CHF2Cl, 81Br satellite v9=1 @ 307.5 v5=1 @ 335 Sat Feb 19 21:50:27 2011 -------------------------------------------------------------------------------------========= obs o-c error blends Notes o-c wt / instead of : below denotes (o-c)>3*err -------------------------------------------------------------------------------------========= 1: 41 1 41 0 40 0 40 0 121238.1040 -0.0059 0.050 2: 41 2 40 0 40 1 39 0 122659.6930 -0.0170 0.050 3: 54 1 54 0 53 0 53 0 159420.5690 0.0272 0.050 4: 53 3 51 0 52 2 50 0 159326.0220 -0.0351 0.050 5: 56 1 56 0 55 0 55 0 165292.5060 -0.0062 0.050 6: 55 3 53 0 54 2 52 0 165197.2760 0.0093 0.050 7: 54 5 50 0 53 4 49 0 165133.2440 -0.0262 0.050 0.0165 0.50 8: 54 4 50 0 53 5 49 0 165133.2440 0.0591 0.050 0.0165 0.50 9: 68 1 68 0 67 0 67 0 200509.4870 0.0140 0.050 10: 67 3 65 0 66 2 64 0 200410.5860 0.0052 0.050 11: 66 5 62 0 65 4 61 0 200329.7050 -0.0298 0.050 12: 71 1 71 0 70 0 70 0 209309.3490 -0.0032 0.050 13: 70 3 68 0 69 2 67 0 209209.7000 0.0051 0.050 14: 74 1 74 0 73 0 73 0 218107.3350 0.0084 0.050 15: 74 2 73 0 73 1 72 0 219522.4030 0.0210 0.050 16: 73 4 70 0 72 3 69 0 219426.8830 0.0011 0.050 17: 72 6 67 0 71 5 66 0 219355.2350 -0.0283 0.050 18: 75 1 75 0 74 0 74 0 221039.5710 0.0235 0.050 19: 74 3 72 0 73 2 71 0 220938.9180 0.0000 0.050 20: 73 5 69 0 72 4 68 0 220852.1230 0.0006 0.050 21: 75 2 74 0 74 1 73 0 222454.4190 0.0184 0.050 22: 74 4 71 0 73 3 70 0 222358.4820 -0.0096 0.050 23: 73 6 68 0 72 5 67 0 222285.5610 -0.0034 0.050 24: 76 1 76 0 75 0 75 0 223971.5460 0.0012 0.050 25: 75 3 73 0 74 2 72 0 223870.7260 0.0471 0.050 26: 74 5 70 0 73 4 69 0 223783.1420 -0.0206 0.050 27: 80 2 79 0 79 1 78 0 237111.0970 0.0408 0.050 28: 79 4 76 0 78 3 75 0 237013.2430 0.0010 0.050 29: 78 6 73 0 77 5 72 0 236934.5360 -0.0376 0.050 30: 77 8 70 0 76 7 69 0 236900.7690 -0.0633 0.050 31: 96 3 94 0 95 2 93 0 285380.9530 -0.0340 0.050 32: 95 5 91 0 94 4 90 0 285282.3210 0.0082 0.050 33: 94 7 88 0 93 6 87 0 285200.7770 -0.0494 0.050 34: 93 9 85 0 92 8 84 0 285154.2270 0.0130 0.050 35: 92 11 82 0 91 10 81 0 285175.5520 -0.0588 0.050 36:103 1103 0 102 0102 0 303040.1220 -0.0064 0.050 37:102 3100 0 101 2 99 0 302933.2210 0.0602 0.050 38:109 2108 0 108 1107 0 321989.5500 0.0857 0.050 39:108 4105 0 107 3104 0 321882.7540 0.0078 0.050 40:107 6102 0 106 5101 0 321784.1890 0.0011 0.050 41:106 8 99 0 105 7 98 0 321702.9010 0.0513 0.050 42:105 10 96 0 104 9 95 0 321653.5560 0.0364 0.050 43:104 12 93 0 103 