Fluorobenzene, v_6a=1 ----------------------+++++------------------------------------------------------------- number of transitions: 261 number of constants : 8 -----++++++++++++++++++++++++++++++----------------------------------------------------- 1 5663.8953375952905844315 A Reduction-A, Representation-I.r 1 2570.5065608444265308208 B 1 1766.8244700708603431849 C 1 0.0001332170942235704 DJ 1 0.0001814129373635940 DJK 1 0.0008478624995666680 DK 1 0.0000440544648646801 dJ 1 0.0003998379253967324 dK ---------------------------------------------------------------------------------------- J' K-1' K+1' J K-1 K+1 frequency error fit? blend Note +++++-----+++++-----+++++-----++++++++++++++++++++---------------+++++----------++++++++ ! ! M.Schafer, A.Bauder, Chem.Phys.Lett. 308(1999)355-362. ! 2 1 2 1 1 1 7870.984400 0.002000 1 2 0 2 1 0 1 8537.414600 0.002000 1 2 1 1 1 1 0 9478.339000 0.002000 1 ! 3 1 3 2 1 2 11726.934300 0.002000 1 3 0 3 2 0 2 12487.573300 0.002000 1 3 2 2 2 2 1 13011.981100 0.005000 1 3 2 1 2 2 0 13536.392400 0.002000 1 3 1 2 2 1 1 14123.051500 0.002000 1 ! ! MMW measurements at IFPAN ! ! type-II bandheads ! 47 0 47 46 0 46 167832.234000 0.050000 1 46 1 45 45 1 44 167839.563000 0.050000 1 45 2 43 44 2 42 167850.804000 0.050000 1 42 5 37 41 5 36 167972.126000 0.050000 1 blended 41 6 35 40 6 34 168088.482000 0.050000 2 1.00E+00 41 7 35 40 7 34 168088.482000 0.050000 2 1.00E+00 40 7 33 39 7 32 168300.843000 0.050000 1 40 8 33 39 8 32 168297.198000 0.050000 1 39 8 31 38 8 30 168737.441000 0.050000 1 37 11 27 36 11 26 168331.138000 0.050000 1 ! 48 0 48 47 0 47 171364.636332 0.050000 1 47 1 46 46 1 45 171371.888003 0.050000 1 46 2 44 45 2 43 171382.872322 0.050000 1 45 3 42 44 3 41 171402.033070 0.050000 1 43 5 38 42 5 37 171497.499306 0.050000 2 9.00E-06 43 6 38 42 6 37 171497.499306 0.050000 2 9.00E-06 42 7 36 41 7 35 171605.519266 0.050000 2 8.78E-06 42 6 36 41 6 35 171605.519266 0.050000 2 8.78E-06 41 7 34 40 7 33 171798.886905 0.050000 1 40 9 32 39 9 31 172133.154496 0.050000 1 40 8 32 39 8 31 172174.964014 0.050000 1 36 11 25 35 11 24 171837.471009 0.050000 1 38 11 28 37 11 27 172310.251931 0.050000 1 ! 49 0 49 48 0 48 174896.990232 0.050000 1 48 1 47 47 1 46 174904.170867 0.050000 1 47 2 45 46 2 44 174914.906446 0.050000 1 46 3 43 45 3 42 174933.325255 0.050000 1 45 4 41 44 4 40 174966.007103 0.050000 1 42 7 35 41 7 34 175301.372322 0.050000 1 42 8 35 41 8 34 175300.401434 0.050000 1 41 8 33 40 8 32 175631.854211 0.050000 1 40 10 31 39 10 30 176076.614733 0.050000 1 ! 46 7 40 45 7 39 185687.304321 0.050000 2 1.01E-05 46 6 40 45 6 39 185687.304321 0.050000 2 1.01E-05 ! 53 0 53 52 0 52 189025.799884 0.050000 1 52 1 51 51 1 50 189032.830652 0.050000 1 51 2 49 50 2 48 189042.689172 0.050000 1 50 3 47 49 3 46 189058.696922 0.050000 1 49 4 45 48 4 44 189085.964328 0.050000 1 48 5 43 47 5 42 189132.185426 0.050000 1 46 7 39 45 7 38 189340.216094 0.050000 2 1.02E-05 46 8 39 45 8 38 189340.216094 0.050000 2 1.02E-05 ! 