CH2CL2: 37Cl 37Cl Tue Jun 11 16:29:58 2024 -------------------------------------------------------------------------------------========= obs o-c error blends Notes o-c wt / instead of : below denotes (o-c)>3*err -------------------------------------------------------------------------------------========= ! ! waveguide FTMW ! 1: 1 1 1 3 4 2 0 2 3 5 16499.2705 0.0021 0.010 2: 1 1 1 3 2 2 0 2 1 3 16501.2955 -0.0003 0.010 3: 1 1 1 1 2 2 0 2 1 3 16502.0065 -0.0041 0.010 4: 1 1 1 3 3 2 0 2 1 3 16502.2207 -0.0032 0.010 5: 1 1 1 2 3 2 0 2 2 3 16504.1311 -0.0016 0.010 -0.0002 0.14 6: 1 1 1 2 3 2 0 2 2 4 16504.1311 0.0042 0.010 -0.0002 0.54 7: 1 1 1 2 2 2 0 2 2 1 16504.1311 -0.0022 0.010 -0.0002 0.04 8: 1 1 1 2 2 2 0 2 2 3 16504.1311 -0.0075 0.010 -0.0002 0.28 9: 1 1 1 1 2 2 0 2 3 2 16504.3756 -0.0005 0.010 10: 1 1 1 3 4 2 0 2 3 4 16511.0672 0.0044 0.010 11: 1 1 1 1 0 2 0 2 1 1 16511.5261 -0.0034 0.010 12: 1 1 1 3 3 2 0 2 3 4 16511.6593 -0.0042 0.010 13: 1 1 1 2 2 2 0 2 2 2 16512.9688 0.0092 0.010 14: 1 1 1 0 1 2 0 2 2 2 16513.4519 0.0061 0.010 15: 1 1 1 1 2 2 0 2 3 3 16513.8160 -0.0018 0.010 ! 16: 2 1 2 3 2 3 0 3 3 2 10219.3597 0.0009 0.010 17: 2 1 2 3 3 3 0 3 3 3 10219.4640 -0.0043 0.010 18: 2 1 2 3 4 3 0 3 3 5 10223.0757 0.0015 0.010 19: 2 1 2 3 5 3 0 3 3 6 10223.2348 -0.0066 0.010 20: 2 1 2 1 1 3 0 3 1 2 10223.8365 0.0127 0.010 21: 2 1 2 2 2 3 0 3 2 3 10224.4396 -0.0067 0.010 22: 2 1 2 1 2 3 0 3 1 3 10224.6027 -0.0148 0.010 23: 2 1 2 1 3 3 0 3 1 4 10225.3080 -0.0107 0.010 24: 2 1 2 3 3 3 0 3 3 4 10225.3868 0.0132 0.010 ! 25: 6 0 6 3 3 5 1 5 3 2 9240.5115 -0.0005 0.010 26: 6 0 6 2 6 5 1 5 0 5 9241.8224 -0.0063 0.010 27: 6 0 6 1 6 5 1 5 1 5 9241.8226 0.0037 0.010 28: 6 0 6 3 9 5 1 5 3 8 9242.7581 0.0053 0.010 29: 6 0 6 3 5 5 1 5 3 4 9243.5305 -0.0006 0.010 30: 6 0 6 1 7 5 1 5 1 6 9244.2296 -0.0001 0.010 31: 6 0 6 2 8 5 1 5 2 7 9244.5689 0.0020 0.010 32: 6 0 6 1 5 5 1 5 1 4 9246.3193 -0.0078 0.010 0.0030 0.39 33: 6 0 6 3 8 5 1 5 3 7 9246.3193 0.0099 0.010 0.0030 0.61 34: 6 0 6 3 7 5 1 5 3 6 9247.9260 0.0000 0.010 35: 7 0 7 2 7 6 1 6 0 6 15922.2446 0.0014 0.010 0.0037 0.50 ! 36: 7 0 7 1 7 6 1 6 1 6 15922.2446 0.0060 0.010 0.0037 0.50 37: 7 0 7 3 10 6 1 6 3 9 15923.0485 0.0045 0.010 38: 7 0 7 3 9 6 1 6 3 8 15926.6441 0.0019 0.010 39: 7 0 7 1 6 6 1 6 1 5 15927.0935 0.0052 0.010 40: 7 0 7 3 7 6 1 6 3 6 15927.2591 -0.0025 0.010 41: 7 0 7 0 7 6 1 6 2 6 15927.9907 0.0008 0.010 42: 7 0 7 3 8 6 1 6 3 7 15928.5899 0.0021 0.010 ! 