40Ar...H35Cl Fri Oct 06 22:21:43 2017 -------------------------------------------------------------------------------------========= obs o-c error blends Notes o-c wt / instead of : below denotes (o-c)>3*err -------------------------------------------------------------------------------------========= 1: 1 2 2 0 2 2 3352.3306 0.0001 0.0010 2: 1 2 1 0 2 1 3352.3349 -0.0009 0.0015 3: 1 3 2 0 2 1 3358.0895 0.0010 0.0010 -0.0001 0.46 4: 1 3 3 0 2 2 3358.0895 -0.0011 0.0010 -0.0001 0.54 5: 1 1 1 0 2 1 3362.6973 -0.0006 0.0010 ! 6: 2 2 2 1 1 1 6707.6340 -0.0003 0.0010 7: 2 2 1 1 1 0 6707.6407 -0.0005 0.0015 8: 2 3 3 1 3 3 6708.1251 0.0003 0.0010 9: 2 3 2 1 3 2 6708.1295 -0.0001 0.0015 10: 2 2 2 1 3 3 6712.2411 -0.0005 0.0010 11: 2 2 1 1 3 2 6712.2492 0.0005 0.0015 12: 2 1 1 1 1 1 6713.3913 0.0005 0.0010 -0.0001 0.67 13: 2 1 1 1 1 0 6713.3913 -0.0014 0.0010 -0.0001 0.33 14: 2 1 0 1 1 1 6713.3966 -0.0001 0.0015 15: 2 3 2 1 2 1 6713.8810 -0.0012 0.0015 16: 2 4 3 1 3 2 6713.8864 0.0005 0.0010 0.0004 0.32 17: 2 3 3 1 2 2 6713.8864 0.0015 0.0010 0.0004 0.24 18: 2 4 4 1 3 3 6713.8864 -0.0002 0.0010 0.0004 0.44 19: 2 2 1 1 2 1 6718.0015 0.0002 0.0010 -0.0001 0.36 20: 2 2 2 1 2 2 6718.0015 -0.0003 0.0010 -0.0001 0.64 21: 2 1 1 1 2 2 6723.7581 -0.0001 0.0010 -0.0003 0.71 22: 2 1 0 1 2 1 6723.7581 -0.0007 0.0010 -0.0003 0.29 ! 23: 3 4 4 2 4 4 10063.3963 0.0015 0.0010 -0.0004 0.56 24: 3 4 3 2 4 3 10063.3963 -0.0029 0.0010 -0.0004 0.44 25: 3 3 3 2 4 4 10066.0879 0.0033 0.0010 0.0003 0.57 26: 3 3 2 2 4 3 10066.0879 -0.0038 0.0010 0.0003 0.43 27: 3 3 2 2 2 1 10067.7286 -0.0004 0.0010 -0.0008 0.39 28: 3 3 3 2 2 2 10067.7286 -0.0010 0.0010 -0.0008 0.61 29: 3 2 1 2 1 0 10067.7349 0.0018 0.0015 0.0017 0.28 30: 3 2 2 2 1 1 10067.7349 0.0016 0.0015 0.0017 0.71 31: 3 4 3 2 3 2 10069.1585 0.0029 0.0010 0.0005 0.17 32: 3 5 4 2 4 3 10069.1585 -0.0004 0.0010 0.0005 0.26 33: 3 4 4 2 3 3 10069.1585 0.0017 0.0010 0.0005 0.23 34: 3 5 5 2 4 4 10069.1585 -0.0007 0.0010 0.0005 0.33 35: 3 3 3 2 3 3 10071.8473 0.0006 0.0010 0.0001 0.59 36: 3 3 2 2 3 2 10071.8473 -0.0008 0.0010 0.0001 0.41 37: 3 2 2 2 2 2 10073.4901 0.0004 0.0010 0.0001 0.64 38: 3 2 1 2 2 1 10073.4901 -0.0005 0.0010 0.0001 0.36 39: 3 2 2 2 3 3 10077.6081 0.0015 0.0010 0.0003 0.61 40: 3 2 1 2 3 2 10077.6081 -0.0015 0.0010 0.0003 0.39 ! 