INSTITUTE OF PHYSICS POLISH ACADEMY OF SCIENCE


ON21 MOLECULAR PHOTOPHYSICS GROUP




Dr hab. Irena Deperasińska

Position

Associate Professor

Address

Al. Lotnikow 32/46
02-668 Warszawa Poland

Phone

+(48-22) 843-66-01 (after connection dial 3295)

E-mail

deper@ifpan.edu.pl

WWW

www.ifpan.edu.pl/ON-2/on21/deper.html





RESEARCH INTERESTS

  • The photophysical properties of the molecular system
  • Determination of the structures of organic molecules and molecular complexes by quantum chemistry calculations


REPRESENTATIVE PUBLICATIONS


103. High-resolution vibronic spectroscopy of a single molecule embedded in a crystal
Johannes Zirkelbach, Masoud Mirzaei,Irena Deperasińska, Bolesław Kozankiewicz,Burak Gurlek,Alexey Shkarin,Tobias Utikal, Stephan Gotzinger, Vahid Sandoghdar,
The Journal of Chemical Physics 154 (2022) 104301.


102. Single organic molecules for photonic quantum technologies.
C. Toninelli, I. Gerhardt, A.S. Clark, A. Reserbat-Plantey, S. Goetzinger, Z. Ristanovic, M. Colautti, P. Lombardi, K.D. Major, Irena Deperasińska, W.H. Pernice, F.H.L. Koppens, Bolesław Kozankiewicz, A. Gourdon, V. Sandoghdar, Michel Orrit,
Nature Materials 20 (2021) 1615-1628.


101. Polarized, V-Shaped, and Conjoined Biscoumarins: From Lack of Dipole Moment Alignment to High Brightness"
Łukasz Kielesiński, Irena Deperasińska,* Olaf Morawski, Kateryna V. Vygranenko, Erik T. Ouellette and Daniel T. Gryko*
J. Org. Chem., 87 (2022) 5961-5975.


7. Quadrupolar Dyes Based on Highly Polarized Coumarins
Krzysztof Górski, Irena Deperasińska, Glib V. Baryshnikov, Shuhei Ozaki, Kenji Kamada, Hans Agren, and Daniel T. Gryko,
Organic Letters 23 (2021) 6770-6774.


100. Spectra and nature of the electronic states of [1]Benzothieno[3,2?b][1]benzothiophene (BTBT): single crystal and the aggregates.
Irena Deperasińska, Marzena Banasiewicz, Paweł Gawryś, Olaf Morawski, Joanna Olas, Bolesław Kozankiewicz,
The Journal of Chemical Physics 155 (2021) 034504.


9. Laser-Induced Frequency Tuning of Fourier-Limited Single-Molecule Emitters
Maja Colautti, Francesco S. Piccioli, Zoran Ristanovia, Pietro Lombardi, Amin Moradi, Subhasis Adhikari, Irena Deperasińska, Bolesław Kozankiewicz, Michel Orrit*, and Costanza Toninelli*
ACS Nano 14 (2020) 13584-13592.


8. Luminescent properties of chameleon-like metal-organic framework between zinc(II) dichloride and two quinoline-N-oxide molecules
Anna Szemik-Hojniak, Irena Deperasińska, Yakov Nizhnik, Lucjan Jerzykiewicz
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 239 (2020) 118464.


99. Non-planar distortion of terrylene molecules in a naphthalene crystal
Irena Deperasińska, Bolesław Kozankiewicz
Chem. Phys. Letters 684 (2019) 208-211.


20. Building Molecular Complexity from Quinizarin: Conjoined Coumarins and Coronene Analogs
M. K. Wecławski, Irena Deperasińska, Marzena Banasiewicz, D. C. Young, A. Leniak, Daniel T. Gryko,
Chem. Asian J. 14 (2019) 1763-1770.


19. Matrix-induced Linear Stark Effect of Single Dibenzoterrylene Molecules in 2,3-Dibromonaphthalene Crystal
Amin Moradi, Zoran Ristanovic, Michel Orrit, Irena Deperasińska, and Bolesław Kozankiewicz,
ChemPhysChem 20 (2019) 55-61.


18. Spectra and nature of the electronic excited states of 2,3-dibromonaphthalene single crystals
Irena Deperasińska, Marzena Banasiewicz, Bolesław Kozankiewicz,
Journal of Luminescence 213 (2019) 108-116.