43: 10 2 9 3 11 11 1 10 3 12 12099.8905 -0.0030 0.010 44: 10 2 9 2 10 11 1 10 2 11 12100.2795 -0.0023 0.010 45: 10 2 9 3 10 11 1 10 3 11 12100.4785 -0.0034 0.010 46: 10 2 9 1 9 11 1 10 1 10 12100.7787 -0.0018 0.010 47: 10 2 9 3 12 11 1 10 3 13 12102.3497 -0.0058 0.010 48: 10 2 9 3 13 11 1 10 3 14 12105.6991 -0.0099 0.010 49: 10 2 9 1 10 11 1 10 1 11 12106.1363 -0.0066 0.010 -0.0064 0.50 50: 10 2 9 0 10 11 1 10 0 11 12106.1363 -0.0062 0.010 -0.0064 0.50 51: 10 2 9 3 7 11 1 10 3 8 12106.6516 -0.0004 0.010 ! 52: 13 2 11 1 13 14 1 14 1 14 15761.8611 -0.0025 0.010 -0.0025 0.50 53: 13 2 11 0 13 14 1 14 0 14 15761.8611 -0.0025 0.010 -0.0025 0.50 54: 13 2 11 2 13 14 1 14 2 14 15773.1638 0.0022 0.010 55: 13 2 11 3 14 14 1 14 3 15 15773.6468 0.0022 0.010 ! 56: 14 1 13 3 11 13 2 12 3 10 10341.1485 0.0013 0.010 57: 14 1 13 2 14 13 2 12 2 13 10341.5472 0.0087 0.010 0.0088 0.50 58: 14 1 13 1 14 13 2 12 1 13 10341.5472 0.0088 0.010 0.0088 0.50 59: 14 1 13 3 17 13 2 12 3 16 10341.8930 0.0096 0.010 60: 14 1 13 3 12 13 2 12 3 11 10343.8363 -0.0013 0.010 61: 14 1 13 3 13 13 2 12 3 12 10344.6047 -0.0003 0.010 -0.0025 0.46 62: 14 1 13 1 15 13 2 12 1 14 10344.6047 -0.0044 0.010 -0.0025 0.54 63: 14 1 13 3 16 13 2 12 3 15 10345.3907 0.0140 0.010 64: 14 1 13 1 13 13 2 12 1 12 10347.3927 0.0026 0.010 65: 14 1 13 3 14 13 2 12 3 13 10347.6827 0.0010 0.010 66: 14 1 13 3 15 13 2 12 3 14 10348.1580 0.0037 0.010 ! 67: 14 2 12 3 11 15 1 15 3 12 12136.9119 -0.0095 0.010 68: 14 2 12 0 14 15 1 15 0 15 12137.4341 -0.0012 0.010 -0.0012 0.50 69: 14 2 12 1 14 15 1 15 1 15 12137.4341 -0.0011 0.010 -0.0012 0.50 70: 14 2 12 3 17 15 1 15 3 18 12137.9146 0.0110 0.010 71: 14 2 12 3 12 15 1 15 3 13 12142.1377 -0.0075 0.010 72: 14 2 12 3 16 15 1 15 3 17 12144.1988 0.0084 0.010 73: 14 2 12 1 13 15 1 15 3 14 12148.4743 -0.0045 0.010 74: 14 2 12 3 14 15 1 15 3 15 12148.9013 0.0005 0.010 75: 14 2 12 3 15 15 1 15 3 16 12149.4972 0.0043 0.010 ! 76: 19 3 17 3 20 20 2 18 3 21 15631.2336 -0.0057 0.010 77: 19 3 17 3 18 20 2 18 3 19 15631.5149 -0.0085 0.010 78: 19 3 17 3 21 20 2 18 3 22 15632.7000 -0.0079 0.010 79: 19 3 17 3 17 20 2 18 3 18 15633.2818 -0.0024 0.010 80: 19 3 17 3 22 20 2 18 3 23 15634.4521 -0.0109 0.010 81: 19 3 17 1 19 20 2 18 1 20 15634.5859 -0.0104 0.010 -0.0104 0.50 82: 19 3 17 2 19 20 2 18 0 20 15634.5859 -0.0104 0.010 -0.0104 0.50 83: 19 3 17 3 16 20 2 18 3 17 15634.7286 -0.0138 0.010 84: 20 3 18 1 21 21 2 19 1 22 8262.5174 -0.0146 0.010 -0.0125 0.49 85: 20 3 18 2 22 21 2 19 2 23 8262.5174 -0.0103 0.010 -0.0125 0.51 ! 