 2 1 0 1 6 2 4 2 1742.9 10999.50140 -0.00002 10999.5014 64.6476 4179.32 39. 2 0 2 1 0 1 6 2 4 2 2004.5 10999.38470 0.00029 10999.3844 74.3509 5528.05 40. 2 0 2 1 0 1 6 2 4 2 2996.0 10998.66350 0.00124 10998.6623 111.1276 12349.34 41. 2 0 2 1 0 1 6 2 4 2 3497.1 10998.15060 0.00425 10998.1464 129.7144 16825.82 42. 2 0 2 1 0 1 6 2 4 2 4018.0 10997.51720 0.00103 10997.5162 149.0356 22211.61 43. 2 0 2 1 0 1 6 2 4 2 4499.8 10996.85240 -0.00184 10996.8542 166.9065 27857.79 44. 2 0 2 1 0 1 6 2 4 2 5023.1 10996.05500 0.00133 10996.0537 186.3168 34713.94 45. 2 0 2 1 0 1 6 2 4 2 5495.9 10995.26310 0.00352 10995.2596 203.8539 41556.40 46. 2 0 2 1 0 1 6 4 4 4 2004.5 11000.14430 0.00276 11000.1415 74.3509 5528.05 47. 2 0 2 1 0 1 6 4 4 4 2996.0 11000.69600 0.00299 11000.6930 111.1276 12349.34 48. 2 0 2 1 0 1 6 4 4 4 3497.1 11001.06960 0.00200 11001.0676 129.7144 16825.82 49. 2 0 2 1 0 1 6 4 4 4 4018.2 11001.52680 -0.00110 11001.5279 149.0430 22213.82 50. 2 0 2 1 0 1 6 4 4 4 4499.8 11002.01850 0.00038 11002.0181 166.9065 27857.79 ! ! Unidentified ! 51. 2 0 2 1 0 1 6 4 4 4 4499.8 11001.81000 -0.20812-- 11002.0181 166.9065 27857.79 52. 2 0 2 1 0 1 6 4 4 4 5023.1 11002.44080 -0.18065-- 11002.6214 186.3168 34713.94 53. 2 0 2 1 0 1 6 4 4 4 5495.9 11003.06800 -0.16155-- 11003.2295 203.8539 41556.40 54. 2 0 2 1 0 1 6 4 4 4 6002.6 11003.79900 -0.14819-- 11003.9472 222.6484 49572.30 55. 2 0 2 1 0 1 6 4 4 4 6501.7 11004.58990 -0.13037-- 11004.7203 241.1610 58158.62 56. 2 0 2 1 0 1 6 4 4 4 7026.5 11005.48470 -0.11879-- 11005.6035 260.6269 67926.36 ! ! DM=+1 ! 57. 2 0 2 1 0 1 6 6 4 4 4015.3 11000.58780 0.00743-- 11000.5804 148.9355 22181.77 58. 2 0 2 1 0 1 6 6 4 4 4499.8 11000.80330 0.00231-- 11000.8010 166.9065 27857.79 59. 2 0 2 1 0 1 2 0 2 0 0.0 11001.73460 -0.00068-- 11001.7353 0.0000 0.00 60. 2 0 2 1 0 1 2 2 2 2 4932.6 11003.67780 0.00103 11003.6768 182.9599 33474.34 61. 2 0 2 1 0 1 2 2 2 2 5450.7 11004.30530 -0.00038 11004.3057 202.1773 40875.66 62. 2 0 2 1 0 1 2 2 2 2 5915.8 11004.93570 -0.00253 11004.9382 219.4288 48148.99 ! ! Second order for K=1 ! ! Beaty 63. 2 1 1 1 1 0 6 0 4 0 0.0 10999.86970 0.00121-- 10999.8685 0.0000 0.00 64. 2 1 1 1 1 0 6 0 4 0 1640.1 11000.67790 0.00291 11000.6750 60.8346 3700.84 65. 2 1 1 1 1 0 6 0 4 0 2318.0 11001.01700 0.00290 11001.0141 85.9792 7392.43 66. 2 1 1 1 1 0 6 0 4 0 2847.2 11001.36140 0.00190 11001.3595 105.6083 11153.11 67. 2 1 1 1 1 0 6 0 4 0 3289.8 11001.70400 0.00129 11001.7027 122.0252 14890.15 68. 2 1 1 1 1 0 6 0 4 0 3669.8 11002.03830 0.00145 11002.0368 136.1202 18528.70 69. 