13. The influence of tetraphenylethylene moieties on the emissive properties of dipyrrolonaphthyridinediones
Bartek Sadowski, S.-H. Su, T.-C. Lin, T. D. Lohrey, Irena Deperasińska, P.-T. Chou, Daniel T. Gryko,
J. Mat. Chem. C, 6 (2018) 12306-12313.


12. Non-planar distortion of terrylene molecules in a naphthalene crystal
Irena Deperasińska, Bolesław Kozankiewicz,
Chem.Phys.Lett. 684 (2017) 208-211.


11. Anomalous doping of a molecular crystal monitored with confocal fluorescence microscopy: Terrylene in a p-terphenyl crystal
Magda Białkowska, Irena Deperasińska, Artur Makarewicz, Bolesław Kozankiewicz,
J.Chem.Phys. 147 (2017) 114302.


10. Unprecedented rearrangement of diketopyrrolopyrroles leads to structurally unique chromophores
O.Vakuliuk, S. Ooi, Irena Deperasińska, O. Staszewska-Krajewska, Marzena Banasiewicz, Bolesław Kozankiewicz, O. Danylyuk and Daniel T. Gryko et al.
Chem. Commun. 53 (2017) 11877-11880.


9. Photophysical behavior of a potential drug candidate, trans-[2-(4-methoxystyryl)] quinoline 1-oxide tuned by environment effects
Anna Szemik-Hojniak, Irena Deperasińska, Yakov P. Nizhnik,
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 187 (2017) 198-206.


98. Single molecules of terrylene in di-substituted naphthalenes crystallizing in the herringbone pattern
Magda Białkowska, W. Chaladaj, Irena Deperasińska, A. Drzewiecka-Antonik, A.E. Kozioł, Artur Makarewicz, Bolesław Kozankiewicz
RSC Advances 7 (2017) 2780-2788.


97. Dipyrrolonaphthyridinediones - structurally unique cross-conjugated dyes
M. Grzybowski, Irena Deperasińska, M. Chotkowski, Marzena Banasiewicz, Artur Makarewicz, Bolesław Kozankiewicz, Daniel T. Gryko
Chemical Communications 52 (2016) 5108-5111.


96. Dipolar Dyes with a Pyrrolo[2,3-b]quinoxaline Skeleton Containing a Cyano Group and a Bridged Tertiary Amino Group: Synthesis, Solvatofluorochromism and Bioimaging
L.G. Lukasiewicz, Irena Deperasińska, Y.M. Poronik, Y. Woong Jun, Marzena Banasiewicz, Bolesław Kozankiewicz,K. Han Ahn, Daniel T. Gryko
Chemistry An Asian Journal 11 (2016) 1718-1724.


95. Double head-to-tail direct arylation as a viable strategy towards the synthesis of the aza-analog of dihydrocyclopenta[hi]aceanthrylene - an intriguing antiaromatic heterocycle
D. Firmansyah, Irena Deperasińska, O. Vakuliuk, Marzena Banasiewicz, M. Tasior, Artur Makarewicz, Michał K. Cyrański, Bolesław Kozankiewicz and Daniel T. Gryko
Chemical Communication 52 (2016) 1262-1265.


94. Solvatofluorochromic, non-centrosymmetric π-expanded diketopyrrolopyrrole
M. Grzybowski, A. Jeżewski, Irena Deperasińska, D.H. Friese, Marzena Banasiewicz, V. Hugues, Bolesław Kozankiewicz, M. Blanchard-Desce and Daniel T. Gryko
Organic & Biomolecular Chemistry 14 (2016) 2025-2033.


93. Photophysics of Derivatives of 3-Hydroxybenzo[c]coumarin
Irena Deperasińska, Artur Makarewicz, M. Krzeszewski, Daniel T. Gryko, Bolesław Kozankiewicz
J. Phys. Chem. A 119 (2015) 9051-9058.


92. Why vertically π-expanded imidazo[1,2-a]pyridines are weak fluorescence emitters: experimental and computational study
Marzena Banasiewicz, Irena Deperasińska, Artur Makarewicz, D. Firmansyah, Daniel T. Gryko, Bolesław Kozankiewicz
Phys. Chem. Chem. Phys. 17 (2015) 8945-8950.


91. Electron Energy Loss of Terrylene Deposited on Au(111): Vibrational and Electronic Spectroscopy
P. Navarro, F.C. Bocquet, Irena Deperasińska, G. Pirug, F. S. Tautz, M. Orrit
J. Phys. Chem. C 119 (2015) 277-283.