86: 22 3 19 1 22 23 2 22 1 23 9707.6870 -0.0075 0.010 -0.0076 0.50 87: 22 3 19 0 22 23 2 22 0 23 9707.6870 -0.0075 0.010 -0.0076 0.50 88: 22 3 19 3 20 23 2 22 3 21 9709.1307 0.0059 0.010 89: 22 3 19 3 24 23 2 22 3 25 9709.4304 -0.0075 0.010 90: 22 3 19 3 21 23 2 22 3 22 9710.7761 -0.0087 0.010 91: 22 3 19 2 22 23 2 22 2 23 9710.8714 -0.0045 0.010 0.0011 0.50 92: 22 3 19 3 22 23 2 22 3 23 9710.8714 0.0068 0.010 0.0011 0.50 93: 22 3 19 3 23 23 2 22 3 24 9710.9665 0.0069 0.010 ! 94: 27 2 26 3 28 26 3 23 3 27 9424.1529 0.0046 0.010 95: 27 2 26 0 27 26 1 25 2 26 9424.2411 0.0051 0.010 -0.0004 0.50 unstable labels 96: 27 2 26 3 27 26 3 23 3 26 9424.2411 -0.0060 0.010 -0.0004 0.50 97: 27 2 26 3 26 26 3 23 3 25 9424.3288 -0.0015 0.010 98: 27 2 26 3 29 26 3 23 3 28 9426.1455 -0.0003 0.010 99: 27 2 26 3 25 26 3 23 3 24 9426.5300 0.0002 0.010 100: 27 2 26 3 30 26 3 23 3 29 9428.3442 -0.0048 0.010 101: 27 2 26 1 27 26 3 23 1 26 9428.4397 0.0012 0.010 0.0012 0.50 102: 27 2 26 2 27 26 5 21 0 26 9428.4397 0.0012 0.010 0.0012 0.50 unstable labels 103: 27 2 26 3 24 26 3 23 3 23 9428.5343 0.0016 0.010 ! 104: 30 2 28 2 30 31 3 29 2 31 13084.1903 0.0005 0.010 0.0005 0.50 unstable labels 105: 30 4 26 1 30 31 3 29 1 31 13084.1903 0.0005 0.010 0.0005 0.50 106: 30 4 26 0 30 31 3 29 0 31 13084.8957 0.0039 0.010 0.0022 0.50 unstable labels 107: 30 4 26 3 30 31 3 29 3 31 13084.8957 0.0005 0.010 0.0022 0.50 ! 108: 33 3 30 1 33 32 4 29 1 32 8212.8561 0.0090 0.010 0.0090 0.50 109: 33 3 30 2 33 32 4 29 2 32 8212.8561 0.0090 0.010 0.0090 0.50 110: 33 3 30 3 33 32 4 29 3 32 8215.1296 0.0053 0.010 -0.0020 0.50 111: 33 3 30 0 33 32 4 29 0 32 8215.1296 -0.0092 0.010 -0.0020 0.50 ! 112: 35 3 33 0 35 34 4 30 2 34 10022.3975 -0.0037 0.010 113: 35 3 33 2 36 34 4 30 2 35 10022.9352 0.0081 0.010 0.0032 0.21 114: 35 3 33 2 37 34 4 30 2 36 10022.9352 -0.0029 0.010 0.0032 0.21 115: 35 3 33 2 34 34 4 30 2 33 10022.9352 0.0038 0.010 0.0032 0.20 116: 35 3 33 1 34 34 4 30 1 33 10022.9352 0.0041 0.010 0.0032 0.20 117: 35 3 33 2 33 34 4 30 2 32 10022.9352 0.0029 0.010 0.0032 0.19 118: 35 3 33 2 35 34 4 30 0 34 10023.4590 0.0011 0.010 ! 