2 1 1 1 1 0 6 0 4 0 4351.0 11002.73060 0.00346 11002.7271 161.3872 26045.84 70. 2 1 1 1 1 0 6 0 4 0 4932.6 11003.41090 0.00168 11003.4092 182.9599 33474.34 71. 2 1 1 1 1 0 6 0 4 0 5450.7 11004.08900 0.00024 11004.0888 202.1773 40875.66 72. 2 1 1 1 1 0 6 0 4 0 5915.8 11004.75570 -0.00080 11004.7565 219.4288 48148.99 73. 2 1 1 1 1 0 6 0 4 0 6361.9 11005.44420 -0.00404 11005.4482 235.9755 55684.45 ! ! Saszy 74. 2 1 2 1 1 1 4 2 2 2 2950.8 11000.35450 0.00554 11000.3490 109.4510 11979.53 75. 2 1 1 1 1 0 4 2 4 2 2950.8 11000.35450 -0.00087 11000.3554 109.4510 11979.53 76. 2 1 2 1 1 1 4 2 2 2 3499.4 11000.79660 -0.00008 11000.7967 129.7997 16847.96 77. 2 1 1 1 1 0 4 2 4 2 3499.4 11000.79660 -0.00549 11000.8021 129.7997 16847.96 78. 2 1 2 1 1 1 4 2 2 2 4045.3 11001.32340 0.00586 11001.3175 150.0482 22514.47 79. 2 1 1 1 1 0 4 2 4 2 4045.3 11001.32340 0.00118 11001.3222 150.0482 22514.47 80. 2 1 1 1 1 0 4 2 2 2 4913.1 11002.30770 0.00352 11002.3042 182.2366 33210.20 81. 2 1 2 1 1 1 4 2 4 2 4913.1 11002.30770 0.00737 11002.3003 182.2366 33210.20 82. 2 1 1 1 1 0 4 2 2 2 5463.5 11003.02320 -0.00242 11003.0256 202.6521 41067.86 83. 2 1 2 1 1 1 4 2 4 2 5463.5 11003.02320 0.00105 11003.0221 202.6521 41067.86 84. 2 1 1 1 1 0 4 2 2 2 5898.5 11003.64590 -0.00403 11003.6499 218.7871 47867.79 85. 2 1 2 1 1 1 4 2 4 2 5898.5 11003.64590 -0.00082 11003.6467 218.7871 47867.79 ! ! Low voltage measurements (BUTCNB and BUTCNK) ! ! principal triplet to low frequency ! !--lowest frequency component - note switch in F, in either upper or lower ! energy level 86. 2 1 1 1 1 0 6 2 2 2 60.1 10997.93770 -0.00869-- 10997.9464 2.2311 4.98 87. 2 1 1 1 1 0 6 2 2 2 100.2 10996.96470 -0.01204-- 10996.9767 3.7148 13.80 88. 2 1 1 1 1 0 6 2 2 2 150.2 10995.73620 -0.01188-- 10995.7481 5.5705 31.03 89. 2 1 1 1 1 0 6 2 2 2 150.4 10995.73340 -0.01024-- 10995.7436 5.5772 31.10 90. 2 1 1 1 1 0 6 2 2 2 180.2 10994.99480 -0.01161-- 10995.0064 6.6843 44.68 91. 2 1 1 1 1 0 6 2 2 2 199.6 10994.51380 -0.01325-- 10994.5270 7.4028 54.80 92. 2 1 1 1 1 0 6 2 2 2 210.3 10994.25160 -0.00967-- 10994.2613 7.8008 60.85 93. 2 1 1 1 1 0 6 2 2 2 240.2 10993.51000 -0.00994-- 10993.5199 8.9099 79.39 94. 2 1 1 1 1 0 6 2 2 2 269.9 10992.77550 -0.00808-- 10992.7836 10.0104 100.21 95. 2 1 1 1 1 0 6 2 2 2 299.7 10992.02870 -0.01329-- 10992.0420 11.1180 123.61 ! !--intermediate frequency component 96. 2 1 1 1 1 0 4 4 4 4 60.1 10997.98180 -0.00846-- 10997.9903 2.2311 4.98 97. 