41: 4 5 5 3 5 5 13417.3415 0.0021 0.0010 0.0003 0.55 42: 4 5 4 3 5 4 13417.3415 -0.0020 0.0010 0.0003 0.45 43: 4 4 3 3 3 2 13422.4366 0.0015 0.0010 -0.0002 0.25 44: 4 4 4 3 3 3 13422.4366 0.0010 0.0010 -0.0002 0.33 45: 4 3 2 3 2 1 13422.4366 -0.0020 0.0010 -0.0002 0.17 46: 4 3 3 3 2 2 13422.4366 -0.0022 0.0010 -0.0002 0.26 47: 4 5 4 3 4 3 13423.1060 0.0028 0.0010 0.0005 0.21 48: 4 5 5 3 4 4 13423.1060 0.0021 0.0010 0.0005 0.24 49: 4 6 5 3 5 4 13423.1060 -0.0009 0.0010 0.0005 0.25 50: 4 6 6 3 5 5 13423.1060 -0.0011 0.0010 0.0005 0.30 51: 4 4 4 3 4 4 13425.1266 0.0012 0.0010 0.0003 0.56 52: 4 4 3 3 4 3 13425.1266 -0.0009 0.0010 0.0003 0.44 53: 4 3 3 3 3 3 13428.1999 0.0010 0.0010 0.0005 0.59 54: 4 3 2 3 3 2 13428.1999 -0.0003 0.0010 0.0005 0.41 ! 55: 5 6 5 4 6 5 16769.4051 -0.0020 0.0010 0.0001 0.46 56: 5 6 6 4 6 6 16769.4051 0.0019 0.0010 0.0001 0.54 57: 5 5 4 4 4 3 16774.7773 0.0017 0.0010 -0.0003 0.25 58: 5 5 5 4 4 4 16774.7773 0.0013 0.0010 -0.0003 0.31 59: 5 4 3 4 3 2 16774.7773 -0.0023 0.0010 -0.0003 0.19 60: 5 4 4 4 3 3 16774.7773 -0.0025 0.0010 -0.0003 0.25 61: 5 6 5 4 5 4 16775.1728 0.0023 0.0010 -0.0002 0.20 62: 5 6 6 4 5 5 16775.1728 0.0019 0.0010 -0.0002 0.24 63: 5 7 6 4 6 5 16775.1728 -0.0020 0.0010 -0.0002 0.26 64: 5 7 7 4 6 6 16775.1728 -0.0021 0.0010 -0.0002 0.30 65: 5 5 5 4 5 5 16776.7985 0.0010 0.0010 0.0000 0.55 66: 5 5 4 4 5 4 16776.7985 -0.0014 0.0010 0.0000 0.45 67: 5 4 4 4 4 4 16780.5435 0.0003 0.0010 -0.0004 0.56 68: 5 4 3 4 4 3 16780.5435 -0.0013 0.0010 -0.0004 0.44 -------------------------------------------------------------------------------- PARAMETERS IN FIT (values truncated and Nlines statistics): 100 A /MHz 1678.508387(79) 1 200 DJ /kHz 20.0635(18) 2 110010000 chi.aa*3/2 /MHz -34.5434(22) 3 110010100 chi.aJ*3/2 /MHz -0.00238(18) 4 10020000 M.bb {+IMJ /MHz 0.000157(88) 5 -10030000 M.cc /MHz 0.000157(88) = 1.00000 * 5 20020000 M.bb {+IMJ /MHz [ 0.] 6 -20030000 M.cc /MHz [ 0.] = 1.00000 * 6 120010000 D.aa*3/2 /MHz -0.0090(11) 7 MICROWAVE AVG = -0.000046 MHz, IR AVG = 0.00000 MICROWAVE RMS = 0.000532 MHz, IR RMS = 0.00000 END OF ITERATION 1 OLD, NEW RMS ERROR= 0.42942 0.42942 distinct frequency lines in fit: 34 distinct parameters of fit: 6 upper state lower state overall limits of quantum number 1: 1 5 0 4 0 5 limits of quantum number 2: 1 7 1 6 1 7 limits of quantum