54 0 54 53 0 53 192557.905000 0.050000 1 53 1 52 52 1 51 192564.818000 0.050000 1 52 2 50 51 2 49 192574.466000 0.050000 1 51 3 48 50 3 47 192590.095000 0.050000 1 50 4 46 49 4 45 192616.159000 0.050000 1 49 5 44 48 5 43 192660.194000 0.050000 1 48 6 42 47 6 41 192733.587000 0.050000 1 eye 47 7 40 46 7 39 192855.125000 0.050000 2 1.00E+00 47 8 40 46 8 39 192855.125000 0.050000 2 1.00E+00 45 9 36 44 9 35 193419.520000 0.050000 1 45 10 36 44 10 35 193401.992000 0.050000 1 44 10 34 43 10 33 194207.260000 0.050000 1 43 12 32 42 12 31 194214.488000 0.050000 1 42 13 30 41 13 29 192504.421000 0.050000 1 41 13 28 40 13 27 194075.553000 0.050000 1 ! 55 0 55 54 0 54 196089.906000 0.050000 1 54 1 53 53 1 52 196096.810000 0.050000 1 52 3 49 51 3 48 196121.416000 0.050000 1 51 4 47 50 4 46 196146.476000 0.050000 1 50 5 45 49 5 44 196188.434000 0.050000 1 49 6 43 48 6 42 196257.693000 0.050000 1 47 8 39 46 8 38 196560.310702 0.050000 1 47 9 39 46 9 38 196559.835702 0.050000 1 eye ! 59 0 59 58 0 58 210217.351388 0.050000 1 57 2 55 56 2 54 210233.149168 0.050000 1 55 4 51 54 4 50 210268.243490 0.050000 1 54 5 49 53 5 48 210303.223094 0.050000 1 53 6 47 52 6 46 210359.379232 0.050000 1 52 7 45 51 7 44 210448.979647 0.050000 1 ! 62 0 62 61 0 61 220812.221925 0.050000 1 58 4 54 57 4 53 220859.797362 0.050000 1 56 6 50 55 6 49 220939.572480 0.050000 1 54 8 46 53 8 45 221134.490801 0.050000 1 ! 63 0 63 62 0 62 224343.718658 0.050000 1 62 1 61 61 1 60 224350.465142 0.050000 1 59 4 55 58 4 54 224390.460125 0.050000 1 58 5 53 57 5 52 224420.238008 0.050000 1 57 6 51 56 6 50 224466.904511 0.050000 1 56 7 49 55 7 48 224539.445501 0.050000 1 55 8 47 54 8 46 224651.594499 0.050000 2 1.25E-05 55 9 47 54 9 46 224651.594499 0.050000 2 1.25E-05 54 9 45 53 9 44 224825.743304 0.050000 2 1.24E-05 54 10 45 53 10 44 224825.743304 0.050000 2 1.24E-05 ! 64 0 64 63 0 63 227875.114672 0.050000 1 63 1 62 62 1 61 227881.873362 0.050000 1 59 5 54 58 5 53 227949.693955 0.050000 1 58 6 52 57 6 51 227994.399560 0.050000 1 57 7 50 56 7 49 228063.362788 0.050000 1 56 8 48 55 8 47 228169.409709 0.050000 1 overlap 55 9 46 54 9 45 228332.778681 0.050000 2 1.25E-05 55 10 46 54 10 45 228332.778681 0.050000 2 1.25E-05 ! 53 11 42 52 11 41 229002.262920 0.050000 1 50 13 37 49 13 36 229227.523579 0.050000 1 52 13 40 51 13 39 229617.266335 0.050000 1 52 12 40 51 12 39 229782.848682 0.050000 1 ! 65 0 65 64 0 64 231406.515000 0.050000 1 64 1 63 63 1 62 231413.156000 0.050000 1 63 2 61 62 2 60 231421.581000 0.050000 1 60 5 55 59 5 54 231479.269308 0.050000 1 59 6 53 58 6 52 231522.038000 0.050000 1 58 7 51 57 7 50 231587.750000 0.050000 1 57 8 49 56 8 48 231688.397000 0.050000 1 56 9 47 55 9 46 231841.961000 0.050000 2 1.00E+00 56 10 47 55 10 46 231841.961000 0.050000 2 1.00E+00 54 11 43 53 11 42 232458.454000 0.050000 1 54 12 43 53 12 42 232452.870000 0.050000 1 53 12 41 52 12 40 233132.795000 0.050000 1 53 13 41 52 13 40 233039.417000 0.050000 1 52 13 39 51 13 38 234805.140000 0.050000 1 52 14 39 51 14 38 233750.753000 0.050000 1 ! 66 0 66 65 0 65 234937.780995 0.050000 1 65 1 64 64 1 63 234944.452210 0.050000 1 64 2 62 63 2 61 234952.717067 0.050000 1 59 7 52 58 7 51 235112.654181 0.050000 1 57 9 48 56 9 47 235352.845572 0.050000 2 1.28E-05 57 10 48 56 10 47 235352.845572 0.050000 2 1.28E-05 55 11 44 54 11 43 235923.492141 0.050000 1 ! 