2 1 1 1 1 0 4 4 4 4 100.2 10997.03770 -0.01361-- 10997.0513 3.7148 13.80 98. 2 1 1 1 1 0 4 4 4 4 150.2 10995.81860 -0.01604-- 10995.8346 5.5705 31.03 99. 2 1 1 1 1 0 4 4 4 4 150.4 10995.81700 -0.01323-- 10995.8302 5.5772 31.10 100. 2 1 1 1 1 0 6 4 4 4 180.2 10995.08350 -0.01251-- 10995.0960 6.6843 44.68 101. 2 1 1 1 1 0 6 4 4 4 199.6 10994.60240 -0.01554-- 10994.6179 7.4028 54.80 102. 2 1 1 1 1 0 6 4 4 4 210.3 10994.33970 -0.01303-- 10994.3527 7.8008 60.85 103. 2 1 1 1 1 0 6 4 4 4 240.2 10993.59720 -0.01543-- 10993.6126 8.9099 79.39 104. 2 1 1 1 1 0 6 4 4 4 269.9 10992.86060 -0.01653-- 10992.8771 10.0104 100.21 105. 2 1 1 1 1 0 6 4 4 4 299.7 10992.11440 -0.02181-- 10992.1362 11.1180 123.61 ! !--highest frequency component 106. 2 1 1 1 1 0 2 0 2 0 60.1 10998.18670 -0.01269-- 10998.1994 2.2311 4.98 107. 2 1 1 1 1 0 2 0 2 0 100.2 10997.15650 -0.01555-- 10997.1721 3.7148 13.80 108. 2 1 1 1 1 0 2 0 2 0 150.2 10995.89390 -0.01721-- 10995.9111 5.5705 31.03 109. 2 1 1 1 1 0 2 0 2 0 150.4 10995.89200 -0.01459-- 10995.9066 5.5772 31.10 110. 2 1 1 1 1 0 2 0 2 0 180.2 10995.14220 -0.01614-- 10995.1583 6.6843 44.68 111. 2 1 1 1 1 0 2 0 2 0 199.6 10994.65490 -0.01866-- 10994.6736 7.4028 54.80 112. 2 1 1 1 1 0 2 0 2 0 210.3 10994.39240 -0.01281-- 10994.4052 7.8008 60.85 113. 2 1 1 1 1 0 2 0 2 0 240.2 10993.63920 -0.01875-- 10993.6579 8.9099 79.39 114. 2 1 1 1 1 0 2 0 2 0 269.9 10992.89780 -0.01922-- 10992.9170 10.0104 100.21 115. 2 1 1 1 1 0 2 0 2 0 299.7 10992.14760 -0.02420-- 10992.1718 11.1180 123.61 ! ! principal multiplet to high frequency ! !--highest frequency component 116. 2 1 2 1 1 1 6 4 4 4 60.1 11001.25060 0.01028-- 11001.2403 2.2311 4.98 117. 2 1 2 1 1 1 6 4 4 4 100.2 11002.22570 0.01491-- 11002.2108 3.7148 13.80 118. 2 1 2 1 1 1 6 4 4 4 150.2 11003.46010 0.01749-- 11003.4426 5.5705 31.03 119. 2 1 2 1 1 1 6 4 4 4 150.4 11003.46110 0.01404-- 11003.4471 5.5772 31.10 120. 2 1 2 1 1 1 6 4 4 4 179.3 11004.18070 0.01608-- 11004.1646 6.6517 44.25 121. 2 1 2 1 1 1 6 4 4 4 199.6 11004.68640 0.01911-- 11004.6673 7.4028 54.80 122. 2 1 2 1 1 1 6 4 4 4 210.3 11004.94720 0.01327-- 11004.9339 7.8008 60.85 123. 2 1 2 1 1 1 6 4 4 4 240.2 11005.69430 0.01655-- 11005.6777 8.9099 79.39 124. 2 1 2 1 1 1 6 4 4 4 269.8 11006.42790 0.01310-- 11006.4148 10.0074 100.15 125. 2 1 2 1 1 1 6 4 4 4 299.7 11007.15850 -0.00282-- 11007.1613 11.1180 123.61 ! !--lowest frequency, strong component 126. 2 1 2 1 1 1 6 2 4 2 60.1 0.00000 -11001.65643-- 11001.6564 2.2311 4.98 127. 2 1 2 1 1 1 6 2 4 2 100.2 0.00000 -11002.15720-- 11002.1572 3.7148 13.80 128. 