11 92 0 321661.9420 -0.0540 0.050 44:110 1110 0 109 0109 0 323505.2200 -0.0373 0.050 45:109 3107 0 108 2106 0 323396.6460 -0.0166 0.050 46:108 5104 0 107 4103 0 323292.9090 -0.0442 0.050 47:107 7101 0 106 6100 0 323201.2380 -0.0173 0.050 48:106 9 98 0 105 8 97 0 323132.8560 -0.0336 0.050 49:105 11 95 0 104 10 94 0 323106.9510 0.1240 0.050 50:112 1112 0 111 0111 0 329349.4780 -0.0573 0.050 ! 51: 56 1 56 1 55 0 55 1 165299.8570 -0.0091 0.050 52: 55 3 53 1 54 2 52 1 165201.7130 0.0084 0.050 53: 54 5 50 1 53 4 49 1 165134.7000 -0.1737 0.150 -0.1298 0.50 54: 54 4 50 1 53 5 49 1 165134.7000 -0.0858 0.150 -0.1298 0.50 55: 68 1 68 1 67 0 67 1 200517.6370 0.0027 0.050 56: 67 3 65 1 66 2 64 1 200415.9530 -0.0048 0.050 57: 66 5 62 1 65 4 61 1 200332.3470 -0.0310 0.050 58: 71 1 71 1 70 0 70 1 209317.6280 -0.0063 0.050 59: 70 3 68 1 69 2 67 1 209215.2210 -0.0099 0.050 60: 74 1 74 1 73 0 73 1 218115.6990 0.0048 0.050 61: 74 2 73 1 73 1 72 1 219529.4290 0.0216 0.050 62: 73 4 70 1 72 3 69 1 219431.2200 -0.0057 0.050 63: 72 6 67 1 71 5 66 1 219357.0270 0.0359 0.050 64: 75 1 75 1 74 0 74 1 221047.9450 0.0095 0.050 65: 74 3 72 1 73 2 71 1 220944.6130 -0.0012 0.050 66: 73 5 69 1 72 4 68 1 220855.1390 -0.0303 0.050 67: 75 2 74 1 74 1 73 1 222461.4660 0.0147 0.050 68: 74 4 71 1 73 3 70 1 222362.8640 -0.0107 0.050 69: 73 6 68 1 72 5 67 1 222287.3360 -0.0070 0.050 70: 75 3 73 1 74 2 72 1 223876.4330 0.0275 0.050 71: 74 5 70 1 73 4 69 1 223786.2370 -0.0163 0.050 72: 80 2 79 1 79 1 78 1 237118.1820 0.0105 0.050 73: 79 4 76 1 78 3 75 1 237017.7280 -0.0346 0.050 74: 78 6 73 1 77 5 72 1 236936.5950 0.0403 0.050 75: 97 1 97 1 96 0 96 1 285494.2530 -0.0273 0.050 76: 96 3 94 1 95 2 93 1 285386.2850 -0.0673 0.050 77: 95 5 91 1 94 4 90 1 285285.4410 0.0506 0.050 78: 93 9 85 1 92 8 84 1 285152.9800 0.0578 0.050 79: 92 11 82 1 91 10 81 1 285172.4640 0.0527 0.050 80:102 3100 1 101 2 99 1 302938.0120 -0.0204 0.050 81:101 5 97 1 100 4 96 1 302834.7780 -0.0009 0.050 82: 99 9 91 1 98 8 90 1 302686.0550 -0.0537 0.050 83:107 6102 1 106 5101 1 321785.3300 0.0355 0.050 84:105 10 96 1 104 9 95 1 321650.8310 -0.0027 0.050 85:109 3107 1 108 2106 1 323400.6860 -0.0259 0.050 86:108 5104 1 107 4103 1 323295.0480 0.0511 0.050 87:107 7101 1 106 6100 1 323201.2380 0.0000 0.050 88:106 9 98 1 105 8 97 1 323131.0470 -0.0322 0.050 89:112 0112 1 111 1111 1 329355.3150 0.0255 0.050 90:107 12 96 1 106 11 95 1 330401.7600 -0.0408 0.050 ! 