Pure second order Stark effect: E.level = E.o + ( A.g + B.g M^2 ) mu.g^2 E^2 Mixed order: E.level = (E1+E2)/2 +- [ (DE/2)^2 + mu.g^2 E^2 |xi|^2 M^2 ]^(1/2) = E1-DE/2+[...]^(1/2) and E2+DE/2-[...]^(1/2) for E1>E2, DE=E1-E2 * E1,E2,DE should in general be inclusive of second order Stark contributions * Asterisk denotes levels implicated in near degeneracy for which A and B are evaluated without the connecting (|Phi.Zg|) term * Sum field contributions for more than one dipole component * Dipoles in D, energies in MHz, field in V/cm * In the .INT file set mu.g to 1 (only one at a time) and STRFLG=1 ------------------------------------------------------------------------ H2O...HF ------------------------------------------------------------------------ A.g B.g level g DE= 123.5200 |xi|= 2.517046E-01 1 1 0 <-> 1 1 1 1 -5.865001E-06 5.865001E-06 0 0 0 1 1 DE= 370.5600 |xi|= 8.390188E-02 2 1 1 <-> 2 1 2 1 DE= .0291 |xi|= 1.678036E-01 2 2 0 <-> 2 2 1 1 * -1.752535E-06 4.381338E-07 1 1 0 1 1 * -1.767634E-06 4.419086E-07 1 1 1 1 1 3.518901E-06 -5.278476E-06 1 0 1 1 1 DE= .0000 |xi|= 1.258529E-01 3 3 0 <-> 3 3 1 1 DE= .1457 |xi|= 8.390214E-02 3 2 1 <-> 3 2 2 1 * -8.388762E-07 9.320847E-08 2 2 0 1 1 * -8.388785E-07 9.320872E-08 2 2 1 1 1 * 4.171609E-07 -2.897589E-07 2 1 1 1 1 * 4.207541E-07 -2.922552E-07 2 1 2 1 1 8.377670E-07 -4.189325E-07 2 0 2 1 1 DE= .0000 |xi|= 7.551164E-02 4 3 1 <-> 4 3 2 1 DE= .4370 |xi|= 5.034110E-02 4 2 2 <-> 4 2 3 1 DE= .0000 |xi|= 1.006822E-01 4 4 1 <-> 4 4 0 1 * -4.900798E-07 3.062999E-08 3 3 0 1 1 * -4.900798E-07 3.062999E-08 3 3 1 1 1 * -9.479126E-11 -4.077278E-08 3 2 1 1 1 3.909241E-07 -9.775453E-08 3 0 3 1 1 2.945121E-07 -2.458507E-06 3 1 3 1 1 2.919971E-07 2.291462E-06 3 1 2 1 1 * -9.677752E-11 -4.077277E-08 3 2 2 1 1 DE= .0001 |xi|= 5.034112E-02 5 3 2 <-> 5 3 3 1 DE= .0000 |xi|= 8.390187E-02 5 5 0 <-> 5 5 1 1 DE= 1.0198 |xi|= 3.356075E-02 5 2 3 <-> 5 2 4 1 DE= .0000 |xi|= 6.712149E-02 5 4 1 <-> 5 4 2 1 ------------------------------------------------------------------------ ------------------------------------------------------------------------