2 1 2 1 1 1 4 2 4 2 150.2 11003.38870 0.01443-- 11003.3743 5.5705 31.03 129. 2 1 2 1 1 1 4 2 4 2 150.4 11003.39020 0.01151-- 11003.3787 5.5772 31.10 130. 2 1 2 1 1 1 4 2 4 2 179.3 11004.10470 0.01263-- 11004.0921 6.6517 44.25 131. 2 1 2 1 1 1 6 2 4 2 199.6 11004.60710 0.01437-- 11004.5927 7.4028 54.80 132. 2 1 2 1 1 1 6 2 4 2 210.3 11004.87160 0.01309-- 11004.8585 7.8008 60.85 133. 2 1 2 1 1 1 6 2 4 2 240.2 11005.61380 0.01329-- 11005.6005 8.9099 79.39 134. 2 1 2 1 1 1 6 2 4 2 269.8 11006.34860 0.01228-- 11006.3363 10.0074 100.15 135. 2 1 2 1 1 1 6 2 4 2 299.7 11007.09210 0.01015-- 11007.0820 11.1180 123.61 Standard deviation = 0.002506 ITERATION NO = 2 CONSTANTS, deviations and changes: Mu.a = 4.012850165 +- 0.000287661 -0.000000001 TRANSITIONS (F and MF in units of 1/2): J K K <- J K K F MF<- F MF Volts Obs Obs-Calc Calc Field Field**2 -1 +1 -1 +1 1. 1 0 1 0 0 0 2 0 2 0 0.0 5498.76380 -0.00058 5498.7644 0.0000 0.00 2. 1 0 1 0 0 0 4 0 2 0 0.0 5500.02940 0.00081 5500.0286 0.0000 0.00 3. 1 0 1 0 0 0 0 0 2 0 0.0 5501.92360 -0.00151 5501.9251 0.0000 0.00 4. 2 0 2 1 0 1 4 0 4 0 0.0 10998.36350 -0.00030 10998.3638 0.0000 0.00 5. 2 0 2 1 0 1 2 0 0 0 0.0 10998.57460 0.00004 10998.5746 0.0000 0.00 6. 2 0 2 1 0 1 4 0 2 0 0.0 10999.62840 0.00040 10999.6280 0.0000 0.00 7. 2 0 2 1 0 1 6 0 4 0 0.0 10999.71980 0.00147 10999.7183 0.0000 0.00 8. 2 0 2 1 0 1 2 0 2 0 0.0 11001.73460 -0.00068 11001.7353 0.0000 0.00 9. 2 1 1 1 1 0 4 0 2 0 0.0 10998.55840 -0.00083 10998.5592 0.0000 0.00 10. 2 1 1 1 1 0 4 0 4 0 0.0 10999.19060 -0.00065 10999.1913 0.0000 0.00 11. 2 1 1 1 1 0 2 0 2 0 0.0 10999.61450 0.00146 10999.6130 0.0000 0.00 12. 2 1 1 1 1 0 6 0 4 0 0.0 10999.86970 0.00121 10999.8685 0.0000 0.00 13. 2 1 1 1 1 0 2 0 0 0 0.0 11001.19250 -0.00068 11001.1932 0.0000 0.00 14. 3 0 3 2 0 2 6 0 6 0 0.0 16498.06800 -0.00034 16498.0683 0.0000 0.00 15. 3 0 3 2 0 2 4 0 2 0 0.0 16499.21140 -0.00071 16499.2121 0.0000 0.00 16. 3 0 3 2 0 2 6 0 4 0 0.0 16499.42430 0.00143 16499.4229 0.0000 0.00 17. 3 0 3 2 0 2 8 0 6 0 0.0 16499.47620 0.00314 16499.4731 0.0000 0.00 18. 3 0 3 2 0 2 4 0 4 0 0.0 16501.31880 -0.00059 16501.3194 0.0000 0.00 19. 3 1 2 2 1 1 6 0 6 0 0.0 16498.45890 -0.00024 16498.4591 0.0000 0.00 20. 3 1 2 2 1 1 6 0 4 0 0.0 16499.13730 0.00093 16499.1364 0.0000 0.00 21. 3 1 2 2 1 1 8 0 6 0 0.0 16499.51410 0.00144 16499.5127 0.0000 0.00 22. 3 1 2 2 1 1 4 0 2 0 0.0 16499.51410 0.00910-- 16499.5050 0.0000 0.00 23. 3 1 2 2 1 1 4 0 4 0 0.0 16500.55950 0.00069 16500.5588 0.0000 0.00 24. 