91: 19 19 1 0 18 18 0 0 143994.6580 -0.0172 0.050 92: 21 21 1 0 20 20 0 0 159382.2520 0.0007 0.050 93: 29 29 1 0 28 28 0 0 220903.1930 -0.0114 0.050 94: 38 38 1 0 37 37 0 0 290042.4880 -0.0774 0.050 95: 39 39 1 0 38 38 0 0 297719.0720 0.0016 0.050 96: 27 26 2 0 26 25 1 0 200994.5760 -0.0103 0.050 97: 30 29 2 0 29 28 1 0 224058.4140 0.0157 0.050 98: 38 37 2 0 37 36 1 0 285518.4940 -0.0102 0.050 99: 43 42 2 0 42 41 1 0 323893.5940 0.1059 0.050 100: 23 21 3 0 22 20 2 0 165694.7670 -0.0091 0.050 101: 30 28 3 0 29 27 2 0 219526.5200 -0.0102 0.050 102: 28 25 4 0 27 24 3 0 199616.0300 0.0122 0.050 103: 31 28 4 0 30 27 3 0 222681.5380 0.0359 0.050 104: 44 41 4 0 43 40 3 0 322525.9180 0.0673 0.050 105: 45 42 4 0 44 41 3 0 330197.7470 -0.0354 0.050 106: 24 20 5 0 23 19 4 0 164313.4470 0.0559 0.050 107: 31 27 5 0 30 26 4 0 218148.7630 -0.0122 0.050 108: 42 38 5 0 41 37 4 0 302654.9220 -0.0375 0.050 109: 32 27 6 0 31 26 5 0 221303.3970 -0.0048 0.050 110: 45 40 6 0 44 39 5 0 321156.9440 0.0967 0.050 111: 30 24 7 0 29 23 6 0 201390.8820 -0.0517 0.050 112: 33 26 8 0 32 25 7 0 219923.7100 -0.0652 0.200 113: 34 26 9 0 33 25 8 0 223077.4930 -0.0040 0.050 114: 45 37 9 0 44 36 8 0 307587.1500 -0.0213 0.050 115: 47 39 9 0 46 38 8 0 322937.7030 0.0107 0.050 116: 45 36 10 0 44 35 9 0 303061.6400 -0.0684 0.050 117: 35 25 11 0 34 24 10 0 221694.9890 -0.0262 0.050 118: 48 38 11 0 47 37 10 0 321565.0810 -0.0526 0.050 119: 47 36 12 0 46 35 11 0 309363.8670 -0.0421 0.050 120: 36 24 13 0 35 23 12 0 220309.6040 0.1099 0.100 121: 37 24 14 0 36 23 13 0 223460.5190 0.0573 0.050 122: 45 32 14 0 44 31 13 0 284947.7350 -0.0945 0.050 123: 50 37 14 0 49 36 13 0 323340.5030 -0.0042 0.100 124: 37 23 15 0 36 22 14 0 218919.8050 0.0058 0.050 125: 48 34 15 0 47 33 14 0 303458.3440 -0.1139 0.050 126: 38 23 16 0 37 22 15 0 222068.8840 -0.0243 0.050 127: 49 33 17 0 48 32 16 0 302077.4300 0.1135 0.050 128: 48 30 18 0 47 29 19 0 285328.0130 -0.0001 0.050 129: 41 21 21 0 40 20 20 0 222405.1860 0.1279 0.050 130: 55 35 21 0 54 34 20 0 330023.7210 -0.0041 0.050 131: 42 20 23 0 41 19 22 0 220979.4950 0.0458 0.050 132: 43 20 24 0 42 19 23 0 224113.3430 -0.0462 0.050 133: 55 33 23 0 54 32 22 0 320957.3020 0.0572 0.050 134: 44 19 26 0 43 18 25 0 222658.8950 0.0448 0.200 135: 43 19 25 0 42 18 24 0 219532.9310 0.0006 0.050 136: 44 18 27 0 43 17 26 0 218055.7970 0.0014 0.050 137: 45 18 28 0 44 17 27 0 221170.5080 0.0268 0.050 138: 55 29 27 0 54 28 26 0 302791.9720 -0.0011 0.050 139: 58 31 28 0 57 30 27 