RESEARCH INTERESTS

Single molecule spectroscopy;
Photophysics and photochemistry;
Ab initio calculations of small molecules

PhD THESIS

Structure, electronic spectra and photophysics of 2-alkylamino- 4-nitropyridine N-oxides. Studies by quantum chemical methods.

REPRESENTATIVE PUBLICATIONS

M. Bialkowska, I. Deperasiñska, A. Makarewicz, B. Kozankiewicz,Anomalous doping of a molecular crystal monitored with confocal fluorescence microscopy: Terrylene in a p-terphenyl crystalJ. Chem. Phys. 147 (2017) 114302

M. Bialkowska, W. Chaladaj, I. Deperasinska, A. Drzewiecka-Antonik, A.E. Koziol, A. Makarewicz, B. Kozankiewicz, Single molecules of terrylene in di-substituted naphthalenes crystallizing in the herringbone pattern RSC Advances 7 (2017) 2780-2788

M. Grzybowski, I. Deperasiñska, M. Chotkowski, M. Banasiewicz, A. Makarewicz, B. Kozankiewicz, D. T. Gryko, Dipyrrolonaphthyridinediones - structurally unique cross-conjugated dyes Chem. Commun. 52 (2016) 5108

D. Firmansyah, I. Deperasiñska, O. Vakuliuk, M. Banasiewicz, M. Tasior, A. Makarewicz, M. K. Cyrañski, B. Kozankiewicz, D. T. Gryko, Double head-to-tail direct arylation as a viable strategy towards aza-analog of dihydrocyclopenta[hi]aceanthrylene - intriguing antiaromatic heterocycle. Chem. Commun. 52 (2016) 1262

I. Deperasinska, A. Makarewicz, M. Krzeszewski, D. T. Gryko, B. Kozankiewicz, Photophysics of Derivatives of 3-Hydroxybenzo[c]coumarin J. Phys. Chem. A 119 (2015) 9051-9058

M. Banasiewicz, I. Deperasinska, A. Makarewicz, D. Firmansyah, D. T. Gryko, B. Kozankiewicz, Why vertically p-expanded imidazo[1,2-a]pyridines are weak fluorescence emitters: experimental and computational studies Physical Chemistry and Chemical Physics 17 (2015) 8945-8950

D. Firmansyah, M. Banasiewicz, I. Deperasinska, A. Makarewicz, B. Kozankiewicz, D. T. Gryko, Vertically pi-Expanded Imidazo[1,2-a]pyridine – Missing Link of the Puzzle Chemistry - An Asian Journal 9 (2014) 2483-2493

M. Bialkowska, A. Makarewicz, M. Banasiewicz, B. Kozankiewicz, Spin-lattice relaxation and anomalous intersystem crossing in single molecule of terrylene embedded in p-perphenyl crystal, Chemical Physics Letters, 555 (2013) 131-134

Szemik-Hojniak A. Wisniewski L. Deperasinska I, Makarewicz A. Jerzykiewicz L. Puszko A. Erez Y. Huppert D, The impact of solvent polarity on intramolecular proton and electron transfer in 2-alkylamino-4-nitro-5-methyl pyridine N-oxides, PHYSICAL CHEMISTRY CHEMICAL PHYSICS Vol. 14 (2012) 8147-8159

A. Makarewicz, I. Deperasiñska, E. Karpiuk, J. Nowacki, B. Kozankiewicz, Vibronic spectra of single dibenzoterrylene molecules in anthracene and 2,3-dimenthylanthracene crystals. Chemical Physics Letter 535 (2012) 140-145.

I. Deperasiñska, D.T. Gryko, E. Karpiuk, B. Kozankiewicz, A. Makarewicz, J. Piechowska, 12-Hydroxy-1-Azaperylene - Limiting Case of the ESIPT System: Enol-Keto Tautomerization in S0 and S1 State, Journal of Physical Chemistry A 116 (2012) 2109-2116.

I. Deperasiñska, D.T. Gryko, E. Karpiuk, B. Kozankiewicz, A. Makarewicz, J. Piechowska. Low Temperature Spectra of the Analogues of 10-Hydroxybenzo[h]quinoline as Indication of Barrierless ESIPT Journal of Physical Chemistry A 116 (49) (2012) 12049-12055

B. Kozankiewicz, I. Deperasinska, E. Karpiuk, M. Banasiewicz, A. Makarewicz, "On Photo-Oxidation of Single Molecules", Optical Materials, 33 (2011) 1391

I. Deperasinska, E. Karpiuk, M. Banasiewicz, A. Makarewicz, B. Kozankiewicz, "Single dibenzoterrylene molecules in naphthalene and 2,3-dimethylnaphthalene crystals: vibronic spectra", Physical Chemistry and Chemical Physics, 13 (2011) 1872