3 2 1 2 2 0 6 0 4 0 0.0 16498.27540 -0.00156 16498.2770 0.0000 0.00 25. 3 2 1 2 2 0 8 0 6 0 0.0 16499.63290 0.00145 16499.6314 0.0000 0.00 26. 3 2 1 2 2 0 4 0 2 0 0.0 16500.38470 0.00058 16500.3841 0.0000 0.00 27. 2 0 2 1 0 1 2 0 0 0 0.0 10998.57460 0.00004-- 10998.5746 0.0000 0.00 28. 2 0 2 1 0 1 2 0 0 0 1742.9 10998.56550 -0.00156 10998.5671 64.6476 4179.32 29. 2 0 2 1 0 1 4 0 2 0 0.0 10999.62840 0.00040-- 10999.6280 0.0000 0.00 30. 2 0 2 1 0 1 4 4 2 2 5023.1 11000.68140 -0.00012 11000.6815 186.3168 34713.94 31. 2 0 2 1 0 1 6 0 4 0 0.0 10999.71980 0.00147-- 10999.7183 0.0000 0.00 32. 2 0 2 1 0 1 6 0 4 0 1742.9 10999.64000 0.00222 10999.6378 64.6476 4179.32 33. 2 0 2 1 0 1 6 0 4 0 2004.5 10999.66550 0.00459 10999.6609 74.3509 5528.05 34. 2 0 2 1 0 1 6 0 4 0 2996.0 11000.03440 0.00376 11000.0306 111.1276 12349.34 35. 2 0 2 1 0 1 6 0 4 0 3497.1 11000.38540 -0.00172 11000.3871 129.7144 16825.82 36. 2 0 2 1 0 1 6 0 4 0 4015.3 11000.86080 0.00660 11000.8542 148.9355 22181.77 37. 2 0 2 1 0 1 6 2 4 2 1308.1 10999.62700 -0.00245 10999.6294 48.5200 2354.19 38. 2 0 2 1 0 1 6 2 4 2 1742.9 10999.50140 -0.00002 10999.5014 64.6476 4179.32 39. 2 0 2 1 0 1 6 2 4 2 2004.5 10999.38470 0.00029 10999.3844 74.3509 5528.05 40. 2 0 2 1 0 1 6 2 4 2 2996.0 10998.66350 0.00124 10998.6623 111.1276 12349.34 41. 2 0 2 1 0 1 6 2 4 2 3497.1 10998.15060 0.00425 10998.1464 129.7144 16825.82 42. 2 0 2 1 0 1 6 2 4 2 4018.0 10997.51720 0.00103 10997.5162 149.0356 22211.61 43. 2 0 2 1 0 1 6 2 4 2 4499.8 10996.85240 -0.00184 10996.8542 166.9065 27857.79 44. 2 0 2 1 0 1 6 2 4 2 5023.1 10996.05500 0.00133 10996.0537 186.3168 34713.94 45. 2 0 2 1 0 1 6 2 4 2 5495.9 10995.26310 0.00352 10995.2596 203.8539 41556.40 46. 2 0 2 1 0 1 6 4 4 4 2004.5 11000.14430 0.00276 11000.1415 74.3509 5528.05 47. 2 0 2 1 0 1 6 4 4 4 2996.0 11000.69600 0.00299 11000.6930 111.1276 12349.34 48. 2 0 2 1 0 1 6 4 4 4 3497.1 11001.06960 0.00200 11001.0676 129.7144 16825.82 49. 2 0 2 1 0 1 6 4 4 4 4018.2 11001.52680 -0.00110 11001.5279 149.0430 22213.82 50. 2 0 2 1 0 1 6 4 4 4 4499.8 11002.01850 0.00038 11002.0181 166.9065 27857.79 ! ! Unidentified ! 51. 2 0 2 1 0 1 6 4 4 4 4499.8 11001.81000 -0.20812-- 11002.0181 166.9065 27857.79 52. 2 0 2 1 0 1 6 4 4 4 5023.1 11002.44080 -0.18065-- 11002.6214 186.3168 34713.94 53. 2 0 2 1 0 1 6 4 4 4 5495.9 11003.06800 -0.16155-- 11003.2295 203.8539 41556.40 54. 2 0 2 1 0 1 6 4 4 4 6002.6 11003.79900 -0.14819-- 11003.9472 222.6484 49572.30 55. 2 0 2 1 0 1 6 4 4 4 6501.7 11004.58990 -0.13037-- 11004.7203 241.1610 58158.62 56. 