benzaldehyde, v=1 ----------------------+++++------------------------------------------------------------- number of transitions: 266 number of constants : 8 -----++++++++++++++++++++++++++++++----------------------------------------------------- 1 5213.1696909218835571664 A Reduction-A, Representation-I.r 1 1564.9302887233952787938 B 1 1206.4943183667196535680 C 1 0.0000698717491001873 DJ 1 0.0001594618953302072 DJK 1 0.0006489841666389842 DK 1 0.0000181813909384731 dJ 1 0.0002757294884877511 dK ---------------------------------------------------------------------------------------- J' K-1' K+1' J K-1 K+1 frequency error fit? blend Note +++++-----+++++-----+++++-----++++++++++++++++++++---------------+++++----------++++++++ ! ! Data from R.K.Kakar, E.A.Reinhart, C.R.Quade, T.Kojima, J.Chem.Phys. ! 52,3803-3813(1970) ! ! Table I = Oklahoma spectrometer ! 7 6 1 6 6 0 19470.200000 0.200000 2 1.0000 7 6 2 6 6 1 19470.200000 0.200000 2 1.0000 7 5 2 6 5 1 19489.300000 0.200000 2 1.0000 7 5 3 6 5 2 19489.300000 0.200000 2 1.0000 7 4 3 6 4 2 19528.300000 0.200000 1 7 4 4 6 4 3 19523.300000 0.200000 1 7 3 4 6 3 3 19679.100000 0.200000 1 7 3 5 6 3 4 19545.200000 0.200000 1 7 2 5 6 2 4 20326.990000 0.200000 1 7 2 6 6 2 5 19206.400000 0.200000 1 7 1 6 6 1 5 20254.200000 0.200000 1 7 1 7 6 1 6 17878.100000 0.200000 0 7 0 7 6 0 6 18274.300000 0.200000 1 8 7 1 7 7 0 22249.600000 0.200000 2 1.0000 8 7 1 7 7 0 22249.600000 0.200000 2 1.0000 8 6 2 7 6 1 22266.300000 0.200000 2 1.0000 8 6 3 7 6 2 22266.300000 0.200000 2 1.0000 8 5 3 7 5 2 22294.600000 0.200000 2 1.0000 8 5 4 7 5 3 22294.600000 0.200000 2 1.0000 8 4 4 7 4 3 22355.500000 0.200000 1 8 4 5 7 4 4 22342.500000 0.200000 1 8 3 5 7 3 4 22608.400000 0.200000 1 8 3 6 7 3 5 22350.600000 0.200000 1 8 2 6 7 2 5 23367.300000 0.200000 1 8 2 7 7 2 6 21869.200000 0.200000 1 8 1 7 7 1 6 22966.300000 0.200000 1 8 1 8 7 1 7 20356.800000 0.200000 1 8 0 8 7 0 7 20660.200000 0.200000 1 9 8 1 8 8 0 25028.800000 0.200000 2 1.0000 9 8 2 8 8 1 25028.800000 0.200000 2 1.0000 9 7 2 8 7 1 25044.000000 0.200000 2 1.0000 9 7 3 8 7 2 25044.000000 0.200000 2 1.0000 9 6 3 8 6 2 25067.800000 0.200000 2 1.0000 9 6 4 8 6 3 25067.800000 0.200000 2 1.0000 9 5 4 8 5 3 25108.300000 0.200000 2 1.0000 9 5 5 8 5 4 25108.300000 0.200000 2 1.0000 9 4 5 8 4 4 25202.400000 0.200000 1 9 4 6 8 4 5 25171.000000 0.200000 1 9 3 6 8 3 5 25596.000000 0.200000 0 9 3 7 8 3 6 25147.600000 0.200000 1 9 2 7 8 2 6 26377.800000 0.200000 1 9 2 8 8 2 7 24502.300000 0.200000 1 9 1 8 8 1 7 25593.900000 0.200000 1 9 1 9 8 1 8 22817.800000 0.200000 1 9 0 9 8 0 8 23036.400000 0.200000 1 ! ! Table I = Wyoming spectrometer ! 