90. Vertically π-Expanded Imidazo[1,2-a]pyridine – Missing Link of the Puzzle
Dikhi Firmansyah, Marzena Banasiewicz, Irena Deperasińska, Artur Makarewicz, Bolesław Kozankiewicz, Daniel T. Gryko
Chemistry - An Asian Journal 9 (2014) 2483-2493.


89. Vertically π-Expanded Coumarin – the Synthesis via the Scholl Reaction and Photophysical Properties,
Mariusz Tasior, Irena Deperasińska, Karolina Morawska, Marzena Banasiewicz, Olena Vakuliuk, Bolesław Kozankiewicz, Daniel T. Gryko
Phys. Chem. Chem. Phys. 16 (2014) 18268-18275.


88. Ultrafast excited state dynamics of trans-[4-(4'-dimethylaminostyryl)] pyridine N-oxide in solution: femtosecond fluorescence up-conversion and theoretical calculations
Szemik-Hojniak A., Deperasińska I., Oberda K., Erez Y., Huppert D., Nizhnik Y.P
Phys. Chem. Chem. Phys. 15 (2013) 9914-9923.


87. A novel complex of zinc tetraphenylporphyrin with two dioxane molecules in a rare attachment. Crystal structure, spectroscopy and theoretical calculations
Oberda K., Deperasińska I., Nizhnik Y.P., Szemik-Hojniak A.
Polyhedron 51 (2013) 61-69.


86. Spin-lattice relaxation and anomalous intersystem crossing in single molecule of terrylene embedded in p-perphenyl crystal
Magda Białkowska, Artur Makarewicz, Marzena Banasiewicz, Bolesław Kozankiewicz
Chem. Phys. Letters 555 (2013) 131-134.


85. Low Temperature Spectra of the Analogues of 10-Hydroxybenzo[h]quinoline as Indication of Barrierless ESIPT.
Irena Deperasińska, Daniel T. Gryko, Elena Karpiuk, Bolesław Kozankiewicz, Artur Makarewicz, and Joanna Piechowska
J. Phys. Chem. A 116 (2012) 12049-12055.


84. 12-Hydroxy-1-azaperylene-Limiting Case of the ESIPT System: Enol-Keto Tautomerization in S0 and S1 States.
Irena Deperasińska, Daniel T. Gryko, Elena Karpiuk, Bolesław Kozankiewicz, Artur Makarewicz, Joanna Piechowska
J. Phys. Chem. A 116 (2012) 2109-2116.


83. Vibronic spectra of single dibenzoterrylene molecules in anthracene and 2,3-dimethylanthracene crystals
Artur Makarewicz, Irena Deperasińska, Jacek Nowacki, Bolesław Kozankiewicz,
Chem. Phys. Letters 535 (2012) 140-145.


82. The impact of solvent polarity on intramolecular proton and electron transfer in 2-alkylamino-4-nitro-5-methyl pyridine N-oxides
A. Szemik-Hojniak, L. Wiśniewski, Irena Deperasińska, Artur Makarewicz, L. Jerzykiewicz, A. Puszko, Y. Erez, D. Huppert,
Phys. Chem. Chem. Phys. 14 (2012) 8147-8159.


81. Photoinduced electron transfer in penacoordinated complex of zinc teraphenylporphyrin and isoquinoline N-oxide. Crystal structure, spectroscopy and DFT studies
K. Oberda, Irena Deperasińska, Y. P. Nizhnik, L. Jerzykiewicz, A. Szemik-Hojniak,
Polyhedron 30 (2011) 2391-2399.


80. Effect of solvent polarity on photophysical parameters of 3 -aminoflavone
Ł. Wiśniewski, Irena Deperasińska, B. śurowska, A. Szemik-Hojniak A.
Photochem. Photobiol. A 224 (2011) 62-67.


79. Synthesis, photophysics and excited state structure of 1,8-di (p-tolyl)-1,3,5,7-octatetrayne
Irena Deperasińska, A. Szemik-Hojniak, K. Osowska, Michał F. Rode, Agnieszka Szczepanik, Ł. Wiśniewski, T. Lis, S. Szafert,
Photochem. Photobiol. A 217 (2011) 62299-307.


78. On Photo-Oxidation of Single Molecules
Bolesław Kozankiewicz, Irena Deperasińska, Elena Karpiuk, Marzena Banasiewicz, Artur Makarewicz,
Optical Materials 33 (2011) 1391.


77. Single dibenzoterrylene molecules in naphthalene and 2,3-dimethylnaphthalene crystals: vibronic spectra
Irena Deperasińska, Elena Karpiuk, Marzena Banasiewicz, Artur Makarewicz, Bolesław Kozankiewicz
Phys. Chem. Chem. Phys. 13 (2011) 1872.