73 0 73 72 0 72 259654.738632 0.050000 1 72 1 71 71 1 70 259661.362865 0.050000 1 71 2 69 70 2 68 259669.090816 0.050000 1 70 3 67 69 3 66 259679.244278 0.050000 1 69 4 65 68 4 64 259694.028787 0.050000 1 63 10 53 62 10 52 260110.478687 0.050000 1 ! 79 0 79 78 0 78 280837.728000 0.050000 1 78 1 77 77 1 76 280844.280000 0.050000 1 77 2 75 76 2 74 280851.725000 0.050000 1 76 3 73 75 3 72 280861.167000 0.050000 1 75 4 71 74 4 70 280874.054000 0.050000 1 74 5 69 73 5 68 280892.388000 0.050000 1 73 6 67 72 6 66 280918.907692 0.050000 1 ! ! ! High K-1 tails ! 37 14 23 36 14 22 168043.473000 0.050000 1 ! 38 21 17 37 21 16 168586.711000 0.050000 1 38 22 16 37 22 15 168317.736000 0.050000 1 38 24 14 37 24 13 167882.214000 0.050000 1 38 25 13 37 25 12 167704.000000 0.050000 1 38 26 12 37 26 11 167546.614000 0.050000 1 ! 39 32 7 38 32 6 171351.752396 0.050000 1 39 31 8 38 31 7 171441.719199 0.050000 1 39 30 9 38 30 8 171540.762439 0.050000 1 39 29 10 38 29 9 171650.291322 0.050000 1 39 28 11 38 28 10 171771.624103 0.050000 1 39 25 14 38 25 13 172229.509902 0.050000 1 39 24 15 38 24 14 172422.573883 0.050000 1 39 17 23 38 17 22 175013.635397 0.050000 1 39 17 22 38 17 21 175014.268381 0.050000 1 39 16 24 38 16 23 175755.996556 0.050000 1 39 16 23 38 16 22 175764.665115 0.050000 1 ! 40 37 3 39 37 2 175441.316222 0.050000 1 40 36 4 39 36 3 175504.234048 0.050000 1 40 35 5 39 35 4 175572.378912 0.050000 1 40 34 6 39 34 5 175646.509089 0.050000 1 40 30 10 39 30 9 176019.655048 0.050000 1 ! 41 12 29 40 12 28 196169.123000 0.050000 1 41 14 27 40 14 26 189493.222103 0.050000 1 ! 42 11 31 41 11 30 194115.492000 0.050000 1 42 14 29 41 14 28 192631.551000 0.050000 1 42 14 28 41 14 27 195429.218000 0.050000 1 42 15 27 41 15 26 192177.629846 0.050000 1 42 17 25 41 17 24 189471.442222 0.050000 1 ! 43 33 10 42 33 9 189130.599453 0.050000 1 43 32 11 42 32 10 189240.501169 0.050000 1 43 31 12 42 31 11 189361.212964 0.050000 1 43 30 13 42 30 12 189494.397577 0.050000 1 43 20 24 42 20 23 192215.089704 0.050000 2 7.43E-06 43 20 23 42 20 22 192215.089704 0.050000 2 7.43E-06 43 18 26 42 18 25 193479.701000 0.050000 1 43 18 25 42 18 24 193481.266000 0.050000 1 43 17 27 42 17 26 194345.037000 0.050000 1 43 17 26 42 17 25 194362.069000 0.050000 1 43 16 28 42 16 27 195425.203000 0.050000 1 43 16 27 42 16 26 195570.996000 0.050000 1 ! 44 38 6 43 38 5 193151.794734 0.050000 1 44 37 7 43 37 6 193228.998776 0.050000 1 44 36 8 43 36 7 193312.372786 0.050000 1 44 35 9 43 35 8 193402.995973 0.050000 1 44 34 10 43 34 9 193501.524141 0.050000 1 44 33 11 43 33 10 193609.161000 0.050000 1 44 31 13 43 31 12 193856.471000 0.050000 1 44 29 15 43 29 14 194157.298711 0.050000 1 44 25 19 43 25 18 194999.053000 0.050000 1 44 24 20 43 24 19 195281.932000 0.050000 1 44 23 21 43 23 20 195605.896000 0.050000 1 44 22 22 43 22 21 195980.121000 0.050000 1 44 21 24 43 21 23 196416.943000 0.050000 2 1.00E+00 44 21 23 43 21 22 196416.943000 0.050000 2 1.00E+00 44 11 34 43 11 33 193931.248574 0.050000 1 ! 