10 9 1 9 9 0 27808.020000 0.100000 2 1.0000 10 9 2 9 9 1 27808.020000 0.100000 2 1.0000 10 8 2 9 8 1 27822.330000 0.100000 2 1.0000 10 8 3 9 8 2 27822.330000 0.100000 2 1.0000 10 7 3 9 7 2 27843.250000 0.100000 2 1.0000 10 7 4 9 7 3 27843.250000 0.100000 2 1.0000 10 6 4 9 6 3 27875.930000 0.100000 2 1.0000 10 6 5 9 6 4 27875.930000 0.100000 2 1.0000 10 5 5 9 5 4 27932.860000 0.100000 1 10 5 6 9 5 5 27930.650000 0.100000 0 10 4 6 9 4 5 28073.270000 0.100000 0 10 4 7 9 4 6 28008.210000 0.100000 1 10 3 7 9 3 6 0.000000 0.100000 0 10 3 8 9 3 7 27930.650000 0.100000 0 10 2 8 9 2 7 29337.740000 0.100000 1 10 2 9 9 2 8 27104.830000 0.100000 1 10 1 9 9 1 8 28131.900000 0.100000 0 11 10 1 10 10 0 30587.230000 0.100000 0 1.0000 11 10 2 10 10 1 30587.200000 0.100000 0 1.0000 11 9 2 10 9 1 30601.350000 0.100000 0 1.0000 11 9 3 10 9 2 30601.350000 0.100000 0 1.0000 11 8 3 10 8 2 30620.440000 0.100000 0 1.0000 11 8 4 10 8 3 30620.440000 0.100000 0 1.0000 11 7 4 10 7 3 30647.900000 0.100000 2 1.0000 11 7 5 10 7 4 30647.900000 0.100000 2 1.0000 11 6 5 10 6 4 30691.670000 0.100000 2 1.0000 11 6 6 10 6 5 30691.670000 0.100000 2 1.0000 11 5 6 10 5 5 30769.480000 0.100000 1 11 5 7 10 5 6 30763.150000 0.100000 0 11 4 7 10 4 6 30977.690000 0.100000 1 11 4 8 10 4 7 30850.740000 0.100000 1 11 3 8 10 3 7 31744.170000 0.100000 0 11 3 9 10 3 8 30692.800000 0.100000 1 11 2 9 10 2 8 32232.760000 0.100000 1 11 2 10 10 2 9 29676.230000 0.100000 1 11 1 10 10 1 9 30586.570000 0.100000 0 11 1 11 10 1 10 27701.680000 0.100000 1 11 0 11 10 0 10 27801.680000 0.100000 1 12 6 6 11 6 5 33515.000000 0.100000 2 1.0000 12 6 7 11 6 6 33515.000000 0.100000 2 1.0000 12 5 7 11 5 6 33620.150000 0.100000 1 12 5 8 11 5 7 33605.700000 0.100000 1 12 4 8 11 4 7 33924.550000 0.100000 1 12 4 9 11 4 8 33695.750000 0.100000 0 12 3 9 11 3 8 34869.480000 0.100000 1 12 3 10 11 3 9 33429.600000 0.100000 1 12 2 10 11 2 9 35049.710000 0.100000 1 12 2 11 11 2 10 32217.770000 0.100000 1 12 1 11 11 1 10 32977.170000 0.100000 1 12 1 12 11 1 11 30130.480000 0.100000 1 12 0 12 11 0 11 30195.110000 0.100000 1 13 12 1 12 12 0 36146.280000 0.100000 2 1.0000 13 12 2 12 12 1 36146.280000 0.100000 2 1.0000 13 11 2 12 11 1 36158.840000 0.100000 2 1.0000 13 11 3 12 11 2 36158.840000 0.100000 2 1.0000 13 10 3 12 10 2 36175.060000 0.100000 2 1.0000 13 10 4 12 10 3 36175.060000 0.100000 2 1.0000 13 9 4 12 9 3 36197.130000 0.100000 0 1.0000 13 9 5 12 9 4 36197.130000 0.100000 0 1.0000 13 8 5 12 8 4 36228.900000 0.100000 2 1.0000 13 8 6 12 8 5 36228.900000 0.100000 2 1.0000 13 7 6 12 7 5 36274.880000 0.100000 2 1.0000 13 7 7 12 7 6 36274.880000 0.100000 2 1.0000 13 6 7 12 6 6 36347.500000 0.100000 0 1.0000 13 6 8 12 6 7 36347.500000 0.100000 0 1.0000 13 5 8 12 5 7 36488.700000 0.100000 1 13 5 9 12 5 8 36458.650000 0.100000 1 13 4 9 12 4 8 36923.440000 0.100000 1 13 4 10 12 4 9 36536.950000 0.100000 0 13 3 10 12 3 9 37988.950000 0.100000 1 13 3 11 12 3 10 36136.680000 0.100000 1 13 2 11 12 2 10 37777.600000 0.100000 1 13 2 12 12 2 11 34731.910000 0.100000 1 13 1 12 12 1 11 35330.280000 0.100000 1 13 1 13 12 1 12 32553.500000 0.100000 1 13 0 13 12 0 12 32594.630000 0.100000 1 14 13 1 13 13 0 38925.680000 0.100000 2 1.0000 14 13 2 13 13 1 38925.680000 0.100000 2 1.0000 14 12 2 13 12 1 38937.900000 0.100000 2 1.0000 14 12 3 13 12 2 38937.900000 0.100000 2 1.0000 14 11 3 13 11 2 38953.350000 0.100000 2 1.0000 14 11 4 13 11 3 38953.350000 0.100000 2 1.0000 14 10 4 13 10 3 38973.830000 0.100000 2 1.0000 14 10 5 13 10 4 38973.830000 0.100000 2 1.0000 14 9 5 13 9 4 39001.690000 0.100000 2 