2 0 2 1 0 1 6 4 4 4 7026.5 11005.48470 -0.11879-- 11005.6035 260.6269 67926.36 ! ! DM=+1 ! 57. 2 0 2 1 0 1 6 6 4 4 4015.3 11000.58780 0.00743-- 11000.5804 148.9355 22181.77 58. 2 0 2 1 0 1 6 6 4 4 4499.8 11000.80330 0.00231-- 11000.8010 166.9065 27857.79 59. 2 0 2 1 0 1 2 0 2 0 0.0 11001.73460 -0.00068-- 11001.7353 0.0000 0.00 60. 2 0 2 1 0 1 2 2 2 2 4932.6 11003.67780 0.00103 11003.6768 182.9599 33474.34 61. 2 0 2 1 0 1 2 2 2 2 5450.7 11004.30530 -0.00038 11004.3057 202.1773 40875.66 62. 2 0 2 1 0 1 2 2 2 2 5915.8 11004.93570 -0.00253 11004.9382 219.4288 48148.99 ! ! Second order for K=1 ! ! Beaty 63. 2 1 1 1 1 0 6 0 4 0 0.0 10999.86970 0.00121-- 10999.8685 0.0000 0.00 64. 2 1 1 1 1 0 6 0 4 0 1640.1 11000.67790 0.00291 11000.6750 60.8346 3700.84 65. 2 1 1 1 1 0 6 0 4 0 2318.0 11001.01700 0.00290 11001.0141 85.9792 7392.43 66. 2 1 1 1 1 0 6 0 4 0 2847.2 11001.36140 0.00190 11001.3595 105.6083 11153.11 67. 2 1 1 1 1 0 6 0 4 0 3289.8 11001.70400 0.00129 11001.7027 122.0252 14890.15 68. 2 1 1 1 1 0 6 0 4 0 3669.8 11002.03830 0.00145 11002.0368 136.1202 18528.70 69. 2 1 1 1 1 0 6 0 4 0 4351.0 11002.73060 0.00346 11002.7271 161.3872 26045.84 70. 2 1 1 1 1 0 6 0 4 0 4932.6 11003.41090 0.00168 11003.4092 182.9599 33474.34 71. 2 1 1 1 1 0 6 0 4 0 5450.7 11004.08900 0.00024 11004.0888 202.1773 40875.66 72. 2 1 1 1 1 0 6 0 4 0 5915.8 11004.75570 -0.00080 11004.7565 219.4288 48148.99 73. 2 1 1 1 1 0 6 0 4 0 6361.9 11005.44420 -0.00404 11005.4482 235.9755 55684.45 ! ! Saszy 74. 2 1 2 1 1 1 4 2 2 2 2950.8 11000.35450 0.00554 11000.3490 109.4510 11979.53 75. 2 1 1 1 1 0 4 2 4 2 2950.8 11000.35450 -0.00087 11000.3554 109.4510 11979.53 76. 2 1 2 1 1 1 4 2 2 2 3499.4 11000.79660 -0.00008 11000.7967 129.7997 16847.96 77. 2 1 1 1 1 0 4 2 4 2 3499.4 11000.79660 -0.00549 11000.8021 129.7997 16847.96 78. 2 1 2 1 1 1 4 2 2 2 4045.3 11001.32340 0.00586 11001.3175 150.0482 22514.47 79. 2 1 1 1 1 0 4 2 4 2 4045.3 11001.32340 0.00118 11001.3222 150.0482 22514.47 80. 2 1 1 1 1 0 4 2 2 2 4913.1 11002.30770 0.00352 11002.3042 182.2366 33210.20 81. 2 1 2 1 1 1 4 2 4 2 4913.1 11002.30770 0.00737 11002.3003 182.2366 33210.20 82. 2 1 1 1 1 0 4 2 2 2 5463.5 11003.02320 -0.00242 11003.0256 202.6521 41067.86 83. 2 1 2 1 1 1 4 2 4 2 5463.5 11003.02320 0.00105 11003.0221 202.6521 41067.86 84. 2 1 1 1 1 0 4 2 2 2 5898.5 11003.64590 -0.00403 11003.6499 218.7871 47867.79 85. 2 1 2 1 1 1 4 2 4 2 5898.5 11003.64590 -0.00082 11003.6467 218.7871 47867.79 ! ! Low voltage measurements (BUTCNB and BUTCNK) ! ! principal triplet to low frequency ! !