number 3: 0 7 0 6 0 7 frequency range: 3352 16780 PARAMETERS IN FIT WITH STANDARD ERRORS ON THOSE THAT ARE FITTED: (values rounded and degrees of freedom, Ndegf=Nlines-Nconst, statistics) 100 A /MHz 1678.508387(37) 1 200 DJ /kHz 20.06353(87) 2 110010000 chi.aa*3/2 /MHz -34.5434(10) 3 110010100 chi.aJ*3/2 /MHz -0.002387(87) 4 10020000 M.bb {+IMJ /MHz 0.000157(41) 5 -10030000 M.cc /MHz 0.000157(41) = 1.00000 * 5 20020000 M.bb {+IMJ /MHz [ 0.] 6 -20030000 M.cc /MHz [ 0.] = 1.00000 * 6 120010000 D.aa*3/2 /MHz -0.00902(56) 7 ------------------------------------------------------------------------------------------ Worst fitted constants, with greater than 20% uncertainty: % 10020000 M.bb {+IMJ /MHz 0.000157(41) 5 26.5 -10030000 M.cc /MHz 0.000157(41) = 1.00000 * 5 26.5 ------------------------------------------------------------------------------------------ CORRELATION COEFFICIENTS, C.ij: A -DJ chi.aa*3 chi.aJ*3 M.bb {+I D.aa*3/2 A 1.0000 -DJ -0.8507 1.0000 chi.aa*3/2 -0.0855 0.0435 1.0000 chi.aJ*3/2 0.0626 -0.0421 -0.7465 1.0000 M.bb {+IMJ 0.5478 -0.2039 -0.1637 0.0562 1.0000 D.aa*3/2 -0.0479 0.0382 -0.1226 0.0608 -0.0079 1.0000 Mean value of |C.ij|, i.ne.j = 0.2053 Mean value of C.ij, i.ne.j = -0.0975 No correlations with absolute value greater than 0.9950 Worst fitted lines (obs-calc/error): 29: 1.1 27: -0.8 15: -0.8 5: -0.6 2: -0.6 31: 0.5 47: 0.5 10: -0.5 53: 0.5 23: -0.4 16: 0.4 67: -0.4 11: 0.3 7: -0.3 21: -0.3 39: 0.3 51: 0.3 6: -0.3 8: 0.3 41: 0.3 25: 0.3 57: -0.3 61: -0.2 43: -0.2 3: -0.1 12: -0.1 19: -0.1 55: 0.1 1: 0.1 35: 0.1 14: -0.1 9: -0.1 37: 0.1 65: 0.0 68: 0.0 66: 0.0 64: 0.0 63: 0.0 62: 0.0 60: 0.0 59: 0.0 58: 0.0 56: 0.0 54: 0.0 52: 0.0 50: 0.0 49: 0.0 48: 0.0 46: 0.0 45: 0.0 29: 3 2 1 2 1 0 10067.7349 0.0018 0.0015 0.0017 0.28 27: 3 3 2 2 2 1 10067.7286 -0.0004 0.0010 -0.0008 0.39 15: 2 3 2 1 2 1 6713.8810 -0.0012 0.0015 5: 1 1 1 0 2 1 3362.6973 -0.0006 0.0010 2: 1 2 1 0 2 1 3352.3349 -0.0009 0.0015 31: 3 4 3 2 3 2 10069.1585 0.0029 0.0010 0.0005 0.17 47: 4 5 4 3 4 3 13423.1060 0.0028 0.0010 0.0005 0.21 10: 2 2 2 1 3 3 6712.2411 -0.0005 0.0010 53: 4 3 3 3 3 3 13428.1999 0.0010 0.0010 0.0005 0.59 23: 3 4 4 2 4 4 10063.3963 0.0015 0.0010 -0.0004 0.56 _____________________________________ __________________________________________/ SPFIT output reformatted with PIFORM