1.0000 14 9 6 13 9 5 39001.690000 0.100000 2 1.0000 14 8 6 13 8 5 39040.930000 0.100000 2 1.0000 14 8 7 13 8 6 39040.930000 0.100000 2 1.0000 14 7 7 13 7 6 39098.630000 0.100000 2 1.0000 14 7 8 13 7 7 39098.630000 0.100000 2 1.0000 14 6 8 13 6 7 39189.430000 0.100000 0 14 6 9 13 6 8 39189.430000 0.100000 0 14 5 9 13 5 8 39379.420000 0.100000 1 14 5 10 13 5 9 39320.870000 0.100000 0 14 4 10 13 4 9 39981.910000 0.100000 1 14 4 11 13 4 10 39369.440000 0.100000 1 14 3 12 13 3 11 38810.400000 0.100000 1 14 2 13 13 2 12 37222.000000 0.100000 1 14 1 13 13 1 12 37670.370000 0.100000 1 14 1 14 13 1 13 34973.120000 0.100000 1 14 0 14 13 0 13 34998.580000 0.100000 1 15 1 14 14 1 13 40013.980000 0.100000 1 15 1 15 14 1 14 37389.900000 0.100000 1 15 0 15 14 0 14 37405.580000 0.100000 1 16 1 16 15 1 15 39805.200000 0.100000 1 16 0 16 15 0 15 39814.700000 0.100000 1 ! !------------------------------------------------------------------------------ ! ! MMW measurements in Warsaw ! ! aR_0,1 bandheads ! 72 0 72 71 0 71 174882.592000 0.050000 1 71 1 70 70 1 69 174867.568000 0.050000 1 70 2 68 69 2 67 174855.559000 0.050000 1 68 4 64 67 4 63 174856.917000 0.050000 1 67 5 62 66 5 61 174883.386000 0.050000 1 66 6 60 65 6 59 174942.507000 0.050000 1 65 7 58 64 7 57 175056.710000 0.050000 1 65 8 58 64 8 57 175055.719000 0.050000 1 64 9 56 63 9 55 175258.371000 0.050000 1 64 8 56 63 8 55 175273.484000 0.050000 1 61 12 50 60 12 49 174903.350000 0.050000 1 88 0 88 87 0 87 213448.560000 0.050000 1 87 1 86 86 1 85 213432.890000 0.050000 1 86 2 84 85 2 83 213419.107000 0.050000 1 84 4 80 83 4 79 213406.088000 0.050000 1 83 5 78 82 5 77 213413.452000 0.050000 1 82 6 76 81 6 75 213436.829000 0.050000 1 81 7 74 80 7 73 213484.229000 0.050000 1 80 8 72 79 8 71 213567.930000 0.050000 1 79 9 70 78 9 69 213707.669000 0.050000 1 89 0 89 88 0 88 215858.349000 0.050000 1 88 1 87 87 1 86 215842.626000 0.050000 1 87 2 85 86 2 84 215828.798000 0.050000 1 86 3 83 85 3 82 215818.774000 0.050000 1 85 4 81 84 4 80 215815.174000 0.050000 1 84 5 79 83 5 78 215821.797000 0.050000 1 83 6 77 82 6 76 215843.854000 0.050000 1 82 7 75 81 7 74 215888.886000 0.050000 1 80 9 71 79 9 70 216101.289000 0.050000 2 1.0000 80 10 71 79 10 70 216101.289000 0.050000 2 1.0000 79 10 69 78 10 68 216320.140000 0.050000 1 79 11 69 78 11 68 216316.904000 0.050000 1 78 11 67 77 11 66 216703.861000 0.050000 1 78 12 67 77 12 66 216658.675000 0.050000 1 105 0 105 104 0 104 254404.804000 0.050000 1 104 1 103 103 1 102 254388.839000 0.050000 1 103 2 101 102 2 100 254373.953000 0.050000 1 102 3 99 101 3 98 254361.580000 0.050000 1 101 4 97 100 4 96 254353.305000 0.050000 1 100 5 95 99 5 94 254351.241000 0.050000 1 98 7 91 97 7 90 254378.411000 0.050000 1 97 8 89 96 8 88 254416.818000 0.050000 1 96 9 87 95 9 86 254480.945000 0.050000 1 95 10 85 94 10 84 254581.774000 0.050000 1 134 0 134 133 0 133 324212.717000 0.050000 1 133 1 132 132 1 131 324196.308000 0.050000 1 132 2 130 131 2 129 324180.453000 0.050000 1 131 3 128 130 3 127 324165.834000 0.050000 1 130 4 126 129 4 125 324153.145000 0.050000 1 129 5 124 128 5 123 324143.656000 0.050000 1 128 6 122 127 6 121 324138.604000 0.050000 1 127 7 120 126 7 119 324139.568000 0.050000 1 126 8 118 125 8 117 324148.578000 0.050000 1 125 9 116 124 9 115 324168.186000 0.050000 1 124 10 114 123 10 113 324201.750000 0.050000 1 123 11 112 122 11 111 324253.535000 0.050000 1 ! ! higher K-1 tails of aR_0,1-type lines for J+1<-J sequences ! 