--lowest frequency component - note switch in F, in either upper or lower ! energy level 86. 2 1 1 1 1 0 6 2 2 2 60.1 10997.93770 -0.00869-- 10997.9464 2.2311 4.98 87. 2 1 1 1 1 0 6 2 2 2 100.2 10996.96470 -0.01204-- 10996.9767 3.7148 13.80 88. 2 1 1 1 1 0 6 2 2 2 150.2 10995.73620 -0.01188-- 10995.7481 5.5705 31.03 89. 2 1 1 1 1 0 6 2 2 2 150.4 10995.73340 -0.01024-- 10995.7436 5.5772 31.10 90. 2 1 1 1 1 0 6 2 2 2 180.2 10994.99480 -0.01161-- 10995.0064 6.6843 44.68 91. 2 1 1 1 1 0 6 2 2 2 199.6 10994.51380 -0.01325-- 10994.5270 7.4028 54.80 92. 2 1 1 1 1 0 6 2 2 2 210.3 10994.25160 -0.00967-- 10994.2613 7.8008 60.85 93. 2 1 1 1 1 0 6 2 2 2 240.2 10993.51000 -0.00994-- 10993.5199 8.9099 79.39 94. 2 1 1 1 1 0 6 2 2 2 269.9 10992.77550 -0.00808-- 10992.7836 10.0104 100.21 95. 2 1 1 1 1 0 6 2 2 2 299.7 10992.02870 -0.01329-- 10992.0420 11.1180 123.61 ! !--intermediate frequency component 96. 2 1 1 1 1 0 4 4 4 4 60.1 10997.98180 -0.00846-- 10997.9903 2.2311 4.98 97. 2 1 1 1 1 0 4 4 4 4 100.2 10997.03770 -0.01361-- 10997.0513 3.7148 13.80 98. 2 1 1 1 1 0 4 4 4 4 150.2 10995.81860 -0.01604-- 10995.8346 5.5705 31.03 99. 2 1 1 1 1 0 4 4 4 4 150.4 10995.81700 -0.01323-- 10995.8302 5.5772 31.10 100. 2 1 1 1 1 0 6 4 4 4 180.2 10995.08350 -0.01251-- 10995.0960 6.6843 44.68 101. 2 1 1 1 1 0 6 4 4 4 199.6 10994.60240 -0.01554-- 10994.6179 7.4028 54.80 102. 2 1 1 1 1 0 6 4 4 4 210.3 10994.33970 -0.01303-- 10994.3527 7.8008 60.85 103. 2 1 1 1 1 0 6 4 4 4 240.2 10993.59720 -0.01543-- 10993.6126 8.9099 79.39 104. 2 1 1 1 1 0 6 4 4 4 269.9 10992.86060 -0.01653-- 10992.8771 10.0104 100.21 105. 2 1 1 1 1 0 6 4 4 4 299.7 10992.11440 -0.02181-- 10992.1362 11.1180 123.61 ! !--highest frequency component 106. 2 1 1 1 1 0 2 0 2 0 60.1 10998.18670 -0.01269-- 10998.1994 2.2311 4.98 107. 2 1 1 1 1 0 2 0 2 0 100.2 10997.15650 -0.01555-- 10997.1721 3.7148 13.80 108. 2 1 1 1 1 0 2 0 2 0 150.2 10995.89390 -0.01721-- 10995.9111 5.5705 31.03 109. 2 1 1 1 1 0 2 0 2 0 150.4 10995.89200 -0.01459-- 10995.9066 5.5772 31.10 110. 2 1 1 1 1 0 2 0 2 0 180.2 10995.14220 -0.01614-- 10995.1583 6.6843 44.68 111. 2 1 1 1 1 0 2 0 2 0 199.6 10994.65490 -0.01866-- 10994.6736 7.4028 54.80 112. 2 1 1 1 1 0 2 0 2 0 210.3 10994.39240 -0.01281-- 10994.4052 7.8008 60.85 113. 2 1 1 1 1 0 2 0 2 0 240.2 10993.63920 -0.01875-- 10993.6579 8.9099 79.39 114. 2 1 1 1 1 0 2 0 2 0 269.9 10992.89780 -0.01922-- 10992.9170 10.0104 100.21 115. 