47 21 27 46 21 26 210560.977647 0.050000 2 8.55E-06 47 21 26 46 21 25 210560.977647 0.050000 2 8.55E-06 ! 48 15 33 47 15 32 228093.357120 0.050000 1 48 14 34 47 14 33 229786.213891 0.050000 1 48 13 35 47 13 34 224239.580341 0.050000 1 ! 49 20 30 48 20 29 220866.324416 0.050000 1 49 20 29 48 20 28 220867.813205 0.050000 1 49 17 33 48 17 32 224349.599783 0.050000 1 49 15 34 48 15 33 234147.982732 0.050000 1 49 14 35 48 14 34 233587.663333 0.050000 1 ! 50 31 19 49 31 18 220969.515278 0.050000 1 50 22 29 49 22 28 224199.101570 0.050000 2 9.15E-06 50 22 28 49 22 27 224199.101570 0.050000 2 9.15E-06 50 21 30 49 21 29 224893.240712 0.050000 2 9.60E-06 50 21 29 49 21 28 224893.240712 0.050000 2 9.60E-06 50 18 32 49 18 31 228262.303506 0.050000 1 50 17 34 49 17 33 229410.356152 0.050000 1 50 17 33 49 17 32 230755.345563 0.050000 1 50 15 36 49 15 35 229435.500894 0.050000 1 ! 51 38 13 50 38 12 224410.921762 0.050000 1 51 34 17 50 34 16 224956.294849 0.050000 1 51 24 27 50 24 26 227803.846612 0.050000 1 51 23 29 50 23 28 228339.764963 0.050000 2 9.00E-06 51 23 28 50 23 27 228339.764963 0.050000 2 9.00E-06 51 21 31 50 21 30 229718.589773 0.050000 1 51 21 30 50 21 29 229718.962564 0.050000 1 51 20 32 50 20 31 230629.802875 0.050000 1 51 20 31 50 20 30 230636.246044 0.050000 1 51 19 32 50 19 31 231812.734526 0.050000 1 51 18 33 50 18 32 233517.648000 0.050000 1 51 18 34 50 18 33 233109.478000 0.050000 1 51 17 35 50 17 34 234439.825529 0.050000 1 51 16 36 50 16 35 234898.010606 0.050000 1 51 14 38 50 14 37 230246.049000 0.050000 1 52 37 15 51 37 14 229022.258784 0.050000 1 52 36 16 51 36 15 229160.174624 0.050000 1 52 35 17 51 35 16 229310.157637 0.050000 1 52 34 18 51 34 17 229473.724653 0.050000 1 52 32 20 51 32 19 229849.222295 0.050000 1 52 31 21 51 31 20 230065.827657 0.050000 1 52 23 30 51 23 29 233083.288583 0.050000 1 52 22 30 51 22 29 233760.216000 0.050000 2 1.00E+00 52 22 31 51 22 30 233760.216000 0.050000 2 1.00E+00 52 21 32 51 21 31 234570.625226 0.050000 1 52 21 31 51 21 30 234572.087254 0.050000 1 52 20 33 51 20 32 235560.302667 0.050000 1 52 20 32 51 20 31 235573.641464 0.050000 1 ! 53 38 15 52 38 14 233384.311000 0.050000 1 53 37 16 52 37 15 233519.009000 0.050000 1 53 36 17 52 36 16 233665.143000 0.050000 1 53 35 18 52 35 17 233823.964252 0.050000 1 53 34 19 52 34 18 233997.500804 0.050000 1 53 33 20 52 33 19 234187.414386 0.050000 1 53 32 21 52 32 20 234395.947590 0.050000 1 ! 54 16 38 53 16 37 259043.889455 0.050000 1 ! 56 15 41 55 15 40 259244.891365 0.050000 1 ! 57 16 42 56 16 41 259141.041237 0.050000 1 57 21 36 56 21 35 259350.891641 0.050000 1 ! 60 19 41 59 19 40 283236.147872 0.050000 1 ! 62 22 41 61 22 40 283252.916428 0.050000 1 62 22 40 61 22 39 283399.558414 0.050000 1 ! 64 38 26 63 38 25 283128.285455 0.050000 1 64 37 27 63 37 26 283369.224034 0.050000 1 64 36 28 63 36 27 283631.550216 0.050000 1 64 16 49 63 16 48 283099.546184 0.050000 1 +++++-----+++++-----+++++-----++++++++++++++++++++---------------+++++----------++++++++ ----------------------------------------------------------------------------------------