59 11 48 58 11 47 174698.962000 0.050000 1 61 14 48 60 14 47 174697.254000 0.050000 1 62 15 48 61 15 47 176967.883000 0.050000 1 62 15 47 61 15 46 177085.782000 0.050000 1 62 18 45 61 18 44 175256.007000 0.050000 1 63 37 26 62 37 25 175532.826000 0.050000 1 63 36 27 62 36 26 175577.997000 0.050000 1 63 35 28 62 35 27 175626.951000 0.050000 1 63 34 29 62 34 28 175680.204000 0.050000 1 73 13 60 72 13 59 214092.676000 0.050000 1 74 15 60 73 15 59 213126.157000 0.050000 1 74 16 59 73 16 58 212857.811000 0.050000 1 75 12 63 74 12 62 213185.591000 0.050000 1 75 18 58 74 18 57 214176.735000 0.050000 1 75 20 55 74 20 54 212791.475000 0.050000 1 75 20 56 74 20 55 212790.672000 0.050000 1 76 24 52 75 24 51 214111.120000 0.050000 1 76 28 48 75 28 47 213192.056000 0.050000 1 76 29 47 75 29 46 213023.772000 0.050000 1 76 30 46 75 30 45 212872.833000 0.050000 1 76 31 45 75 31 44 212736.705000 0.050000 1 76 32 44 75 32 43 212613.555000 0.050000 1 76 33 43 75 33 42 212501.631000 0.050000 1 77 25 52 76 25 51 216731.169000 0.050000 1 77 26 51 76 26 50 216478.899000 0.050000 1 77 30 47 76 30 46 215727.351000 0.050000 1 77 31 46 76 31 45 215585.667000 0.050000 1 77 32 45 76 32 44 215457.438000 0.050000 1 115 18 97 114 18 96 323825.750000 0.050000 1 115 19 97 114 19 96 323752.550000 0.050000 1 115 36 79 114 36 78 323796.870000 0.050000 1 ! ! bQ-type lines ! 64 24 40 64 23 41 176795.193000 0.050000 1 63 24 39 63 23 40 176975.300000 0.050000 1 62 24 38 62 23 39 177146.492000 0.050000 1 72 29 43 72 28 44 215318.978000 0.050000 1 70 29 41 70 28 42 215596.774000 0.050000 1 66 29 37 66 28 38 216083.271000 0.050000 1 65 29 36 65 28 37 216191.608000 0.050000 1 64 29 35 64 28 36 216295.015000 0.050000 1 63 29 34 63 28 35 216393.592000 0.050000 1 ! ! bR-type lines ! 21 16 6 20 15 5 176877.282000 0.050000 1 23 20 4 22 19 3 213013.470000 0.050000 1 24 20 5 23 19 4 215791.718000 0.050000 1 26 19 8 25 18 7 213700.903000 0.050000 1 27 19 8 26 18 9 216476.458000 0.050000 1 34 16 19 33 15 18 212822.292000 0.050000 1 35 16 20 34 15 19 215564.786000 0.050000 1 37 15 23 36 14 22 213272.636000 0.050000 1 38 15 23 37 14 24 215980.952000 0.050000 2 1.0000 38 15 24 37 14 23 215980.952000 0.050000 2 1.0000 38 20 19 37 19 18 254585.425000 0.050000 1 41 14 28 40 13 27 216119.250000 0.050000 1 41 28 14 40 27 13 324135.089000 0.050000 1 49 12 38 48 11 37 216384.396000 0.050000 1 52 24 28 51 23 29 323849.506000 0.050000 1 67 19 48 66 18 49 323904.122000 0.050000 1 69 13 57 68 12 56 214064.268000 0.050000 1 77 12 65 76 13 64 216030.211000 0.050000 1 79 10 69 78 11 68 216310.536000 0.050000 1 +++++-----+++++-----+++++-----++++++++++++++++++++---------------+++++----------++++++++ ----------------------------------------------------------------------------------------