2 1 1 1 1 0 2 0 2 0 299.7 10992.14760 -0.02420-- 10992.1718 11.1180 123.61 ! ! principal multiplet to high frequency ! !--highest frequency component 116. 2 1 2 1 1 1 6 4 4 4 60.1 11001.25060 0.01028-- 11001.2403 2.2311 4.98 117. 2 1 2 1 1 1 6 4 4 4 100.2 11002.22570 0.01491-- 11002.2108 3.7148 13.80 118. 2 1 2 1 1 1 6 4 4 4 150.2 11003.46010 0.01749-- 11003.4426 5.5705 31.03 119. 2 1 2 1 1 1 6 4 4 4 150.4 11003.46110 0.01404-- 11003.4471 5.5772 31.10 120. 2 1 2 1 1 1 6 4 4 4 179.3 11004.18070 0.01608-- 11004.1646 6.6517 44.25 121. 2 1 2 1 1 1 6 4 4 4 199.6 11004.68640 0.01911-- 11004.6673 7.4028 54.80 122. 2 1 2 1 1 1 6 4 4 4 210.3 11004.94720 0.01327-- 11004.9339 7.8008 60.85 123. 2 1 2 1 1 1 6 4 4 4 240.2 11005.69430 0.01655-- 11005.6777 8.9099 79.39 124. 2 1 2 1 1 1 6 4 4 4 269.8 11006.42790 0.01310-- 11006.4148 10.0074 100.15 125. 2 1 2 1 1 1 6 4 4 4 299.7 11007.15850 -0.00282-- 11007.1613 11.1180 123.61 ! !--lowest frequency, strong component 126. 2 1 2 1 1 1 6 2 4 2 60.1 0.00000 -11001.65643-- 11001.6564 2.2311 4.98 127. 2 1 2 1 1 1 6 2 4 2 100.2 0.00000 -11002.15720-- 11002.1572 3.7148 13.80 128. 2 1 2 1 1 1 4 2 4 2 150.2 11003.38870 0.01443-- 11003.3743 5.5705 31.03 129. 2 1 2 1 1 1 4 2 4 2 150.4 11003.39020 0.01151-- 11003.3787 5.5772 31.10 130. 2 1 2 1 1 1 4 2 4 2 179.3 11004.10470 0.01263-- 11004.0921 6.6517 44.25 131. 2 1 2 1 1 1 6 2 4 2 199.6 11004.60710 0.01437-- 11004.5927 7.4028 54.80 132. 2 1 2 1 1 1 6 2 4 2 210.3 11004.87160 0.01309-- 11004.8585 7.8008 60.85 133. 2 1 2 1 1 1 6 2 4 2 240.2 11005.61380 0.01329-- 11005.6005 8.9099 79.39 134. 2 1 2 1 1 1 6 2 4 2 269.8 11006.34860 0.01228-- 11006.3363 10.0074 100.15 135. 2 1 2 1 1 1 6 2 4 2 299.7 11007.09210 0.01015-- 11007.0820 11.1180 123.61 Standard deviation = 0.002506 ITERATION NO = 3 CONSTANTS, deviations and changes: Mu.a = 4.012850165 +- 0.000287661 0.000000000 FINAL RESULTS OF LEAST SQUARES FITTING PROCEDURE ================================================ FITTED CONSTANTS: A /MHz 4500. 1:Xab /MHz 0. B /MHz 2749.90955 1:XJ.a/kHz 0. C /MHz 0. 1:XK.a/kHz 0. DJ /kHz 0.31878 1:XJbc/kHz 0. DJK /kHz 3.8524 1:Ma /MHz 0. DK /kHz 0. 1:Mb-c/MHz 0. dJ /kHz 0. 1:Tr /MHz 0. dK /kHz 0. 1:Xd /kHz 0. HJ / Hz 0. 1:Xbc /MHz 0. HJK / Hz 0. 1:Xac /MHz 0. HKJ / Hz 0. HK / Hz 0. hJ / Hz 0. hJK / Hz 0. Mu.a /D 4.01285(28) hK / Hz 0. Mu.b /D 0. LKKJ /mHz 0. Mu.c /D 0. 1:Xa /MHz -4.2143 d /cm 26.96 1:Xb-c/MHz 0. k /cm 0. 1:X.bb /MHz 2.107150000000 1:X.cc /MHz 2.107150000000 ------------------------------------------------------------------------------