L. Wisniewski, A. Urbanowicz, L. Jerzykiewicz, A. Makarewicz, I. Deperasinska, G. van der Zwan, N. Haraszkiewicz, A. Puszko and A. Szemik-Hojniak, "Crystal structure, spectroscopic, and theoretical studies of 2-methylamino-6-methyl-4 nitropyridine N-oxide", Journal of Molecular Structure, 920 (2009) 45

A. Makarewicz, A. Szemik-Hojniak, G. van der Zwan, and I. Deperasinska, "Complex photophysical and photochemical behavior of 2-alkylamino-6-methyl-4-nitropyridine Noxides", Journal of Physical Chemistry A,113 (2009) 3438

CONFERENCE PRESENTATIONS

A. Makarewicz, I. Deperasinska, A. Szemik-Hojniak, ,,Modelowanie struktury i widma elektronowego dimeru N-tlenku 2-butyloamino-6-metylo-4-nitropirydyny’’, konferencja ,,Krysztaly molekularne 2010’’ w Polanicy Zdroj, 13-17 wrzesnia 2010, Materia³y, str. 90, - poster.

B. Kozankiewicz, I. Deperasinska, E. Karpiuk, A. Makarewicz, On photo-oxidation of terrylene. Contribution to single molecule studies, 12th International Conference. Electronic and Related Properties of Organic Systems, July 11-13, 2011, Vilnius, Lithuania, Abstract book, p. 62 -poster.

B. Kozankiewicz, I. Deperasinska, E. Karpiuk, A. Makarewicz, On vibronic spectra of single molecules, Second French-Polish Workshop on Organic Electronics and Nanophotonics, September 4-8, 2011, Angers, France, Abstracts, I-35 (invited lecture).

I. Deperasinska, B. Kozankiewicz, E. Karpiuk, M. Banasiewicz, A. Makarewicz, Badania pojedynczych czasteczek terylenu oraz dibenzoterylenu, Sesja Sprawozdawczo-Szkoleniowa U¿ytkowników KDM - Bêdlewo 2011, 23-26 marca 2011, wyst¹pienie konferencyjne i poster.

A. Makarewicz, B. Kozankiewicz, I. Deperasinska, E. Karpiuk, M. Banasiewicz, Widma wibronowe pojedynczej cz¹steczki dibenzoterylenu w krysztale molekularnym, konferencja ,,Kryszta³y molekularne 2012’’ w Gdansku-Sobieszewie, 10-14 wrzeœnia 2012, Materia³y, str. 81; -poster.

M. Bialkowska, A. Makarewicz, B. Kozankiewicz, Badania relaksacji spin-sieæ dla pojedynczych cz¹steczek terylenu w krysztale p-terfenylu, ,,Krysztaly molekularne 2012’’ w Gdañsku-Sobieszewie, 10-14 wrzesnia 2012, Materialy, str. 58; -poster.

I. Deperasinska, D.T. Gryko, E. Karpiuk, B. Kozankiewicz, A. Makarewicz, J. Piechowska, Graniczny przypadek wewnatrz-molekularnego przeniesienia protonu-cz¹steczka 12-hydroxy-1-azaperylenu, konferencja ,,Krysztaly molekularne 2014’’ Krakow - Sromowce Nizne, 8-12 wrzesnia 2014, Materialy, str. 121 -poster

M. Bialkowska, A. Makarewicz, B. Kozankiewicz, Badania widm wzbudzenia fluorescencji skupisk cz¹steczek terylenu w krysztalach p-terfenylu, konferencja ,,Krysztaly molekularne 2014’’ Kraków - Sromowce Ni¿ne, 8-12 wrzesnia 2014, Materialy, str. 127, -poster

D. Firmansyah, M. Banasiewicz, I. Deperasinska, A. Makarewicz, B. Kozankiewicz, D.T. Gryko, Wlasnoœci spektroskopowe pochodnych imidazo[1,2-a]pirydyny, konferencja ,,Krysztaly molekularne 2014’’ Krakow - Sromowce Nizne, 8-12 wrzesnia 2014, Materialy, str. 103, -poster

A. Szemik-Hojniak, I. Deperasinska, A. Makarewicz, D. Huppert, Y. Erez, “Intramolecular Process of Proton Coupled Electron Transfer in Alkylamino-Nitro Pyridine N-oxides”, International Conference of Computational Methods in Sciences and Engineering 2014, Ateny, Grecja, 04-07 kwiecieñ 2014 – oral presentation.

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