119: 36 5 32 0 36 35 4 31 2 35 15611.6952 -0.0053 0.010 -0.0055 0.50 unstable labels 120: 36 3 34 3 36 35 4 31 3 35 15611.6952 -0.0056 0.010 -0.0055 0.50 121: 36 3 34 1 35 35 4 31 1 34 15612.2915 0.0007 0.010 0.0007 0.50 122: 36 3 34 2 35 35 4 31 2 34 15612.2915 0.0006 0.010 0.0007 0.50 123: 36 3 34 1 36 35 4 31 1 35 15612.8852 0.0058 0.010 ! ! cavity FTMW ! 124: 2 1 2 3 3 3 0 3 1 4 10214.0664 -0.0015 0.002 125: 2 1 2 3 2 3 0 3 3 1 10214.3241 -0.0010 0.002 126: 2 1 2 2 3 3 0 3 0 3 10215.7114 -0.0012 0.002 127: 2 1 2 2 2 3 0 3 2 2 10215.8437 -0.0032 0.002 128: 2 1 2 3 4 3 0 3 1 4 10216.3263 0.0037 0.002 129: 2 1 2 0 2 3 0 3 2 2 10232.6715 -0.0007 0.002 130: 2 1 2 2 3 3 0 3 2 3 10232.8531 -0.0037 0.002 131: 2 1 2 3 5 3 0 3 3 5 10234.3102 0.0000 0.002 -------------------------------------------------------------------------------- PARAMETERS IN FIT (values truncated and Nlines statistics): 10000 A /MHz [31754.33417] 1 20000 B /MHz [3142.856079] 2 30000 C /MHz [2911.308339] 3 200 DJ /kHz [ 1.2615726] 4 1100 DJK /kHz [-24.864523] 5 2000 DK /kHz [465.91513] 6 40100 delJ /kHz [ 0.1536083] 7 41000 delK /kHz [ 4.93958] 8 300 HJ /Hz [ 0.00076522] 9 1200 HJK /Hz [ 0.010301] 10 2100 HKJ /Hz [-1.630399] 11 3000 HK /Hz [22.5842] 12 40200 hJ /Hz [ 0.00023736] 13 41100 hJK /Hz [ 0.003654] 14 42000 hK /Hz [ 1.38925] 15 400 LJ /mHz [ 0.] 16 1300 LJJK /mHz [-0.0000465] 17 2200 LJK /mHz [ 0.00241] 18 3100 LKKJ /mHz [ 0.1032] 19 4000 LK /mHz [-1.5196] 20 40300 lJ /mHz [ 0.] 21 41200 lJK /mHz [ 0.] 22 42100 lKJ /mHz [ 0.] 23 43000 lK /mHz [ 0.544] 24 5000 PK /mHz [ 0.] 25 110010000 chi.aa*3/2 /MHz -49.3488(51) 26 -220010000 chi.aa*3 /MHz -49.3488(51) = 1.00000 * 26 110040000 chi(b-c)/4 /MHz -7.5138(16) 27 -220040000 chi(b-c) /MHz -7.5138(16) = 1.00000 * 27 110610000 chi.ab /MHz [-40.5] 28 -220610000 chi.ab /MHz [40.5] = -1.00000 * 28 10030000 Mcc {+IMJ /MHz [ 0.001101] 29 -20030000 Mcc /MHz [ 0.001101] = 1.00000 * 29 MICROWAVE AVG = -0.000557 MHz, IR AVG = 0.00000 MICROWAVE RMS = 0.005753 MHz, IR RMS = 0.00000 END OF ITERATION 1 OLD, NEW RMS ERROR= 0.65764 0.65764 distinct frequency lines in fit: 105 distinct parameters of fit: 2 upper state lower state overall limits of quantum number 1: 1 36 2 35 1 36 limits of quantum number 2: 0 5 0 5 0 5 limits of quantum number 3: 1 34 2 31 1 34 limits of quantum number 4: 0 3 0 3 0 3 limits of quantum number 5: 0 37 1 36 0 37 frequency range: 8212 16513 PARAMETERS IN FIT WITH STANDARD ERRORS ON THOSE THAT ARE FITTED: (values rounded and degrees of