76. Photophysical Properties of Dipeptides Containing Substituted 3-(Quinoxalin-6-yl) Alanine. Spectroscopic Studies and Theoretical Calculations
Ł. Wiśniewski, Irena Deperasińska, A. Staszewska, P. Stefanowicza, S. Berski, P. Lipkowski, Z. Szewczuka, A. Szemik- Hojniak,
J. Phys. Chem. A 114 (2010) 9405.


75. Excited State Processes of 2- Butylamino-6-methyl-4-nitropyridine N-oxide in Nonpolar Solvents. A Transient Absorption Spectroscopy Study
J. De Klerk, I.H. Van Stokkum, A. Szemik-Hojniak, Irena Deperasińska, C. Gooijer, H. Zhang, W.J. Buma, F. Ariese,
J. Phys. Chem. A 114 (2010) 4045.


74. On the photo-stability of single molecules. Dibenzoterrylene in 2,3-dimethylnaphthalene crystals
Irena Deperasińska, Elena Karpiuk, marzena Banasiewicz, Bolesław Kozankiewicz
Chem. Phys. Letters 492 (2010) 93.


73. Excited-State Forms of 2-Methylamino-6-methyl-4-nitropyridine N-Oxide and 2-Butylamino-6-methyl-4-nitropyridine N-Oxide
Artur Makarewicz, A. Szemik-Hojniak, G. Van der Zwan, Irena Deperasińska,
J. Phys. Chem. A 113 (2009) 3438.


72. Excited-State Forms of 2-Methylamino-6-methyl-4-nitropyridine N-Oxide and 2-Butylamino-6-methyl-4-nitropyridine N-Oxide
Artur Makarewicz, A. Szemik-Hojniak, G. Van der Zwan, Irena Deperasińska,
J. Phys. Chem. A 113 (2009) 3438.


71. Crystal structure, spectroscopic, and theoretical studies of 2-methylamino-6-methyl-4 nitropyridine N-oxide
Ł. Wiśniewski, A. Urbanowicz, L. Jerzykiewicz, Artur Makarewicz, Irena Deperasińska, G. Van der Zwan, N. Haraszkiewicz, A. Puszko, A. Szemik-Hojniak
J. Mol. Struct. 920 (2009) 45.


70. X-ray Crystal Structure and Magnetic and Photophysical Properties of Novel Copper(II) N-Oxide Adduct [(4-MPyO)2(CuCl2)2(H2O)(C2H5OH)] (4-MPyO = 4-(4-Methoxystyryl)pyridine N-Oxide)
Y.P. Nizhnik, A. Szemik-Hojniak, Irena Deperasińska, L. Jerzykiewicz, M. Korabik, M. Hojniak, V.P. Andeev
Inorg. Chem. 47 (2008) 2103.


69. Fluorescence Studies of Terrylene in a Supersonic Jet: Indication of A Dark Electronic State Below the Allowed Transition
Irena Deperasińska, A. Zehnacker, F. Lahmani, J. Borowski, Jurek Sepioł,
J. Phys. Chem. A 111 (2007) 4252.


68. Theoretical Analysis of the Electronic Ground and Excited Franck-Condon State of 2-Alkylamino- (3,5, or 6) - Methyl-4-Nitropyridine N-oxides
Irena Deperasińska, Artur Makarewicz, A. Szemik-Hojniak
Acta Phys. Pol. A 112 (2007) S71.


67. Crystal Structure, Spectroscopic, and Theoretical Investigations of Excited-State Proton Transfer in the Doubly Hydrogen-Bonded Dimer of 2-Butylamino-6-methyl-4-nitropyridine N-Oxide
A. Szemik-Hojniak, Irena Deperasińska, L. Jerzykiewicz, P. Sobota, M. Hojniak, A. Puszko, N. Haraszkiewicz, G. Van der Zwan, P. Jacques,
J. Phys. Chem. A 110 (2006) 10690.


66. Femtosecond Studies of Charge-Transfer Mediated Proton Transfer in 2-Butylamino-6-methyl-4-nitropyridine N-Oxide
B. Poór, N. Michniewicz, M. Kallay, W.J. Buma, M. Kubinyi, A. Szemik-Hojniak, Irena Deperasińska, A. Puszko, H. Zhang
J. Phys. Chem. A 110 (2006) 7086-7091.