0 321303.1330 -0.0178 0.100 140: 46 17 30 0 45 16 29 0 219631.6270 0.0632 0.050 141: 57 29 29 0 56 28 28 0 309067.7690 -0.0750 0.050 142: 47 17 31 0 46 16 30 0 222724.7620 -0.0263 0.050 143: 60 30 31 0 59 29 30 0 323027.8060 0.0072 0.050 144: 48 16 33 0 47 15 32 0 221082.4830 0.0056 0.050 145: 58 27 32 0 57 26 31 0 303082.1710 0.0582 0.050 146: 49 16 34 0 48 15 33 0 224141.8830 -0.0525 0.050 147: 60 27 34 0 59 26 33 0 309337.8410 0.1062 0.100 148: 61 29 33 0 60 28 32 0 321602.7280 -0.0274 0.050 ! 149: 19 19 1 1 18 18 0 1 143998.0620 -0.0301 0.050 150: 21 21 1 1 20 20 0 1 159386.0070 -0.0150 0.050 151: 22 22 1 1 21 21 0 1 167078.9920 -0.0035 0.050 152: 29 29 1 1 28 28 0 1 220908.3810 0.1006 0.050 153: 38 38 1 1 37 37 0 1 290048.8260 -0.0132 0.050 154: 40 40 1 1 39 39 0 1 305400.8180 -0.0043 0.050 155: 30 29 2 1 29 28 1 1 224063.1980 -0.0937 0.100 156: 38 37 2 1 37 36 1 1 285524.6080 0.0450 0.100 157: 23 21 3 1 22 20 2 1 165698.0830 0.0170 0.100 158: 28 25 4 1 27 24 3 1 199619.8300 0.0023 0.050 159: 31 28 4 1 30 27 3 1 222685.9150 0.0546 0.100 160: 44 41 4 1 43 40 3 1 322532.3480 0.0275 0.050 161: 45 42 4 1 44 41 3 1 330204.3440 -0.0494 0.050 162: 24 20 5 1 23 19 4 1 164316.0230 0.0140 0.050 163: 31 27 5 1 30 26 4 1 218152.7600 -0.0011 0.100 164: 32 27 6 1 31 26 5 1 221307.2260 0.0272 0.100 165: 45 40 6 1 44 39 6 1 321163.2320 0.1502 0.100 166: 30 24 7 1 29 23 6 1 201393.8180 -0.1016 0.050 167: 33 26 8 1 32 25 7 1 219927.1510 0.1637 0.200 168: 34 26 9 1 33 25 8 1 223080.5030 -0.0178 0.050 169: 45 37 9 1 44 36 8 1 307592.6490 0.0043 0.050 170: 47 39 9 1 46 38 8 1 322943.5040 -0.1007 0.100 171: 45 36 10 1 44 35 9 1 303066.8450 -0.0356 0.050 172: 35 25 11 1 34 24 10 1 221697.4390 0.0066 0.050 173: 48 38 11 1 47 37 10 1 321570.7670 0.0439 0.050 174: 47 36 12 1 46 35 11 1 309368.8260 -0.1063 0.050 175: 36 24 13 1 35 23 12 1 220311.3810 0.0916 0.050 176: 37 24 14 1 36 23 13 1 223462.1060 0.0341 0.050 177: 48 35 14 1 47 34 13 1 307991.7550 0.0413 0.050 178: 50 37 14 1 49 36 13 1 323345.7040 0.0185 0.050 179: 37 23 15 1 36 22 14 1 218920.9570 -0.0066 0.050 180: 48 34 15 1 47 33 14 1 303463.0200 0.3230 0.200 181: 38 23 16 1 37 22 15 1 222069.8870 -0.0035 0.050 182: 48 30 18 1 47 29 19 1 285330.6810 0.0584 0.100 183: 41 21 21 1 40 20 20 1 222404.5310 -0.1140 0.100 184: 42 20 23 1 41 19 22 1 220978.4180 -0.0592 0.050 185: 43 20 24 1 42 19 23 1 224112.2540 -0.0330 0.050 186: 43 19 25 1 42 18 24 1 219531.4070 -0.0636 0.100 