freedom, Ndegf=Nlines-Nconst, statistics) 10000 A /MHz [31754.33417] 1 20000 B /MHz [3142.856079] 2 30000 C /MHz [2911.308339] 3 200 DJ /kHz [ 1.2615726] 4 1100 DJK /kHz [-24.864523] 5 2000 DK /kHz [465.91513] 6 40100 delJ /kHz [ 0.1536083] 7 41000 delK /kHz [ 4.93958] 8 300 HJ /Hz [ 0.00076522] 9 1200 HJK /Hz [ 0.010301] 10 2100 HKJ /Hz [-1.630399] 11 3000 HK /Hz [22.5842] 12 40200 hJ /Hz [ 0.00023736] 13 41100 hJK /Hz [ 0.003654] 14 42000 hK /Hz [ 1.38925] 15 400 LJ /mHz [ 0.] 16 1300 LJJK /mHz [-0.0000465] 17 2200 LJK /mHz [ 0.00241] 18 3100 LKKJ /mHz [ 0.1032] 19 4000 LK /mHz [-1.5196] 20 40300 lJ /mHz [ 0.] 21 41200 lJK /mHz [ 0.] 22 42100 lKJ /mHz [ 0.] 23 43000 lK /mHz [ 0.544] 24 5000 PK /mHz [ 0.] 25 110010000 chi.aa*3/2 /MHz -49.3488(34) 26 -220010000 chi.aa*3 /MHz -49.3488(34) = 1.00000 * 26 110040000 chi(b-c)/4 /MHz -7.5139(11) 27 -220040000 chi(b-c) /MHz -7.5139(11) = 1.00000 * 27 110610000 chi.ab /MHz [-40.5] 28 -220610000 chi.ab /MHz [40.5] = -1.00000 * 28 10030000 Mcc {+IMJ /MHz [ 0.001101] 29 -20030000 Mcc /MHz [ 0.001101] = 1.00000 * 29 CORRELATION COEFFICIENTS, C.ij: chi.aa*3 chi(b-c) chi.aa*3/2 1.0000 chi(b-c)/4 -0.3770 1.0000 Mean value of |C.ij|, i.ne.j = 0.3770 Mean value of C.ij, i.ne.j = -0.3770 No correlations with absolute value greater than 0.9950 Worst fitted lines (obs-calc/error): 128: 1.9 130: -1.9 127: -1.6 22: -1.5 63: 1.4 83: -1.4 24: 1.3 20: 1.3 84: -1.2 70: 1.1 80: -1.1 23: -1.1 81: -1.0 48: -1.0 59: 1.0 67: -0.9 13: 0.9 108: 0.9 57: 0.9 90: -0.9 77: -0.9 72: 0.8 78: -0.8 86: -0.8 71: -0.8 124: -0.8 89: -0.8 93: 0.7 21: -0.7 19: -0.7 49: -0.6 26: -0.6 14: 0.6 126: -0.6 88: 0.6 47: -0.6 123: 0.6 76: -0.6 119: -0.5 28: 0.5 39: 0.5 125: -0.5 100: -0.5 94: 0.5 37: 0.4 73: -0.4 10: 0.4 17: -0.4 75: 0.4 12: -0.4 128: 2 1 2 3 4 3 0 3 1 4 10216.3263 0.0037 0.002 130: 2 1 2 2 3 3 0 3 2 3 10232.8531 -0.0037 0.002 127: 2 1 2 2 2 3 0 3 2 2 10215.8437 -0.0032 0.002 22: 2 1 2 1 2 3 0 3 1 3 10224.6027 -0.0148 0.010 63: 14 1 13 3 16 13 2 12 3 15 10345.3907 0.0140 0.010 83: 19 3 17 3 16 20 2 18 3 17 15634.7286 -0.0138 0.010 24: 2 1 2 3 3 3 0 3 3 4 10225.3868 0.0132 0.010 20: 2 1 2 1 1 3 0 3 1 2 10223.8365 0.0127 0.010 84: 20 3 18 1 21 21 2 19 1 22 8262.5174 -0.0146 0.010 -0.0125 0.49 70: 14 2 12 3 17 15 1 15 3 18 12137.9146 0.0110 0.010 _____________________________________ __________________________________________/ SPFIT output reformatted with PIFORM