65. The asymmetric nature of charge transfer states of the cyano-substituted proton sponge
A. Szemik-Hojniak, Irena Deperasińska, W.J. Buma, G. Balkowski, A. F. Pozharskii, N. V. Vistorobskii, X. Allonas,
Chem. Phys. Lett. 401 (2005) 189.


64. Two Excited State Structures of Donor-Acceptor Substituted "Proton Sponge"
A. Szemik-Hojniak, Irena Deperasińska, W.J. Buma, G. Balkowski, A. F. Pozharskii, N. V. Vistorobskii,
Key Engineering Materials 277–279 (2005) 1060–0.


63. Fluorescence Spectra of Phenanthridine Isolated in the Supersonic Jet Expansion - An Ab Initio Analysis
Irena Deperasińska, Jerzy Prochorow, Y. Stepanenko,
Acta Phys. Pol. A 108 (2005) 1005.


62. Fluorescence excitation and fluorescence spectra of jet-cooled phenanthridine and 7,8-benzoquinoline
Jerzy Prochorow, Irena Deperasińska, Y. Stepanenko,
Chem. Phys. Lett. 399 (2004) 239.


61. Fluorescence Spectra of 7,8-Benzoquinoline Isolated in the Supersonic Jet Expansion - An Ab Initio Analysis
Irena Deperasińska, Jerzy Prochorow, Y. Stepanenko,
Acta Phys. Pol. A 106 (2004) 535.


60. Molecular Crystals of Nitraminopyridine N-oxides
A. Szemik-Hojniak, T. Głowiak, Irena Deperasińska, A. Puszko, Z. Talik,
Non-Linear Optics, Quantum Optics 30 (2003) 215.


59. Spectroscopy and Photophysics of Monoazaphenanthrenes II. Ab initio Analysis of Molecular Parameters and Electronic Spectra
Irena Deperasińska, Jerzy Prochorow,
Acta Phys. Pol. A 104 (2003) 601.


58. Spectroscopic characteristics of pentacene In Shpol'skii matrixes
Marzena Banasiewicz, Irena Deperasińska, Bolesław Kozankiewicz
J. Phys. Chem. A 107 (2003) 662.


57. II.Semiempirical studies of naphthalene-tricyanoethylene exciplex
Irena Deperasińska, Jerzy Prochorow
Acta Physica Polonica A 102 (2000) 811.


56. Photoinduced charge-transfer reactions of tricyanoethylene with aromatic hydrocarbon electron donors. I.Emission studies of naphthalene-tricyanoethylene exciplex
J. Dresner, K. Kwapisz, Irena Deperasińska, Jerzy Prochorow, P. Bruni, A. Giardina, G. Tosi,
Acta Physica Polonica A 102 (2002) 443-468.


55. Crystal structure and spectral considerations of 5-methyl-2-nitroaminopyridine N-oxide
A. Szemik-Hojniak, T. Glowiak, Irena Deperasińska, A. Puszko,
Canadian Journal of Chemistry 80 (2002) 1242.


54. Anomalous fluorescence of terrylene in neon matrix
Irena Deperasińska, Bolesław Kozankiewicz, I. Biktchantaev, Jerzy Sepiol,
J. Phys. Chem. A 105 (2001) 810.


53. Structural and spectral analysis of 3- and 4-methylated nitraminopyridine N-oxides
A. Szemik-Hojniak, T. Glowiak, Irena Deperasińska, A. Puszko,
J. Mol. Structure 597 (2001) 279.


52. The forbidden emission of protonated proton sponge
A. Szemik-Hojniak, W. Rettig, Irena Deperasińska,
Chemical Physics Letters 343 (2001) 404.


51. Laser-induced emission spectroscopy of acridine cooled in a supersonic jet: the role of dimers and hydrogen-bonding in photophysics of acridine
Jerzy Prochorow, Irena Deperasińska, Olaf Morawski,
J. Mol. Struct. 555 (2000) 97.


50. Normal mode analysis of vibrations of jet-cooled acridine dimer
Irena Deperasińska, Jerzy Prochorow,
Acta Physica Polonica A 97 (2000) 285.


49. Inversion of states in two conformers of 1,8-bis(dimethylamino) naphthalene-the proton sponge
A. Szemik-Hojniak, Irena Deperasińska, X. Allonas, P. Jacques,
J. Mol. Structure 526 (2000) 219.


48. Relaxation of excited Franck-Condon states of molecular electron donor-acceptor complexes in liquid solution: the role of orientational isomers
Jerzy Prochorow, Irena Deperasińska,
J. Mol. Structure 450 (1998) 47.