187: 44 18 27 1 43 17 26 1 218053.9440 -0.0228 0.050 188: 44 19 26 1 43 18 25 1 222657.2810 -0.0098 0.100 189: 47 17 31 1 46 16 30 1 222722.8600 0.0106 0.050 190: 48 16 33 1 47 15 32 1 221080.9940 0.0621 0.050 191: 49 16 34 1 48 15 33 1 224140.6170 0.0118 0.050 192: 49 13 37 1 48 12 36 1 208969.0550 -0.0044 0.050 -------------------------------------------------------------------------------- PARAMETERS IN FIT: 10000 A /MHz 3851.10629(50) 1 20000 B /MHz 1684.0692(15) 2 30000 C /MHz 1470.26777(17) 3 200 DJ /kHz 0.193463(66) 4 1100 DJK /kHz 0.06686(28) 5 2000 DK /kHz 1.09626(35) 6 40100 d1 /kHz -0.037949(48) 7 50000 d2 /kHz -0.003023(15) 8 300 HJ /Hz [ 0.000011903] 9 1200 HJK /Hz [ 0.000250872] 10 2100 HKJ /Hz [-0.001239213] 11 3000 HK /Hz [ 0.002727639] 12 40200 h1 /Hz [ 0.000007926] 13 50100 h2 /Hz [ 0.000002598] 14 60000 h3 /Hz [ 0.000000183] 15 10011 A /MHz 3849.03992(56) 16 20011 B /MHz 1680.4844(17) 17 30011 C /MHz 1470.35440(19) 18 211 DJ /kHz 0.197902(76) 19 1111 DJK /kHz 0.07852(43) 20 2011 DK /kHz 1.08812(49) 21 40111 d1 /kHz -0.038938(56) 22 50011 d2 /kHz -0.002959(19) 23 311 HJ /Hz [ 0.000011903] 24 1211 HJK /Hz [ 0.000250872] 25 2111 HKJ /Hz [-0.001239213] 26 3011 HK /Hz [ 0.002727639] 27 40211 h1 /Hz [ 0.000007926] 28 50111 h2 /Hz [ 0.000002598] 29 60011 h3 /Hz [ 0.000000183] 30 11 DE /MHz 858102.(74) 31 200001 Ga /MHz [-964.] 32 400001 Gb /MHz [1175.] 33 MICROWAVE AVG = 0.002309 MHz, IR AVG = 0.00000 MICROWAVE RMS = 0.053274 MHz, IR RMS = 0.00000 END OF ITERATION 1 OLD, NEW RMS ERROR= 0.82911 0.82911 distinct frequency lines in fit: 190 distinct parameters of fit: 17 for standard parameter errors previous errors are multiplied by: 0.868892 MICROWAVE lines fitted lines lines RMS RMS ERROR J range Ka range total dv=0 dv.ne.0 UNFITTD e>900 v"=0: 107 107 0 0 0 0.046168 0.87420 18 112 0 42 v"=1: 83 83 0 0 0 0.061171 0.76559 18 112 0 42 PARAMETERS IN FIT WITH STANDARD ERRORS ON THOSE THAT ARE FITTED: 10000 A /MHz 3851.10629(43) 1 20000 B /MHz 1684.0692(13) 2 30000 C /MHz 1470.26777(15) 3 200 DJ /kHz 0.193463(57) 4 1100 DJK /kHz 0.06686(24) 5 2000 DK /kHz 1.09626(30) 6 40100 d1 /kHz -0.037949(41) 7 50000 d2 /kHz -0.003023(13) 8 300 HJ /Hz [ 0.000011903] 9 1200 HJK /Hz [ 0.000250872] 10 2100 HKJ /Hz [-0.001239213] 11 3000 HK /Hz [ 0.002727639] 12 40200 h1 /Hz [ 0.000007926] 13 50100 h2 /Hz [ 0.000002598] 14 60000 h3 /Hz [ 0.000000183] 15 10011 A /MHz 3849.03992(48) 16 20011 B /MHz 1680.4844(15) 17 30011 C /MHz 1470.35440(17) 18 211 DJ /kHz 0.197902(66) 19 1111 DJK /kHz 0.07852(37) 20 2011 DK /kHz 1.08812(42) 21 40111 d1 /kHz -0.038938(48) 22 50011 d2 /kHz -0.002959(16) 23 311 HJ /Hz [ 0.000011903] 24 1211 HJK /Hz [ 0.000250872] 25 2111 HKJ /Hz [-0.001239213] 26 3011 HK /Hz [ 0.002727639] 27 40211 h1 /Hz [ 0.000007926] 28 50111 h2 /Hz [ 0.000002598] 29 60011 h3 /Hz [ 0.000000183] 30 11 DE /MHz 858102.(64) 31 200001 Ga /MHz [-964.] 32 400001 Gb /MHz [1175.] 33 CORRELATION COEFFICIENTS, C.ij: A B C -DJ -DJK -DK d1 d2 A 1.0000 B -0.5556 1.0000 C 0.3076 -0.6398 1.0000 -DJ 0.1927 -0.4179 0.2493 1.0000 -DJK 0.0666 -0.3686 0.2010 -0.5907 1.0000 -DK -0.5646 0.6726 -0.3667 0.2384 -0.8206 1.0000 d1 0.1690 -0.4075 0.3151 0.9943 -0.5908 0.2493 1.0000 d2 0.0273 -0.2046 0.1718 0.9515 -0.6822 0.4008 0.9630 1.0000 A -0.0478 -0.0070 -0.0046 0.0047 -0.0139 0.0146 0.0054 0.0085 B -0.0071 -0.0074 0.0013 -0.0011 -0.0019 0.0021 -0.0006 0.0008 C 0.0178 0.0117 -0.0035 0.0028 0.0006 -0.0008 0.0022 0.0014 -DJ 0.0367 0.0179 -0.0005 -0.0238 0.0247 -0.0173 -0.0237 -0.0238 -DJK -0.0345 -0.0134 -0.0005 0.0194 -0.0223 0.0158 0.0188 0.0177 -DK 0.0310 0.0107 0.0005 -0.0157 0.0179 -0.0129 -0.0151 -0.0141 d1 0.0421 0.0205 -0.0010 -0.0230 0.0244 -0.0172 -0.0231 -0.0234 d2 0.0484 0.0230 -0.0012 -0.0218 0.0231 -0.0160 -0.0220 -0.0226 DE -0.2213 -0.0350 -0.0262 0.0170 -0.0801 0.0804 0.0198 0.0365 A B C -DJ -DJK -DK d1 d2 A 1.0000 B -0.4047 1.0000 C 0.1679 -0.5874 0.0000 -DJ 0.0915 -0.3641 0.2065 0.0000 -DJK -0.0703 -0.4617 0.1943 -0.4569 0.0000 -DK -0.3138 0.6662 -0.2887 0.2345 -0.8946 0.0000 d1 0.0547 -0.3581 0.2810 0.9934 -0.4442 0.2334 0.0000 d2 -0.0726 -0.1794 0.1453 0.9527 -0.4908 0.3260 0.9644 0.0000 DE 0.2057 0.0394 -0.0975 -0.1874 0.1803 -0.1575 -0.2158 -0.2489 DE DE 0.0000 Mean value of |C.ij|, i.ne.j = 0.1918 Mean value of C.ij, i.ne.j = -0.0046 Worst fitting lines (obs-calc/error): 129: 2.6 49: 2.5 125: -2.3 127: 2.3 174: -2.1 99: 2.1 166: -2.0 152: 2.0 110: 1.9 122: -1.9 175: 1.8 38: 1.7 180: 1.6 94: -1.5 165: 1.5 141: -1.5 116: -1.4 76: -1.3 104: 1.3 30: -1.3 140: 1.3 190: 1.2 37: 1.2 184: -1.2 35: -1.2 145: 1.2 78: 1.2 121: 1.1 50: -1.1 133: 1.1 183: -1.1 106: 1.1 120: 1.1 43: -1.1 82: -1.1 147: 1.1 79: 1.1 118: -1.1 146: -1.0 111: -1.0 41: 1.0 86: 1.0 77: 1.0 170: -1.0 161: -1.0 33: -1.0 25: 0.9 155: -0.9 132: -0.9 131: 0.9 _____________________________________ __________________________________________/ SPFIT output reformatted with PIFORM